Dicalcium Ruthenate

	Dicalcium Ruthenate Dicalcium ruthenate, with the chemical formula Ca2RuO4, is a stochiometric oxide compound that hosts a multi-orbital (band) Mott insulator, Mott insulating ground state. For this reason, Ca2RuO4 serves as an important "meeting-point" between conceptual developments of strongly correlated multi-band physics and advanced experimental spectroscopies. Its electronic structure and also orbital magnetism are therefore subjects of experimental and theoretical scrutiny. Electronic properties Around 350 K, Ca2RuO4 undergoes a Metal–insulator transition, metal insulator transition which involves a crystal structure transition leading to a strong ''c''-axis compression. Negative thermal expansion has also been reported in conjunction with this ''c''-axis compression. The metal insulator transition is sensitive to electrical current. Below 80 K, an Antiferromagnetism, anti-ferromagnetic ordering emerges. Related materials Ca1.8Sr0.2RuO4 has been proposed as a candidate system for orbit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]
	Distrontium Ruthenate Distrontium ruthenate, also known as strontium ruthenate, is an oxide of strontium and ruthenium with the chemical formula Sr2RuO4. It was the first reported perovskite superconductor that did not contain copper. Strontium ruthenate is structurally very similar to the high-temperature cuprate superconductors, and in particular, is almost identical to the lanthanum doped superconductor (La, Sr)2CuO4. However, the transition temperature for the superconducting phase transition is 0.93 K (about 1.5 K for the best sample), which is much lower than the corresponding value for cuprates. Superconductivity Superconductivity in SRO was first observed by Yoshiteru Maeno et al. Unlike the cuprate superconductors, SRO displays superconductivity in the absence of doping. The superconducting order parameter in SRO exhibits signatures of time-reversal symmetry breaking, and hence, it can be classified as an unconventional superconductor. Sr2RuO4 is believed to be a fairly two-dimensiona ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]
	Oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of (called a passivation layer) that protects the foil from further oxidation.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Stoichiometry Oxides are extraordinarily diverse in terms of stoichiometries (the measurable relationship between reactants and chemical equations of an equation or reaction) and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide.Greenwood, N. N.; & Earnsh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]
	Mott Insulator Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators (particularly at low temperatures). These insulators fail to be correctly described by band theories of solids due to their strong electron–electron interactions, which are not considered in conventional band theory. A Mott transition is a transition from a metal to an insulator, driven by the strong interactions between electrons. One of the simplest models that can capture Mott transition is the Hubbard model. The band gap in a Mott insulator exists between bands of like character, such as 3d electron bands, whereas the band gap in charge-transfer insulators exists between anion and cation states. History Although the band theory of solids had been very successful in describing various electrical properties of materials, in 1937 Jan Hendrik de Boer and Evert Johannes Willem Verwey pointed out that a variety of transiti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]
picture info	Magnetism Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, magnetism is one of two aspects of electromagnetism. The most familiar effects occur in ferromagnetic materials, which are strongly attracted by magnetic fields and can be magnetized to become permanent magnets, producing magnetic fields themselves. Demagnetizing a magnet is also possible. Only a few substances are ferromagnetic; the most common ones are iron, cobalt, nickel, and their alloys. All substances exhibit some type of magnetism. Magnetic materials are classified according to their bulk susceptibility. Ferromagnetism is responsible for most of the effects of magnetism encountered in everyday life, but there are actually several types of magnetism. Paramagnetic substances, such as aluminium and oxygen, are weakly attracted ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]
	Metal–insulator Transition Metal–insulator transitions are transitions of a material from a metal (material with good electrical conductivity of electric charges) to an insulator (material where conductivity of charges is quickly suppressed). These transitions can be achieved by tuning various ambient parameters such as temperature, pressure or, in case of a semiconductor, doping. History The basic distinction between metals and insulators was proposed by Hans Bethe, Arnold Sommerfeld and Felix Bloch in 1928-1929. It distinguished between conducting metals (with partially filled bands) and nonconducting insulators. However, in 1937 Jan Hendrik de Boer and Evert Verwey reported that many transition-metal oxides (such as NiO) with a partially filled d-band were poor conductors, often insulating. In the same year, the importance of the electron-electron correlation was stated by Rudolf Peierls. Since then, these materials as well as others exhibiting a transition between a metal and an insulator hav ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]
	Antiferromagnetism In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. This is, like ferromagnetism and ferrimagnetism, a manifestation of ordered magnetism. The phenomenon of antiferromagnetism was first introduced by Lev Landau in 1933. Generally, antiferromagnetic order may exist at sufficiently low temperatures, but vanishes at and above the Néel temperature – named after Louis Néel, who had first identified this type of magnetic ordering. Above the Néel temperature, the material is typically paramagnetic. Measurement When no external field is applied, the antiferromagnetic structure corresponds to a vanishing total magnetization. In an external magnetic field, a kind of ferrimagnetic behavior may be displayed in the antiferromagnetic phase, with the absolute value of one of the sublattice magne ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]
picture info	Calcium Compounds Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth's crust, and the third most abundant metal, after iron and aluminium. The most common calcium compound on Earth is calcium carbonate, found in limestone and the fossils of early sea life; gypsum, anhydrite, fluorite, and apatite are also sources of calcium. The name comes from Latin ''calx'' " lime", which was obtained from heating limestone. Some calcium compounds were known to the ancients, though their chemistry was unknown until the seventeenth century. Pure calcium was isolated in 1808 via electrolysis of its oxide by Humphry Davy, who named the element. Calcium compounds are widely used in many industries: in foods and pharmaceuticals for calc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu]