Radium Compounds
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Radium Compounds
Radium compounds are compounds containing the element radium (Ra). Due to radium's radioactivity, not many compounds have been well characterized. Solid radium compounds are white as radium ions provide no specific coloring, but they gradually turn yellow and then dark over time due to self-radiolysis from radium's alpha decay.Kirby et al., p. 4 Insoluble radium compounds coprecipitate with all barium, most strontium, and most lead compounds.Kirby et al., p. 8 Oxides and hydroxides Radium oxide (RaO) has not been characterized well past its existence, despite oxides being common compounds for the other alkaline earth metals. Radium hydroxide (Ra(OH)2) is the most readily soluble among the alkaline earth hydroxides and is a stronger base than its barium congener, barium hydroxide.Kirby et al., pp. 4–8 It is also more soluble than actinium hydroxide and thorium hydroxide: these three adjacent hydroxides may be separated by precipitating them with ammonia. Halides Radium flu ...
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Radium
Radium is a chemical element; it has chemical symbol, symbol Ra and atomic number 88. It is the sixth element in alkaline earth metal, group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) upon exposure to air, forming a black surface layer of radium nitride (Ra3N2). All isotopes of radium are radioactive, the most stable isotope being radium-226 with a half-life of 1,600 years. When radium decays, it emits ionizing radiation as a by-product, which can excite fluorescent chemicals and cause radioluminescence. For this property, it was widely used in Self-luminous paint, self-luminous paints following its discovery. Of the Radionuclide, radioactive elements that occur in quantity, radium is considered particularly Toxicity, toxic, and it is Carcinogen, carcinogenic due to the radioactivity of both it and its immediate decay product radon as well as its tendency to B ...
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Alpha Radiation
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an atomic number that is reduced by two. An alpha particle is identical to the nucleus of a helium-4 atom, which consists of two protons and two neutrons. It has a charge of and a mass of , and is represented as ^_\alpha. For example, uranium-238 undergoes alpha decay to form thorium-234. While alpha particles have a charge , this is not usually shown because a nuclear equation describes a nuclear reaction without considering the electrons – a convention that does not imply that the nuclei necessarily occur in neutral atoms. Alpha decay typically occurs in the heaviest nuclides. Theoretically, it can occur only in nuclei somewhat heavier than nickel (element 28), where the overall binding energy per nucleon is no longer a maximum and the nuc ...
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Tetrafluoroberyllate
Tetrafluoroberyllate or orthofluoroberyllate is an anion with the chemical formula . It contains beryllium and fluorine. This fluoroanion has a tetrahedral shape, with the four fluorine atoms surrounding a central beryllium atom. It has the same size, charge, and outer electron structure as sulfate . Therefore, many compounds that contain sulfate have equivalents with tetrafluoroberyllate. Examples of these are the langbeinites, and Tutton's salts. Properties The Be–F bond length is between 145 and 153  pm. The beryllium is sp3 hybridized, leading to a longer bond than in , where beryllium is sp hybridized. In trifluoroberyllates, there are actually tetrahedra arranged in a triangle, so that three fluorine atoms are shared on two tetrahedra each, resulting in a formula of . In the tetrafluoroberyllates, the tetrahedra can rotate to various degrees. At room temperature, they are hindered from moving. But as temperature increases, they can rotate around the threefold ...
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Radium Iodate
Radium iodate is an inorganic compound, a salt of radium and iodic acid with the chemical formula . Synthesis Radium iodate is obtained by the reaction of a soluble radium salt and potassium iodate Potassium iodate ( K I O3) is an ionic inorganic compound with the formula . It is a white salt that is soluble in water. Preparation and properties It can be prepared by reacting a potassium-containing base such as potassium hydroxide with iod ...: :: Physical properties Radium iodate forms colorless crystals. It is poorly soluble in water. References {{Radium compounds Iodates Radium compounds ...
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Chromate And Dichromate
Chromate salts contain the chromate anion, . Dichromate salts contain the dichromate anion, . They are oxyanions of chromium in the +6 oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate ions can be interconvertible. Chemical properties Potassium-chromate-sample.jpg, Potassium chromate Potassium-dichromate-sample.jpg, Potassium dichromate Chromates react with hydrogen peroxide, giving products in which peroxide, , replaces one or more oxygen atoms. In acid solution the unstable blue peroxo complex Chromium(VI) oxide peroxide, , is formed; it is an uncharged covalent molecule, which may be extracted into ether. Addition of pyridine results in the formation of the more stable complex . Acid–base properties In aqueous solution, chromate and dichromate anions exist in a chemical equilibrium. : The predominance diagram shows that the position of the equilibrium depends on both pH and the analytical concentration o ...
