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Eucalyptol
Eucalyptol (also called cineole) is a monoterpenoid colorless liquid, and a bicyclic ether. It has a fresh camphor-like odor and a spicy, cooling taste. It is insoluble in water, but miscible with organic solvents. Eucalyptol makes up about 70–90% of eucalyptus oil. Eucalyptol forms crystalline adducts with hydrohalic acids, ''o''-cresol, resorcinol, and phosphoric acid. Formation of these adducts is useful for purification. In 1870, F. S. Cloez identified and ascribed the name "eucalyptol" to the dominant portion of ''Eucalyptus globulus'' oil. Uses Because of its pleasant, spicy aroma and taste, eucalyptol is used in flavorings, fragrances, and cosmetics. Cineole-based eucalyptus oil is used as a flavoring at low levels (0.002%) in various products, including baked goods, confectionery, meat products, and beverages. In a 1994 report released by five top cigarette companies, eucalyptol was listed as one of the 599 additives to cigarettes. It is claimed to be add ...
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Eucalyptol Synthesis
Eucalyptol (also called cineole) is a monoterpenoid colorless liquid, and a bicyclic ether. It has a fresh camphor-like odor and a spicy, cooling taste. It is insoluble in water, but miscible with organic solvents. Eucalyptol makes up about 70–90% of eucalyptus oil. Eucalyptol forms crystalline adducts with hydrohalic acids, ''o''-cresol, resorcinol, and phosphoric acid. Formation of these adducts is useful for purification. In 1870, F. S. Cloez identified and ascribed the name "eucalyptol" to the dominant portion of ''Eucalyptus globulus'' oil. Uses Because of its pleasant, spicy aroma and taste, eucalyptol is used in flavorings, fragrances, and cosmetics. Cineole-based eucalyptus oil is used as a flavoring at low levels (0.002%) in various products, including baked goods, confectionery, meat products, and beverages. In a 1994 report released by five top cigarette companies, eucalyptol was listed as one of the 599 additives to cigarettes. It is claimed to be added to ...
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Monoterpenoid
Monoterpenes are a class of terpenes that consist of two isoprene units and have the molecular formula C10H16. Monoterpenes may be linear (acyclic) or contain rings (monocyclic and bicyclic). Modified terpenes, such as those containing oxygen functionality or missing a methyl group, are called monoterpenoids. Monoterpenes and monoterpenoids are diverse. They have relevance to the pharmaceutical, cosmetic, agricultural, and food industries. Biosynthesis Monoterpenes are derived biosynthetically from units of isopentenyl pyrophosphate, which is formed from acetyl-CoA via the intermediacy of mevalonic acid in the HMG-CoA reductase pathway. An alternative, unrelated biosynthesis pathway of IPP is known in some bacterial groups and the plastids of plants, the so-called MEP-(2-methyl-D-erythritol-4-phosphate) pathway, which is initiated from C5 sugars. In both pathways, IPP is isomerized to DMAPP by the enzyme isopentenyl pyrophosphate isomerase. Geranyl pyrophosphate is the precursor ...
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Mouthwash
Mouthwash, mouth rinse, oral rinse, or mouth bath is a liquid which is held in the mouth passively or swirled around the mouth by contraction of the perioral muscles and/or movement of the head, and may be gargled, where the head is tilted back and the liquid bubbled at the back of the mouth. Usually mouthwashes are antiseptic solutions intended to reduce the microbial load in the mouth, although other mouthwashes might be given for other reasons such as for their analgesic, anti-inflammatory or anti-fungal action. Additionally, some rinses act as saliva substitutes to neutralize acid and keep the mouth moist in xerostomia (dry mouth). Cosmetic mouthrinses temporarily control or reduce bad breath and leave the mouth with a pleasant taste. Rinsing with water or mouthwash after brushing with a fluoride toothpaste can reduce the availability of salivary fluoride. This can lower the anti-cavity re-mineralization and antibacterial effects of fluoride. Fluoridated mouthwash may mi ...
