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Flames
A flame () is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction made in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density, they are then considered plasma. Mechanism Color and temperature of a flame are dependent on the type of fuel involved in the combustion. For example, when a lighter is held to a candle, the applied heat causes the fuel molecules in the candle wax to vaporize. In this state they can then readily react with oxygen in the air, which gives off enough heat in the subsequent exothermic reaction to vaporize yet more fuel, thus sustaining a consistent flame. The high temperature of the flame causes the vaporized fuel molecules to decompose, forming various incomplete combustion products and free radicals, and these products then react with each other and with the oxidizer involved in the reaction of the following flame (fire). One may investigate different parts of a candle f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffusion Flame
In combustion, a diffusion flame is a flame in which the oxidizer and fuel are separated before burning. Contrary to its name, a diffusion flame involves both diffusion and convection processes. The name diffusion flame was first suggested by S.P. Burke and T.E.W. Schumann in 1928, to differentiate from premixed flame where fuel and oxidizer are premixed prior to burning. The diffusion flame is also referred to as nonpremixed flame. The burning rate is however still limited by the rate of diffusion. Diffusion flames tend to burn slower and to produce more soot than premixed flames because there may not be sufficient oxidizer for the reaction to go to completion, although there are some exceptions to the rule. The soot typically produced in a diffusion flame becomes incandescent from the heat of the flame and lends the flame its readily identifiable orange-yellow color. Diffusion flames tend to have a less-localized flame front than premixed flames. The contexts for diffusion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fire
Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction Product (chemistry), products. Flames, the most visible portion of the fire, are produced in the combustion reaction when the fuel reaches its ignition point temperature. Flames from hydrocarbon fuels consist primarily of carbon dioxide, water vapor, oxygen, and nitrogen. If hot enough, the gases may become ionized to produce Plasma (physics), plasma. The color and Intensity (heat transfer), intensity of the flame depend on the type of fuel and composition of the surrounding gases. Fire, in its most common form, has the potential to result in conflagration, which can lead to permanent physical damage. It directly impacts land-based ecological systems worldwide. The positive effects of fire include stimulating plant growth and maintaining ecological balance. Its negative effects include hazards to life and property, atmospheric pollution, and water ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Premixed Flame
A premixed flame is a flame formed under certain conditions during the combustion of a premixed charge (also called pre-mixture) of fuel and oxidiser. Since the fuel and oxidiser—the key chemical reactants of combustion—are available throughout a homogeneous stoichiometric premixed charge, the combustion process once initiated sustains itself by way of its own heat release. The majority of the chemical transformation in such a combustion process occurs primarily in a thin interfacial region which separates the unburned and the burned gases. The premixed flame interface propagates through the mixture until the entire charge is depleted. The propagation speed of a premixed flame is known as the flame speed (or burning velocity) which depends on the convection-diffusion-reaction balance within the flame, i.e. on its inner chemical structure. The premixed flame is characterised as laminar or turbulent depending on the velocity distribution in the unburned pre-mixture (which prov ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Soot
Soot ( ) is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons. Soot is considered a hazardous substance with carcinogenic properties. Most broadly, the term includes all the particulate matter produced by this process, including black carbon and residual pyrolysed fuel particles such as coal, cenospheres, charred wood, and petroleum coke classified as cokes or char. It can include polycyclic aromatic hydrocarbons and heavy metals like mercury. Soot causes various types of cancer and lung disease. Terminology Definition Among scientists, exact definitions for soot vary, depending partly on their field. For example, atmospheric scientists may use a different definition compared to toxicologists. Soot's definition can also vary across time, and from paper to paper even among scientists in the same field. A common feature of the definitions is that soot is composed largely of carbon based particles resulting from the incomplete burni ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pyrolysis
