Curium(III) Iodide
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Curium(III) Iodide
Curium(III) iodide is the chemical compound with the formula . Since all isotopes of curium are only artificially produced, the compound has no natural occurrence. Synthesis Elemental curium and iodine can be reacted to synthesize curium(III) iodide. :: Also by the reaction of curium(III) chloride with ammonium iodide: :: Physical properties Curium(III) iodide is a colorless ionic compound consisting of Cm3+ and I− ions. It forms white crystals the hexagonal crystal system in the space group ''R3'' (space group no. 148) with the lattice parameters a = 744 pm and c = 2040 pm with six units per unit cell. Its crystal structure is isotypic with that of bismuth(III) iodide Bismuth(III) iodide is the inorganic compound with the formula Bi I3. This gray-black salt is the product of the reaction of bismuth and iodine, which once was of interest in qualitative inorganic analysis. Bismuth(III) iodide adopts a distin .... References {{Actinide halides Curium compounds ...
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Americium Triiodide
Americium(III) iodide or americium triiodide is the chemical compound, a salt composed of americium and iodine with the formula AmI3. Preparation Americium(III) iodide can be prepared by reacting americium(III) chloride with ammonium iodide: : Properties Americium(III) iodide takes the form of yellow crystals. The crystal form is orthorhombic. It melts around 960 °C. The density is 6.9 g/cm3. The compound consists of Am3+ and I− ions. It crystallizes in the trigonal crystal system in the space group R (space group no. 148) with the lattice parameters a = 742 pm and c = 2055 pm and six formula units per unit cell. Its crystal structure is isotypic with bismuth(III) iodide Bismuth(III) iodide is the inorganic compound with the formula Bi I3. This gray-black salt is the product of the reaction of bismuth and iodine, which once was of interest in qualitative inorganic analysis. Bismuth(III) iodide adopts a distin ....'' Gmelins Handbuch der anorganischen Chemi ...
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Springer Netherlands
Springer Science+Business Media, commonly known as Springer, is a German multinational publishing company of books, e-books and peer-reviewed journals in science, humanities, technical and medical (STM) publishing. Originally founded in 1842 in Berlin, it expanded internationally in the 1960s, and through mergers in the 1990s and a sale to venture capitalists it fused with Wolters Kluwer and eventually became part of Springer Nature in 2015. Springer has major offices in Berlin, Heidelberg, Dordrecht, and New York City. History Julius Springer founded Springer-Verlag in Berlin in 1842 and his son Ferdinand Springer grew it from a small firm of 4 employees into Germany's then second-largest academic publisher with 65 staff in 1872.Chronology
". Springer Science+Business Media.
In 1964, Springer expanded its business internationally, op ...
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McGraw-Hill
McGraw Hill is an American education science company that provides educational content, software, and services for students and educators across various levels—from K-12 to higher education and professional settings. They produce textbooks, digital learning tools, and adaptive technology to enhance learning experiences and outcomes. It is one of the "big three" educational publishers along with Houghton Mifflin Harcourt and Pearson Education. McGraw Hill also publishes reference and trade publications for the medical, business, and engineering professions. Formerly a division of The McGraw Hill Companies (later renamed McGraw Hill Financial, now S&P Global), McGraw Hill Education was divested and acquired by Apollo Global Management in March 2013 for $2.4 billion in cash. McGraw Hill was sold in 2021 to Platinum Equity for $4.5 billion. History McGraw Hill was founded in 1888, when James H. McGraw, co-founder of McGraw Hill, purchased the ''American Journal of Railway ...
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Curium(III) Chloride
Curium(III) chloride is the chemical compound with the formula CmCl3. Structure Curium(III) chloride has a 9 coordinate tricapped trigonal prismatic geometry. Synthesis Curium(III) chloride can be obtained from the reaction of hydrogen chloride gas with curium dioxide, curium(III) oxide, or curium(III) oxychloride at a temperature of 400-600 °C: : It can also be obtained from the dissolution of metallic curium in dilute hydrochloric acid: :2Cm 6HCl -> atop\ce2CmCl3 3H2 This method is complicated by the ongoing processes of hydrolysis and hydration of the resulting compound in an aqueous solution, making it problematic to obtain a pure product. It can be obtained from the reaction of curium nitride with cadmium chloride Cadmium chloride is a white crystalline compound of cadmium and chloride, with the formula CdCl2. This salt is a hygroscopic solid that is highly soluble in water and slightly soluble in alcohol. The crystal structure of cadmium chloride (descr ...
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Ammonium Iodide
Ammonium iodide is the inorganic compound with the formula NH4I. A white solid. It is an ionic compound, although impure samples appear yellow. This salt consists of ammonium cation and an iodide anion.Holleman, A. F.; Wiberg, E. ''Inorganic Chemistry'' Academic Press: San Diego, 2001. . It can be prepared by the action of hydroiodic acid on ammonia. It is easily soluble in water, from which it crystallizes in cubes. It is also soluble in ethanol. Ammonium iodide in aqueous solutions are observed as acidic and display elevated vapor pressures at high temperatures Preparation Ammonium iodide can be made in lab by treating ammonia with hydroiodic acid: : NH3 + HI → NH4I Uses Ammonium iodide is used as dietary supplement to treat iodine deficiency Iodine deficiency is a lack of the trace element iodine, an essential nutrient in the diet. It may result in metabolic problems such as goiter, sometimes as an endemic goiter as well as congenital iodine deficiency syndrome ...