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François Stanislas Cloez
François Stanislas Cloez (24 June 1817 – 12 October 1883) was a French chemist, who authored both as "''F. S. Cloez''" and "''S. Cloez''", and is known for his pioneering role in analytical chemistry during the 19th century. He was a founder and later president of the Chemistry Society of France. In 1851, Cloez and Italian chemist Stanislao Cannizzaro, working on collaborative research, prepared cyanamide by the action of ammonia on cyanogen chloride in ethereal solution. In the 1870s, he commenced the identification of the constituents of individual essential oils and their classification into groups according to their suitability for medicinal, industrial and perfumery purposes. He identified the major constituent of eucalyptus oil, which he called "''eucalyptol''" (now generally known as cineole). In honour of his work on eucalyptus oil '' Eucalyptus cloeziana'' (Gympie messmate) is named after him. Cloez also played a role in developing a theory on the origin of life else ...
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Insect Repellent
An insect repellent (also commonly called "bug spray" or "bug deterrent") is a substance applied to the skin, clothing, or other surfaces to discourage insects (and arthropods in general) from landing or climbing on that surface. Insect repellents help prevent and control the outbreak of insect-borne (and other arthropod-bourne) diseases such as malaria, Lyme disease, dengue fever, bubonic plague, river blindness, and West Nile fever. Pest animals commonly serving as vectors for disease include insects such as flea, fly, and mosquito; and ticks (arachnids). Some insect repellents are insecticides (bug killers), but most simply discourage insects and send them flying or crawling away. Effectiveness Synthetic repellents tend to be more effective and/or longer lasting than "natural" repellents. For protection against ticks and mosquito bites, the U.S. Centers for Disease Control (CDC) recommends DEET, icaridin (picaridin, KBR 3023), oil of lemon eucalyptus (OLE), para-me ...
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Eucalyptus Globulus
''Eucalyptus globulus'', commonly known as southern blue gum or blue gum, is a species of flowering plant in the family Myrtaceae. It is a tall, evergreen tree Endemism, endemic to southeastern Australia. This ''Eucalyptus'' species has mostly smooth bark, juvenile leaves that are whitish and waxy on the lower surface, glossy green, lance-shaped adult leaves, wikt:glaucous#Adjective, glaucous, ribbed flower buds arranged singly or in groups of three or seven in leaf wikt:axil, axils, white flowers and woody fruit. There are four subspecies, each with a different distribution across Australia, occurring in New South Wales, Victoria and Tasmania. The subspecies are the Victorian blue gum, Tasmanian blue gum, Maiden's gum, and Victorian eurabbie. Description ''Eucalyptus globulus'' is a tree that typically grows to a height of but may sometimes only be a stunted shrub, or alternatively under ideal conditions can grow as tall as , and forms a lignotuber. The bark is usually smo ...
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Aframomum Corrorima
''Aframomum corrorima'' is a species of flowering plant in the ginger family, Zingiberaceae. It is an herbaceous perennial that produces leafy stems 1–2 meters tall from rhizomatous roots. The alternately-arranged leaves are dark green, 10–30 cm long and 2.5–6 cm across, elliptical to oblong in shape. Pink flowers are borne near the ground and give way to red, fleshy fruits containing shiny brown seeds, which are typically 3–5 mm in diameter. The spice, known as Ethiopian cardamom, false cardamom, or ''korarima'', is obtained from the plant's seeds (usually dried), and is extensively used in Ethiopian and Eritrean cuisine. It is an ingredient in '' berbere'', '' mitmita'', ''awaze'', and other spice mixtures, and is also used to flavor coffee. Its flavor is comparable to that of the closely related '' Elettaria cardamomum'' or green cardamom. In Ethiopian herbal medicine, the seeds are used as a tonic, carminative, and laxative. The plant is native to ...
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Eucalyptus Oil
Eucalyptus oil is the generic name for distilled oil from the leaves of ''Eucalyptus'', a genus of the plant family Myrtaceae, mostly native to Australia but cultivated worldwide. Eucalyptus oil has a history of wide application, as a pharmaceutical, antiseptic, insect repellent, repellent, flavouring and fragrance, as well as having industrial uses. The leaves of selected ''Eucalyptus'' species are steam distillation, steam distilled to extract eucalyptus oil. Types and production In the trade, eucalyptus oils are categorized into three broad types according to their composition and main end-use: medicinal, perfumery and industrial. The most prevalent is the standard cineole-based "oil of eucalyptus", a colourless mobile liquid (which yellows with age), having a penetrating, camphoraceous, woody plant, woody-sweet scent. China produces about 75% of the world output, but most of that is derived from the cineole fractions of Cinnamomum camphora, camphor laurel rather than being ...