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Radium Sulfate
Radium sulfate (or radium sulphate) is an inorganic compound with the formula RaSO4 and an average molecular mass of 322.088 g/mol. This white salt is the least soluble of all known sulfate salts. It was formerly used in radiotherapy and smoke detectors, but this has been phased out in favor of less hazardous alternatives. Properties Radium sulfate crystallizes in a solid in the same structure as barium sulfate. It forms crystals in the orthorhombic crystal system, with a unit cell of dimensions ''a'' = 9.13 ''b''=5.54 and ''c'' = 7.31 Å. The unit cell volume is 369.7 Å3. Distance from the radium ion to oxygen is 2.96  Å and the sulfur to oxygen bond length in the sulfate ion is 1.485  Å. In this compound the ionic radius of the radium ion is 1.66 Å, and it is in ten coordination. Radium sulfate can form solid solution A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a ...
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Nitric Acid
Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as synthetic dyes and medicines (e.g. metronidazole). Nitric acid is ...
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Radium Carbonate
Radium carbonate is a chemical compound of radium, carbon, and oxygen, having the chemical formula . It is the radium salt of carbonic acid. It contains radium cations () and carbonate anions (). This salt is a highly radioactive, amorphous, white powder that has potential applications in medicine. It is notable for forming disordered crystals at room temperature and for being approximately 10 times more soluble than its lighter congener barium carbonate. Radium carbonate is one of a few radium compounds which has significantly different properties from corresponding barium compounds. Moreover, radium is the only alkaline-earth metal which forms disordered crystals in its carbonate phase. Even though radium carbonate has very low solubility in water, it is soluble in dilute mineral acids and concentrated ammonium carbonate Ammonium carbonate is a chemical compound with the chemical formula . It is an ammonium salt of carbonic acid. It is composed of ammonium cations and carbonate ...
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Radium Nitrate
Radium nitrate is a radioactive salt with the formula Ra(NO3)2. It is a white solid, but old samples appear yellowish-grey. Although radium chloride and radium bromide are less soluble than the corresponding barium salts, radium nitrate is more soluble than barium nitrate. It decomposes at 280 °C to radium oxide. Production Radium nitrate is produced by the reaction of radium carbonate or radium sulfate with nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...: :RaCO3 + HNO3 → Ra(NO3)2 + CO2 + H2O References Radium compounds Nitrates {{salt-stub ...
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Helium
Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is the lowest among all the Chemical element, elements, and it does not have a melting point at standard pressures. It is the second-lightest and second-most Abundance of the chemical elements, abundant element in the observable universe, after hydrogen. It is present at about 24% of the total elemental mass, which is more than 12 times the mass of all the heavier elements combined. Its abundance is similar to this in both the Sun and Jupiter, because of the very high nuclear binding energy (per nucleon) of helium-4 with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of both nuclear fusion and radioactive decay. The most common isotope of helium in the universe is helium-4, ...
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Alpha Particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produced in different ways. Alpha particles are named after the first letter in the Greek alphabet, α. The symbol for the alpha particle is α or α2+. Because they are identical to helium nuclei, they are also sometimes written as He2+ or 2+ indicating a helium ion with a +2 charge (missing its two electrons). Once the ion gains electrons from its environment, the alpha particle becomes a normal (electrically neutral) helium atom . Alpha particles have a net spin of zero. When produced in standard alpha radioactive decay, alpha particles generally have a kinetic energy of about 5  MeV and a velocity in the vicinity of 4% of the speed of light. They are a highly ionizing form of particle radiation, with low penetration depth (stopped b ...
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Nitrogen
Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. It is a common element in the universe, estimated at Abundance of the chemical elements, seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element chemical bond, bond to form N2, a colourless and odourless diatomic molecule, diatomic gas. N2 forms about 78% of Atmosphere of Earth, Earth's atmosphere, making it the most abundant chemical species in air. Because of the volatility of nitrogen compounds, nitrogen is relatively rare in the solid parts of the Earth. It was first discovered and isolated by Scottish physician Daniel Rutherford in 1772 and independently by Carl Wilhelm Scheele and Henry Cavendish at about the same time. The name was suggested by French chemist ...
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