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Inorganic Chemistry (journal)
''Inorganic Chemistry'' is a biweekly peer-reviewed scientific journal published by the American Chemical Society since 1962. It covers research in all areas of inorganic chemistry. The current editor-in-chief is Stefanie Dehnen ( Karlsruhe Institute of Technology). Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2022 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a type of journal ranking. Journals with higher impact factor values are considered more prestigious or important within their field. The Impact Factor of a journa ... of 4.6. See also * '' Organometallics'' References External links * American Chemical Society academic journals Biweekly journals Academic journals established in 1962 English-language journals Inorganic chemistry journals {{chem-journal-stub ...
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Springer-Verlag
Springer Science+Business Media, commonly known as Springer, is a German multinational publishing company of books, e-books and peer-reviewed journals in science, humanities, technical and medical (STM) publishing. Originally founded in 1842 in Berlin, it expanded internationally in the 1960s, and through mergers in the 1990s and a sale to venture capitalists it fused with Wolters Kluwer and eventually became part of Springer Nature in 2015. Springer has major offices in Berlin, Heidelberg, Dordrecht, and New York City. History Julius Springer founded Springer-Verlag in Berlin in 1842 and his son Ferdinand Springer grew it from a small firm of 4 employees into Germany's then second-largest academic publisher with 65 staff in 1872.Chronology
". Springer Science+Business Media.
In 1964, Springer expanded its business internationally, ...
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Hexagonal Crystal System
In crystallography, the hexagonal crystal family is one of the six crystal family, crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section hexagonal crystal family#Crystal systems, crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhom ...
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Bismuth(III) Iodide
Bismuth(III) iodide is the inorganic compound with the formula Bi I3. This gray-black salt is the product of the reaction of bismuth and iodine, which once was of interest in qualitative inorganic analysis. Bismuth(III) iodide adopts a distinctive crystal structure, with iodide centres occupying a hexagonally closest-packed lattice, and bismuth centres occupying either none or two-thirds of the octahedral holes (alternating by layer), therefore it is said to occupy one third of the total octahedral holes. Synthesis Bismuth(III) iodide forms upon heating an intimate mixture of iodine and bismuth powder: :2Bi + 3I2 → 2BiI3 BiI3 can also be made by the reaction of bismuth oxide with aqueous hydroiodic acid: :Bi2O3(s) + 6HI(aq) → 2BiI3(s) + 3H2O(l) Reactions Since bismuth(III) iodide is insoluble in water, an aqueous solution can be tested for the presence of Bi3+ ions by adding a source of iodide such as potassium iodide. A black precipitate of bismuth(III) iodide ...
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CRC Press
The CRC Press, LLC is an American publishing group that specializes in producing technical books. Many of their books relate to engineering, science and mathematics. Their scope also includes books on business, forensics and information technology. CRC Press is now a division of Taylor & Francis, itself a subsidiary of Informa. History The CRC Press was founded as the Chemical Rubber Company (CRC) in 1903 by brothers Arthur, Leo and Emanuel Friedman in Cleveland, Ohio, based on an earlier enterprise by Arthur, who had begun selling rubber laboratory aprons in 1900. The company gradually expanded to include sales of laboratory equipment to chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...s. In 1913 the CRC offered a short (116-page) manual called the ''Rubber Handboo ...
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Curium Compounds
Curium (Cm) usually forms compounds in the +3 oxidation state, although compounds with curium in the +4, +5 and +6 oxidation states are also known. Oxides Curium readily reacts with oxygen forming mostly Cm2O3 and CmO2 oxides,Delta T2Cm2O3 + O2. Or, Cm2O3 can be obtained by reducing CmO2 with molecular hydrogen: : 2CmO2 + H2 -> Cm2O3 + H2O Also, a number of ternary oxides of the type M(II)CmO3 are known, where M stands for a divalent metal, such as barium. Thermal oxidation of trace quantities of curium hydride (CmH2–3) has been reported to give a volatile form of CmO2 and the volatile trioxide CmO3, one of two known examples of the very rare +6 state for curium. Another observed species was reported to behave similar to a supposed plutonium tetroxide and was tentatively characterized as CmO4, with curium in the extremely rare +8 state; but new experiments seem to indicate that CmO4 does not exist, and have cast doubt on the existence of PuO4 as well. Halides The colorles ...
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Nuclear Materials
Nuclear material refers to the metals uranium, plutonium, and thorium, in any form, according to the IAEA. This is differentiated further into "source material", consisting of natural and depleted uranium, and "special fissionable material", consisting of enriched uranium ( U-235), uranium-233, and plutonium-239. Uranium ore concentrates are considered to be a "source material", although these are not subject to safeguards under the Nuclear Non-Proliferation Treaty. According to the Nuclear Regulatory Commission(NRC), there are four different types of regulated nuclear materials: special nuclear material, source material, byproduct material and radium. Special nuclear materials have plutonium, uranium-233 or uranium with U233 or U235 that has a content found more than in nature. Source material is thorium or uranium that has a U235 content equal to or less than what is in nature. Byproduct material is radioactive material that is not source or special nuclear material. It ca ...
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