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Chlorine-36
Chlorine-36 (36Cl) is an isotope of chlorine. Chlorine has two stable isotopes and one naturally occurring radioactive isotope, the cosmogenic isotope 36Cl. Its half-life is 301,300 ± 1,500 years. 36Cl decays primarily (98%) by beta-minus decay to 36 Ar, and the balance to 36 S. Trace amounts of radioactive 36Cl exist in the environment, in a ratio of about (7–10) × 10−13 to 1 with stable chlorine isotopes. This corresponds to a concentration of approximately 1 Bq/(kg Cl). 36Cl is produced in the atmosphere by spallation of 36 Ar by interactions with cosmic ray protons. In the top meter of the lithosphere, 36Cl is generated primarily by thermal neutron activation of 35Cl and spallation of 39 K and 40 Ca. In the subsurface environment, muon capture by 40 Ca becomes more important. The production rates are about 4200 atoms 36Cl/yr/mole 39K and 3000 atoms 36Cl/yr/mole 40Ca, due to spallation in rocks at sea level. The half-life of this isotope makes it suitable ...
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Environmental Isotopes
The environmental isotopes are a subset of isotopes, both stable and radioactive, which are the object of isotope geochemistry. They are primarily used as tracers to see how things move around within the ocean-atmosphere system, within terrestrial biomes, within the Earth's surface, and between these broad domains. Isotope geochemistry Chemical elements are defined by their number of protons, but the mass of the atom is determined by the number of protons and neutrons in the nucleus. Isotopes are atoms that are of a specific element, but have different numbers of neutrons and thus different mass numbers. The ratio between isotopes of an element varies slightly in the world, so in order to study isotopic ratio changes across the world, changes in isotope ratios are defined as deviations from a standard, multiplied by 1000. This unit is a "per mil". As a convention, the ratio is of the heavier isotope to the lower isotope. \delta \ce = \left( \frac -1 \right) \times 1000 ‰ Thes ...
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Chlorine
Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval alchemists, which commonly involved the heating of chloride salts like ammonium chloride ( sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and hydrochloric acid (in the form of ). However, the nature of free chlorine gas as a separate substance was only recognised aroun ...
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Cosmogenic
Cosmogenic nuclides (or cosmogenic isotopes) are rare nuclides (isotopes) created when a high-energy cosmic ray interacts with the nucleus of an ''in situ'' Solar System atom, causing nucleons (protons and neutrons) to be expelled from the atom (see cosmic ray spallation). These nuclides are produced within Earth materials such as rocks or soil, in Earth's atmosphere, and in extraterrestrial items such as meteoroids. By measuring cosmogenic nuclides, scientists are able to gain insight into a range of geological and astronomical processes. There are both radioactive and stable cosmogenic nuclides. Some of these radionuclides are tritium, carbon-14 and phosphorus-32. Certain light (low atomic number) primordial nuclides (isotopes of lithium, beryllium and boron) are thought to have been created not only during the Big Bang, but also (and perhaps primarily) to have been made after the Big Bang, but before the condensation of the Solar System, by the process of cosmic ray spall ...
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Underwater Explosion
An underwater explosion (also known as an UNDEX) is a chemical or nuclear explosion that occurs under the surface of a body of water. While useful in anti-ship and submarine warfare, underwater bombs are not as effective against coastal facilities. Properties of water Underwater explosions differ from in-air explosions due to the properties of water: *Mass and incompressibility (all explosions) – water has a much higher density than air, which makes water harder to move (higher inertia). It is also relatively hard to compress (increase density) when under pressure in a low range (up to about 100 atmospheres). These two together make water an excellent conductor of shock waves from an explosion. *Effect of neutron exposure on salt water (nuclear explosions only) – most underwater blast scenarios happen in seawater, not fresh or pure water. The water itself is not much affected by neutrons but salt is strongly affected. When exposed to neutron radiation during the microsecond o ...
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Muon Capture
Muon capture is the capture of a negative muon by a proton, usually resulting in production of a neutron and a neutrino, and sometimes a gamma photon. Muon capture by heavy nuclei often leads to emission of particles; most often neutrons, but charged particles can be emitted as well. Ordinary muon capture (OMC) involves capture of a negative muon from the atomic orbital without emission of a gamma photon: : +  → μ +  Radiative muon capture (RMC) is a radiative version of OMC, where a gamma photon is emitted: : +  → μ +  +  Theoretical motivation for the study of muon capture on the proton is its connection to the proton's induced pseudoscalar form factor gp. Practical application - Nuclear waste disposal Muon capture is being investigated for practical application in radioactive waste disposal, for example in the artificial transmutation of large quantities of long-lived radioactive waste that ha ...
