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Energy Operator
In quantum mechanics, energy is defined in terms of the energy operator, acting on the wave function of the system as a consequence of time translation symmetry. Definition It is given by: \hat = i\hbar\frac It acts on the wave function (the probability amplitude for different configurations of the system) \Psi\left(\mathbf, t\right) Application The energy operator corresponds to the full energy of a system. The Schrödinger equation describes the space- and time-dependence of the slow changing (non- relativistic) wave function of a quantum system. The solution of the Schrödinger equation for a bound system is discrete (a set of permitted states, each characterized by an energy level) which results in the concept of quanta. Schrödinger equation Using the energy operator in the Schrödinger equation: i\hbar\frac \Psi(\mathbf,\,t) = \hat H \Psi(\mathbf,t) one obtains: \hat\Psi(\mathbf, t) = \hat \Psi(\mathbf, t) where ''i'' is the imaginary unit, ''ħ'' is the reduce ...
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Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ...
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Schrödinger Equation
The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after Erwin Schrödinger, an Austrian physicist, who postulated the equation in 1925 and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics. Given a set of known initial conditions, Newton's second law makes a mathematical prediction as to what path a given physical system will take over time. The Schrödinger equation gives the evolution over time of the wave function, the quantum-mechanical characterization of an isolated physical system. The equation was postulated by Schrödinger based on a postulate of Louis de Broglie that all matter has an associated matter wave. The equati ...
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Linear Operator
In mathematics, and more specifically in linear algebra, a linear map (also called a linear mapping, linear transformation, vector space homomorphism, or in some contexts linear function) is a mapping V \to W between two vector spaces that preserves the operations of vector addition and scalar multiplication. The same names and the same definition are also used for the more general case of modules over a ring; see Module homomorphism. If a linear map is a bijection then it is called a . In the case where V = W, a linear map is called a linear endomorphism. Sometimes the term refers to this case, but the term "linear operator" can have different meanings for different conventions: for example, it can be used to emphasize that V and W are real vector spaces (not necessarily with V = W), or it can be used to emphasize that V is a function space, which is a common convention in functional analysis. Sometimes the term ''linear function'' has the same meaning as ''linear map' ...
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Partial Derivative
In mathematics, a partial derivative of a function of several variables is its derivative with respect to one of those variables, with the others held constant (as opposed to the total derivative, in which all variables are allowed to vary). Partial derivatives are used in vector calculus and differential geometry. The partial derivative of a function f(x, y, \dots) with respect to the variable x is variously denoted by It can be thought of as the rate of change of the function in the x-direction. Sometimes, for the partial derivative of z with respect to x is denoted as \tfrac. Since a partial derivative generally has the same arguments as the original function, its functional dependence is sometimes explicitly signified by the notation, such as in: f'_x(x, y, \ldots), \frac (x, y, \ldots). The symbol used to denote partial derivatives is ∂. One of the first known uses of this symbol in mathematics is by Marquis de Condorcet from 1770, who used it for partial differ ...
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Scalar (mathematics)
A scalar is an element of a field which is used to define a ''vector space''. In linear algebra, real numbers or generally elements of a field are called scalars and relate to vectors in an associated vector space through the operation of scalar multiplication (defined in the vector space), in which a vector can be multiplied by a scalar in the defined way to produce another vector. Generally speaking, a vector space may be defined by using any field instead of real numbers (such as complex numbers). Then scalars of that vector space will be elements of the associated field (such as complex numbers). A scalar product operation – not to be confused with scalar multiplication – may be defined on a vector space, allowing two vectors to be multiplied in the defined way to produce a scalar. A vector space equipped with a scalar product is called an inner product space. A quantity described by multiple scalars, such as having both direction and magnitude, is called a ...
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De Broglie Relation
Matter waves are a central part of the theory of quantum mechanics, being half of wave–particle duality. At all scales where measurements have been practical, matter exhibits wave-like behavior. For example, a beam of electrons can be diffracted just like a beam of light or a water wave. The concept that matter behaves like a wave was proposed by French physicist Louis de Broglie () in 1924, and so matter waves are also known as de Broglie waves. The ''de Broglie wavelength'' is the wavelength, , associated with a particle with momentum through the Planck constant, : \lambda = \frac. Wave-like behavior of matter has been experimentally demonstrated, first for electrons in 1927 and for other elementary particles, neutral atoms and molecules in the years since. Matter waves have more complex velocity relations than solid objects and they also differ from electromagnetic waves (light). Collective matter waves are used to model phenomena in solid state physics; standing matter ...
