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Physical Chemists
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria. Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids). Some of the relationships that physical chemistry strives to understand include the effects of: # Intermolecular forces that act upon the physical properties of materials (plasticity, tensile strength, surface tension in liquids). # Reaction kinetics on the rate of a reaction. # The identity of ions and the electrical conductivity of materials. # Surface science and electrochemistry of cell membranes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plasticity (physics)
In physics and materials science, plasticity (also known as plastic deformation) is the ability of a solid material to undergo permanent Deformation (engineering), deformation, a non-reversible change of shape in response to applied forces. For example, a solid piece of metal being bent or pounded into a new shape displays plasticity as permanent changes occur within the material itself. In engineering, the transition from Elasticity (physics), elastic behavior to plastic behavior is known as Yield (engineering), yielding. Plastic deformation is observed in most materials, particularly metals, soils, Rock (geology), rocks, concrete, and foams. However, the physical mechanisms that cause plastic deformation can vary widely. At a crystalline scale, plasticity in metals is usually a consequence of dislocations. Such defects are relatively rare in most crystalline materials, but are numerous in some and part of their crystal structure; in such cases, plastic crystallinity can resul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase (matter)
In the physical sciences, a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is a different material, in its own separate phase. (See .) More precisely, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, magnetization and chemical composition. The term ''phase'' is sometimes used as a synonym for state of matter, but there can be several immiscible phases of the same state of matter (as where oil and water separate into distinct phases, both in the liquid state). Types of phases Distinct phases may be described as different states of matter such as gas, liquid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Thermodynamics
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the ''spontaneity'' of processes. The structure of chemical thermodynamics is based on the first two laws of thermodynamics. Starting from the first and second laws of thermodynamics, four equations called the "fundamental equations of Gibbs" can be derived. From these four, a multitude of equations, relating the thermodynamic properties of the thermodynamic system can be derived using relatively simple mathematics. This outlines the mathematical framework of chemical thermodynamics. History In 1865, the German physicist Rudolf Clausius, in his ''Mechanical Theory of Heat'', suggested that the principles ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Work (physics)
In science, work is the energy transferred to or from an Physical object, object via the application of force along a Displacement (vector), displacement. In its simplest form, for a constant force aligned with the direction of motion, the work equals the Product (mathematics), product of the force strength and the distance traveled. A force is said to do ''positive work'' if it has a component in the direction of the displacement of the point of application. A force does ''negative work'' if it has a component opposite to the direction of the displacement at the point of application of the force. For example, when a ball is held above the ground and then dropped, the work done by the gravitational force on the ball as it falls is positive, and is equal to the weight of the ball (a force) multiplied by the distance to the ground (a displacement). If the ball is thrown upwards, the work done by the gravitational force is negative, and is equal to the weight multiplied by the dis ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat
In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by such mechanisms as thermal conduction, electromagnetic radiation, and friction, which are microscopic in nature, involving sub-atomic, atomic, or molecular particles, or small surface irregularities, as distinct from the macroscopic modes of energy transfer, which are thermodynamic work and transfer of matter. For a closed system (transfer of matter excluded), the heat involved in a process is the difference in internal energy between the final and initial states of a system, after subtracting the work done in the process. For a closed system, this is the formulation of the first law of thermodynamics. Calorimetry is measurement of quantity of energy transferred as heat by its effect on the states of interacting bodies, for example, by the amount of ice melted or by change in temperature of a body. In the International System of Units (SI), the unit of measurement for he ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cell Membrane
The cell membrane (also known as the plasma membrane or cytoplasmic membrane, and historically referred to as the plasmalemma) is a biological membrane that separates and protects the interior of a cell from the outside environment (the extracellular space). The cell membrane consists of a lipid bilayer, made up of two layers of phospholipids with cholesterols (a lipid component) interspersed between them, maintaining appropriate membrane fluidity at various temperatures. The membrane also contains membrane proteins, including integral proteins that span the membrane and serve as membrane transporters, and peripheral proteins that loosely attach to the outer (peripheral) side of the cell membrane, acting as enzymes to facilitate interaction with the cell's environment. Glycolipids embedded in the outer lipid layer serve a similar purpose. The cell membrane controls the movement of substances in and out of a cell, being selectively permeable to ions and organic mole ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemistry
Electrochemistry is the branch of physical chemistry concerned with the relationship between Electric potential, electrical potential difference and identifiable chemical change. These reactions involve Electron, electrons moving via an electronically conducting phase (typically an external electrical circuit, but not necessarily, as in Electroless nickel-phosphorus plating, electroless plating) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic chemical species, species in a Solution (chemistry), solution). When a chemical reaction is driven by an electrical Voltage, potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an ''electrochemical'' reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the aforementioned electron ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Science
Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid–liquid interfaces, solid– gas interfaces, solid– vacuum interfaces, and liquid– gas interfaces. It includes the fields of ''surface chemistry'' and '' surface physics''. Some related practical applications are classed as surface engineering. The science encompasses concepts such as heterogeneous catalysis, semiconductor device fabrication, fuel cells, self-assembled monolayers, and adhesives. Surface science is closely related to interface and colloid science. Interfacial chemistry and physics are common subjects for both. The methods are different. In addition, interface and colloid science studies macroscopic phenomena that occur in heterogeneous systems due to peculiarities of interfaces. History The field of surface chemistry started with heterogeneous catalysis pioneered by Paul Sabatier on hydrogenation and Fritz Haber on the Haber ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conductivity (electrolytic)
Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a solution. For example, the measurement of product conductivity is a typical way to monitor and continuously trend the performance of water purification systems. In many cases, conductivity is linked directly to the total dissolved solids (TDS). High-quality deionized water has a conductivity of : \kappa = 0.05501 \pm 0.0001 μS/cm at 25 °C. This corresponds to a specific resistivity of : \rho = 18.18 \pm 0.03 MΩ⋅cm. The preparation of salt solutions often takes place in unsealed beakers. In this case the conductivity of purified water often is 10 to 20 times higher. A discussion can be found below. Typical drinking water is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reaction Rate
The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. Reaction rates can vary dramatically. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second. For most reactions, the rate decreases as the reaction proceeds. A reaction's rate can be determined by measuring the changes in concentration over time. Chemical kinetics is the part of physical chemistry that concerns how rates of chemical reactions are measured and predicted, and how reaction-rate data can be used to deduce probable reaction mechanisms. The concepts of chemical kinetics are applied in many disciplines, such as chemical engineering, enzymology and environmental e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History The pioneering work of chemical kinetics was done by German chemist Ludwig Wilhelmy in 1850. He experimentally studied the rate of inversion of sucrose and he used integrated rate law for the determination of the reaction kinetics of this reaction. His work was noticed 34 years later by Wilhelm Ostwald. In 1864, Peter Waage and Cato Guldberg published the law ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