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Isotopes Of Chlorine
Chlorine (17Cl) has 25 isotopes with mass numbers ranging from 28Cl to 52Cl and 2 isomers (34mCl and 38mCl). There are two stable isotopes, 35Cl (75.77%) and 37Cl (24.23%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is 36Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 hour, many less than one second. The shortest-lived are 29Cl and 30Cl, with half-lives less than 10 picoseconds and 30 nanoseconds, respectively—the half-life of 28Cl is unknown. List of isotopes , - , 28Cl , style="text-align:right" , 17 , style="text-align:right" , 11 , 28.02954(64)# , , p , 27S , 1+# , , , - , 29Cl , style="text-align:right" , 17 , style="text-align:right" , 12 , 29.01413(20) , <10 ps , p , 28S , (1/2+) , , , - , 30Cl , style="text-align:right" , 17 , style="text-align:right" , 13 , 30.00477(21)# , <30 ns , p , ...
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Ground Water
Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidated deposit is called an aquifer when it can yield a usable quantity of water. The depth at which soil pore spaces or fractures and voids in rock become completely saturated with water is called the water table. Groundwater is recharged from the surface; it may discharge from the surface naturally at springs and seeps, and can form oases or wetlands. Groundwater is also often withdrawn for agricultural, municipal, and industrial use by constructing and operating extraction wells. The study of the distribution and movement of groundwater is hydrogeology, also called groundwater hydrology. Typically, groundwater is thought of as water flowing through shallow aquifers, but, in the technical sense, it can also contain soil moisture, permafro ...
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Soil
Soil, also commonly referred to as earth or dirt Dirt is an unclean matter, especially when in contact with a person's clothes, skin, or possessions. In such cases, they are said to become dirty. Common types of dirt include: * Debris: scattered pieces of waste or remains * Dust: a gener ..., is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former term specifically to displaced soil. Soil consists of a solid phase of minerals and organic matter (the soil matrix), as well as a Porosity, porous phase that holds Soil gas, gases (the soil atmosphere) and water (the soil solution). Accordingly, soil is a three-state of matter, state system of solids, liquids, and gases. Soil is a product of several factors: the influence of climate, terrain, relief (elevation, orientation, and slope of terrain), organisms, and the soil's parent materials (ori ...
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Nuclear Weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bomb types release large quantities of energy from relatively small amounts of matter. The first test of a fission ("atomic") bomb released an amount of energy approximately equal to . The first thermonuclear ("hydrogen") bomb test released energy approximately equal to . Nuclear bombs have had yields between 10 tons TNT (the W54) and 50 megatons for the Tsar Bomba (see TNT equivalent). A thermonuclear weapon weighing as little as can release energy equal to more than . A nuclear device no larger than a conventional bomb can devastate an entire city by blast, fire, and radiation. Since they are weapons of mass destruction, the proliferation of nuclear weapons is a focus of international relations policy. Nuclear weapons have been d ...
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Nuclear Weapons Testing
Nuclear weapons tests are experiments carried out to determine nuclear weapons' effectiveness, yield, and explosive capability. Testing nuclear weapons offers practical information about how the weapons function, how detonations are affected by different conditions, and how personnel, structures, and equipment are affected when subjected to nuclear explosions. However, nuclear testing has often been used as an indicator of scientific and military strength. Many tests have been overtly political in their intention; most nuclear weapons states publicly declared their nuclear status through a nuclear test. The first nuclear device was detonated as a test by the United States at the Trinity site in New Mexico on July 16, 1945, with a yield approximately equivalent to 20 kilotons of TNT. The first thermonuclear weapon technology test of an engineered device, codenamed "Ivy Mike", was tested at the Enewetak Atoll in the Marshall Islands on November 1, 1952 (local date), also by t ...
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Seawater
Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximately of dissolved salts (predominantly sodium () and chloride () ions). The average density at the surface is 1.025 kg/L. Seawater is denser than both fresh water and pure water (density 1.0 kg/L at ) because the dissolved salts increase the mass by a larger proportion than the volume. The freezing point of seawater decreases as salt concentration increases. At typical salinity, it freezes at about . The coldest seawater still in the liquid state ever recorded was found in 2010, in a stream under an Antarctic glacier: the measured temperature was . Seawater pH is typically limited to a range between 7.5 and 8.4. However, there is no universally accepted reference pH-scale for seawater and the difference between measu ...
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Proxy (statistics)
In statistics, a proxy or proxy variable is a variable that is not in itself directly relevant, but that serves in place of an unobservable or immeasurable variable. In order for a variable to be a good proxy, it must have a close correlation, not necessarily linear, with the variable of interest. This correlation might be either positive or negative. Proxy variable must relate to an unobserved variable, must correlate with disturbance, and must not correlate with regressors once the disturbance is controlled for. Examples In social sciences, proxy measurements are often required to stand in for variables that cannot be directly measured. This process of standing in is also known as operationalization. Per-capita gross domestic product (GDP) is often used as a proxy for measures of standard of living or quality of life. Montgomery ''et al.'' examine several proxies used, and point out limitations with each, stating "In poor countries, no single empirical measure can be expected ...
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