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Plane Wave
In physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ..., a plane wave is a special case of a wave or field: a physical quantity whose value, at any given moment, is constant through any plane that is perpendicular to a fixed direction in space. For any position \vec x in space and any time t, the value of such a field can be written as F(\vec x,t) = G(\vec x \cdot \vec n, t), where \vec n is a unit-length vector, and G(d,t) is a function that gives the field's value as dependent on only two real parameters: the time t, and the scalar-valued displacement d = \vec x \cdot \vec n of the point \vec x along the direction \vec n. The displacement is constant over each plane perpendicular to \vec n. The values of the field F may be scalars, vectors, or any other physical or ma ...
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Free Particle
In physics, a free particle is a particle that, in some sense, is not bound by an external force, or equivalently not in a region where its potential energy varies. In classical physics, this means the particle is present in a "field-free" space. In quantum mechanics, it means the particle is in a region of uniform potential, usually set to zero in the region of interest since the potential can be arbitrarily set to zero at any point in space. Classical free particle The classical free particle is characterized by a fixed velocity ''v''. The momentum of a particle with mass ''m'' is given by p=mv and the kinetic energy (equal to total energy) by E=\fracmv^2=\frac. Quantum free particle Mathematical description A free particle with mass m in non-relativistic quantum mechanics is described by the free Schrödinger equation: - \frac \nabla^2 \ \psi(\mathbf, t) = i\hbar\frac \psi (\mathbf, t) where ''ψ'' is the wavefunction of the particle at position r and time ''t''. The sol ...
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Momentum Operator
In quantum mechanics, the momentum operator is the operator associated with the linear momentum. The momentum operator is, in the position representation, an example of a differential operator. For the case of one particle in one spatial dimension, the definition is: \hat = - i \hbar \frac where is the reduced Planck constant, the imaginary unit, is the spatial coordinate, and a partial derivative (denoted by \partial/\partial x) is used instead of a total derivative () since the wave function is also a function of time. The "hat" indicates an operator. The "application" of the operator on a differentiable wave function is as follows: \hat\psi = - i \hbar \frac In a basis of Hilbert space consisting of momentum eigenstates expressed in the momentum representation, the action of the operator is simply multiplication by , i.e. it is a multiplication operator, just as the position operator is a multiplication operator in the position representation. Note that the definition ab ...
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Klein–Gordon Equation
The Klein–Gordon equation (Klein–Fock–Gordon equation or sometimes Klein–Gordon–Fock equation) is a relativistic wave equation, related to the Schrödinger equation. It is named after Oskar Klein and Walter Gordon. It is second-order in space and time and manifestly Lorentz-covariant. It is a differential equation version of the relativistic energy–momentum relation E^2 = (pc)^2 + \left(m_0c^2\right)^2\,. Statement The Klein–Gordon equation can be written in different ways. The equation itself usually refers to the position space form, where it can be written in terms of separated space and time components \ \left(\ t, \mathbf\ \right)\ or by combining them into a four-vector \ x^\mu = \left(\ c\ t, \mathbf\ \right) ~. By Fourier transforming the field into momentum space, the solution is usually written in terms of a superposition of plane waves whose energy and momentum obey the energy-momentum dispersion relation from special relativity. Here, the Klein– ...
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Speed Of Light
The speed of light in vacuum, commonly denoted , is a universal physical constant exactly equal to ). It is exact because, by international agreement, a metre is defined as the length of the path travelled by light in vacuum during a time interval of second. The speed of light is invariant (physics), the same for all observers, no matter their relative velocity. It is the upper limit for the speed at which Information#Physics_and_determinacy, information, matter, or energy can travel through Space#Relativity, space. All forms of electromagnetic radiation, including visible light, travel at the speed of light. For many practical purposes, light and other electromagnetic waves will appear to propagate instantaneously, but for long distances and sensitive measurements, their finite speed has noticeable effects. Much starlight viewed on Earth is from the distant past, allowing humans to study the history of the universe by viewing distant objects. When Data communication, comm ...
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Invariant Mass
The invariant mass, rest mass, intrinsic mass, proper mass, or in the case of bound systems simply mass, is the portion of the total mass of an object or system of objects that is independent of the overall motion of the system. More precisely, it is a characteristic of the system's total energy and momentum that is the same in all frames of reference related by Lorentz transformations.Lawrence S. LernerPhysics for Scientists and Engineers, Volume 2, page 1073 1997. If a center-of-momentum frame exists for the system, then the invariant mass of a system is equal to its total mass in that "rest frame". In other reference frames, where the system's momentum is non-zero, the total mass (a.k.a. relativistic mass) of the system is greater than the invariant mass, but the invariant mass remains unchanged. Because of mass–energy equivalence, the rest energy of the system is simply the invariant mass times the speed of light squared. Similarly, the total energy of the system is ...
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