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Fine Electronic Structure
In solid state physics and physical chemistry, the fine electronic structure of a solid are the features of the electronic bands induced by intrinsic interactions between charge carriers. Valence and conduction bands split slightly compared to the difference between the various bands. Some mechanisms that allow it are angular momentum couplings, spin-orbit coupling, lattice distortions (Jahn–Teller effect), and other interactions described by crystal field theory. The name comes from the fine structure of atoms, where energy levels suffer from a similar effect from the non- relativistic calculation due to effects like spin–orbit interaction, zitterbewegung, and corrections to the kinetic energy. See also * Fine structure constant *Rashba effect The Rashba effect, also called Bychkov–Rashba effect, is a momentum-dependent splitting of spin bands in bulk crystalsMore specifically, uniaxial noncentrosymmetric crystals. and low-dimensional condensed matter syste ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solid-state Physics
Solid-state physics is the study of rigid matter, or solids, through methods such as quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state physics studies how the large-scale properties of solid materials result from their atomic-scale properties. Thus, solid-state physics forms a theoretical basis of materials science. It also has direct applications, for example in the technology of transistors and semiconductors. Background Solid materials are formed from densely packed atoms, which interact intensely. These interactions produce the mechanical (e.g. hardness and elasticity), thermal, electrical, magnetic and optical properties of solids. Depending on the material involved and the conditions in which it was formed, the atoms may be arranged in a regular, geometric pattern ( crystalline solids, which include metals and ordinary water ice) or irregularly (an amorphous solid such as common ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fine Structure
In atomic physics, the fine structure describes the splitting of the spectral lines of atoms due to electron spin and relativistic corrections to the non-relativistic Schrödinger equation. It was first measured precisely for the hydrogen atom by Albert A. Michelson and Edward W. Morley in 1887, laying the basis for the theoretical treatment by Arnold Sommerfeld, introducing the fine-structure constant. Background Gross structure The ''gross structure'' of line spectra is the line spectra predicted by the quantum mechanics of non-relativistic electrons with no spin. For a hydrogenic atom, the gross structure energy levels only depend on the principal quantum number ''n''. However, a more accurate model takes into account relativistic and spin effects, which break the degeneracy of the energy levels and split the spectral lines. The scale of the fine structure splitting relative to the gross structure energies is on the order of (''Zα'')2, where ''Z'' is the atomic number and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Physics
Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned with the way in which electrons are arranged around the nucleus and the processes by which these arrangements change. This comprises ions, neutral atoms and, unless otherwise stated, it can be assumed that the term ''atom'' includes ions. The term ''atomic physics'' can be associated with nuclear power and nuclear weapons, due to the synonymous use of ''atomic'' and ''nuclear'' in standard English. Physicists distinguish between atomic physics—which deals with the atom as a system consisting of a nucleus and electrons—and nuclear physics, which studies nuclear reactions and special properties of atomic nuclei. As with many scientific fields, strict delineation can be highly contrived and atomic physics is often considered in the wider ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dresselhaus Effect
The Dresselhaus effect is a phenomenon in solid-state physics in which spin–orbit interaction causes energy bands to split. It is usually present in crystal systems lacking inversion symmetry. The effect is named after Gene Dresselhaus, husband of Mildred Dresselhaus, who discovered this splitting in 1955. Spin–orbit interaction is a relativistic coupling between the electric field produced by an ion-core and the resulting dipole moment arising from the relative motion of the electron, and its intrinsic magnetic dipole proportional to the electron spin. In an atom, the coupling weakly splits an orbital energy state into two states: one state with the spin aligned to the orbital field and one anti-aligned. In a solid crystalline material, the motion of the conduction electrons in the lattice can be altered by a complementary effect due to the coupling between the potential of the lattice and the electron spin. If the crystalline material is not centro-symmetric, the asymmetry ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rashba Effect
The Rashba effect, also called Bychkov–Rashba effect, is a momentum-dependent splitting of spin bands in bulk crystalsMore specifically, uniaxial noncentrosymmetric crystals. and low-dimensional condensed matter systems (such as heterostructures and surface states) similar to the splitting of particles and anti-particles in the Dirac Hamiltonian. The splitting is a combined effect of spin–orbit interaction and asymmetry of the crystal potential, in particular in the direction perpendicular to the two-dimensional plane (as applied to surfaces and heterostructures). This effect is named in honour of Emmanuel Rashba, who discovered it with Valentin I. Sheka in 1959 for three-dimensional systems and afterward with Yurii A. Bychkov in 1984 for two-dimensional systems.Yu. A. Bychkov and E. I. Rashba, Properties of a 2D electron gas with a lifted spectrum degeneracy, Sov. Phys. - JETP Lett. 39, 78-81 (1984) Remarkably, this effect can drive a wide variety of novel physical ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fine Structure Constant