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Hydrogen Halide
In chemistry, hydrogen halides (hydrohalic acids when in the aqueous phase) are diatomic, inorganic compounds that function as Arrhenius acids. The formula is HX where X is one of the halogens: fluorine, chlorine, bromine, iodine, astatine, or tennessine. All known hydrogen halides are gases at standard temperature and pressure.The Acidity of the Hydrogen Halides. (2020, August 21). Retrieved May 5, 2021, from https://chem.libretexts.org/@go/page/3699 Comparison to hydrohalic acids The hydrogen halides are diatomic molecules with no tendency to ionize in the gas phase (although liquified hydrogen fluoride is a polar solvent somewhat similar to water). Thus, chemists distinguish hydrogen chloride from hydrochloric acid. The former is a gas at room temperature that reacts with water to give the acid. Once the acid has formed, the diatomic molecule can be regenerated only with difficulty, but not by normal distillation. Commonly the names of the acid and the molecules are ...
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Orchid Bee
The tribe Euglossini, in the subfamily Apinae, commonly known as orchid bees or euglossine bees, are the only group of corbiculate bees whose non-parasitic members do not all possess eusocial behavior. Description, distribution, and behavior Most of the tribe's species are solitary, though a few are communal, or exhibit simple forms of eusociality. There are about 200 described species, distributed in five genera: '' Euglossa'', '' Eulaema'', '' Eufriesea'', '' Exaerete'' and the monotypic '' Aglae''. All species occur in South or Central America, though one species, ''Euglossa dilemma'', has become established in Florida in the United States, and species of '' Eulaema'' and '' Eufriesea'' have been reported from Arizona and Texas, respectively. The genera ''Exaerete'' and ''Aglae'' are kleptoparasites in the nests of other orchid bees. All except ''Eulaema'' are characterized by brilliant metallic coloration, primarily green, gold, and blue. Females gather pollen and necta ...
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Ether
In organic chemistry, ethers are a class of compounds that contain an ether group, a single oxygen atom bonded to two separate carbon atoms, each part of an organyl group (e.g., alkyl or aryl). They have the general formula , where R and R′ represent the organyl groups. Ethers can again be classified into two varieties: if the organyl groups are the same on both sides of the oxygen atom, then it is a simple or symmetrical ether, whereas if they are different, the ethers are called mixed or unsymmetrical ethers. A typical example of the first group is the solvent and anaesthetic diethyl ether, commonly referred to simply as "ether" (). Ethers are common in organic chemistry and even more prevalent in biochemistry, as they are common linkages in carbohydrates and lignin. Structure and bonding Ethers feature bent linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141  pm. The barrier to rotation about the C–O bonds is low. The bonding of ox ...
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1,8-cineole Synthase
1,8-Cineole synthase (EC 4.2.3.108, ''1,8-cineole cyclase'', ''geranyl pyrophoshate:1,8-cineole cyclase'', ''1,8-cineole synthetase'') is an enzyme with systematic name geranyl-diphosphate diphosphate-lyase (cyclizing, 1,8-cineole-forming). This enzyme catalyses the following chemical reaction : geranyl diphosphate + H2O \rightleftharpoons 1,8- cineole + diphosphate In chemistry, pyrophosphates are phosphorus oxyanions that contain two phosphorus atoms in a linkage. A number of pyrophosphate salts exist, such as disodium pyrophosphate () and tetrasodium pyrophosphate (), among others. Often pyrophosphate ... :: This enzyme requires Mn2+ or Zn2+. Geranyl diphosphate first isomerizes to (''S'')-linalyl diphosphate which ionises to the alpha-terpinyl cation which reacts with water to form the product. References External links * {{Portal bar, Biology, border=no EC 4.2.3 ...
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