Pyrolysis is a process involving the Bond cleavage, separation of covalent bonds in organic matter by thermal decomposition within an Chemically inert, inert environment without oxygen. Etymology The word ''pyrolysis'' is coined from the Greek language, Greek-derived morpheme, elements ''pyro-'' (from Ancient Greek : - "fire, heat, fever") and ''lysis'' ( : - "separation, loosening"). Applications Pyrolysis is most commonly used in the treatment of organic compound, organic materials. It is one of the processes involved in the charring of wood or pyrolysis of biomass. In general, pyrolysis of organic substances produces volatile products and leaves Char (chemistry), char, a carbon-rich solid residue. Extreme pyrolysis, which leaves mostly carbon as the residue, is called carbonization. Pyrolysis is considered one of the steps in the processes of gasification or combustion. Laypeople often confuse pyrolysis gas with syngas. Pyrolysis gas has a high percentage of heavy tar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radical (chemistry)
In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes. A notable example of a radical is the hydroxyl radical (HO·), a molecule that has one unpaired electron on the oxygen atom. Two other examples are triplet oxygen and triplet carbene (꞉) which have two unpaired electrons. Radicals may be generated in a number of ways, but typical methods involve redox reactions. Ionizing radiation, heat, electrical discharges, and electrolysis are known to produce radicals. Radicals are intermediates in many chemical reactions, more so than is apparent from the balanced equations. Radicals are important in combustion, atmospheric chemistry, polymerization, plasma chemistry, biochemistry, and many other chemical processes. A majority ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorine
Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extremely Reactivity (chemistry), reactive as it reacts with all other Periodic table, elements except for the light Noble gas, noble gases. It is highly toxicity, toxic. Among the elements, fluorine ranks Abundance of the chemical elements, 24th in cosmic abundance and 13th in crustal abundance. Fluorite, the primary mineral source of fluorine, which gave the element its name, was first described in 1529; as it was added to metal ores to lower their melting points for smelting, the Latin verb meaning gave the mineral its name. Proposed as an element in 1810, fluorine proved difficult and dangerous to separate from its compounds, and several early experimenters died or sustained injuries from their attempts. Only in 1886 did French chemist He ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Chloride
The Chemical compound, compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride gas and hydrochloric acid are important in technology and industry. Hydrochloric acid, the aqueous solution of hydrogen chloride, is also commonly given the formula HCl. Reactions Hydrogen chloride is a diatomic molecule, consisting of a hydrogen atom H and a chlorine atom Cl connected by a Polar-covalent bond, polar covalent bond. The chlorine atom is much more Electronegativity, electronegative than the hydrogen atom, which makes this bond polar. Consequently, the molecule has a large Molecular dipole moment, dipole moment with a negative partial charge (δ−) at the chlorine atom and a positive partial charge (δ+) at the hydrogen atom. In part because of its high polarity, HCl is very soluble in water (and in other ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History The pioneering work of chemical kinetics was done by German chemist Ludwig Wilhelmy in 1850. He experimentally studied the rate of inversion of sucrose and he used integrated rate law for the determination of the reaction kinetics of this reaction. His work was noticed 34 years later by Wilhelm Ostwald. In 1864, Peter Waage and Cato Guldberg published the law ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluoropolymer
A fluoropolymer is a fluorocarbon-based polymer with multiple carbon–fluorine bonds. It is characterized by a high resistance to solvents, acids, and bases. The best known fluoropolymer is polytetrafluoroethylene under the brand name "Teflon," trademarked by the DuPont Company. History In 1938, polytetrafluoroethylene (DuPont brand name Teflon) was discovered by accident by a recently hired DuPont Ph.D., Roy J. Plunkett. While working with tetrafluoroethylene gas to develop refrigerants, he noticed that a previously pressurized cylinder had no pressure remaining. In dissecting the cylinder, he found a mass of white solid in a quantity similar to that of the tetrafluoroethylene gas. It was determined that this material was a new-to-the-world polymer. Tests showed the substance was resistant to corrosion from most acids, bases and solvents and had better high temperature stability than any other plastic. By early 1941, a crash program was making substantial quantities of PT ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hypergolic
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other. The two propellant components usually consist of a fuel and an oxidizer. The main advantages of hypergolic propellants are that they can be stored as liquids at room temperature and that engines which are powered by them are easy to ignite reliably and repeatedly. Common hypergolic propellants are extremely toxic or corrosive, making them difficult to handle. In contemporary usage, the terms "hypergol" and "hypergolic propellant" usually mean the most common such propellant combination: dinitrogen tetroxide plus hydrazine. History The fact that turpentine may spontaneously combust when mixed with nitric acid was discovered as early as the late 17th century by Frederick Slare, but it remained a scientific curiosity for centuries until it was proposed to use it for rocket-assisted take off during WWII. In 1935, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