In physics, the fine-structure constant, also known as the Sommerfeld constant, commonly denoted by (the Greek letter ''alpha''), is a fundamental physical constant which quantifies the strength of the electromagnetic interaction between elementary charged particles. It is a dimensionless quantity, independent of the system of units used, which is related to the strength of the coupling of an elementary charge ''e'' with the electromagnetic field, by the formula . Its numerical value is approximately , with a relative uncertainty of The constant was named by Arnold Sommerfeld, who introduced it in 1916 Equation 12a, ''"rund 7·" (about ...)'' when extending the Bohr model of the atom. quantified the gap in the fine structure of the spectral lines of the hydrogen atom, which had been measured precisely by Michelson and Morley in 1887. Definition In terms of other fundamental physical constants, may be defined as: \alpha = \frac = \frac , where * is the elementary ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zitterbewegung
In physics, the zitterbewegung ("jittery motion" in German, ) is the predicted rapid oscillatory motion of elementary particles that obey relativistic wave equations. The existence of such motion was first discussed by Gregory Breit in 1928 and later by Erwin Schrödinger in 1930 as a result of analysis of the wave packet solutions of the Dirac equation for relativistic electrons in free space, in which an interference between positive and negative energy states produces what appears to be a fluctuation (up to the speed of light) of the position of an electron around the median, with an angular frequency of , or approximately radians per second. For the hydrogen atom, zitterbewegung can be invoked as a heuristic way to derive the Darwin term, a small correction of the energy level of the s-orbitals. Theory Free fermion The time-dependent Dirac equation is written as : H \psi (\mathbf,t) = i \hbar \frac (\mathbf,t) , where \hbar is the reduced Planck constant, \psi(\mathbf,t) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Special Relativity
In physics, the special theory of relativity, or special relativity for short, is a scientific theory regarding the relationship between space and time. In Albert Einstein's original treatment, the theory is based on two postulates: # The laws of physics are invariant (that is, identical) in all inertial frames of reference (that is, frames of reference with no acceleration). # The speed of light in vacuum is the same for all observers, regardless of the motion of the light source or the observer. Origins and significance Special relativity was originally proposed by Albert Einstein in a paper published on 26 September 1905 titled "On the Electrodynamics of Moving Bodies".Albert Einstein (1905)''Zur Elektrodynamik bewegter Körper'', ''Annalen der Physik'' 17: 891; English translatioOn the Electrodynamics of Moving Bodiesby George Barker Jeffery and Wilfrid Perrett (1923); Another English translation On the Electrodynamics of Moving Bodies by Megh Nad Saha (1920). The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Energy Level
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized. In chemistry and atomic physics, an electron shell, or principal energy level, may be thought of as the orbit of one or more electrons around an atom's nucleus. The closest shell to the nucleus is called the " shell" (also called "K shell"), followed by the " shell" (or "L shell"), then the " shell" (or "M shell"), and so on farther and farther from the nucleus. The shells correspond with the principal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Field Theory
Crystal field theory (CFT) describes the breaking of degeneracies of electron orbital states, usually ''d'' or ''f'' orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors). This theory has been used to describe various spectroscopies of transition metal coordination complexes, in particular optical spectra (colors). CFT successfully accounts for some magnetic properties, colors, hydration enthalpies, and spinel structures of transition metal complexes, but it does not attempt to describe bonding. CFT was developed by physicists Hans Bethe and John Hasbrouck van Vleck in the 1930s. CFT was subsequently combined with molecular orbital theory to form the more realistic and complex ligand field theory (LFT), which delivers insight into the process of chemical bonding in transition metal complexes. Overview of crystal field theory According to crystal field theory, the interaction between a transition metal and ligands arises from th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria. Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids). Some of the relationships that physical chemistry strives to resolve include the effects of: # Intermolecular forces that act upon the physical properties of materials ( plasticity, tensile strength, surface tension in liquids). # Reaction kinetics on the rate of a reaction. # The identity of ions and the electrical conductivity of materials. # Surface science and electrochemistry of cel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jahn–Teller Effect
The Jahn–Teller effect (JT effect or JTE) is an important mechanism of spontaneous symmetry breaking in molecular and solid-state systems which has far-reaching consequences in different fields, and is responsible for a variety of phenomena in spectroscopy, stereochemistry, crystal chemistry, molecular and solid-state physics, and materials science. The effect is named for Hermann Arthur Jahn and Edward Teller, who first reported studies about it in 1937.Bunker, Philip R.; Jensen, Per (1998) ''Molecular Symmetry and Spectroscopy'' (2nd ed.). NRC Research Press, Ottaw/ref> Simplified overview The Jahn–Teller effect, sometimes also referred to as Jahn–Teller distortion, describes the geometrical distortion of molecules and ions that result from certain electron configurations. The Jahn–Teller theorem essentially states that any non-linear molecule with a spatially degenerate electronic ground state will undergo a geometrical distortion that removes that degeneracy, because t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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