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Contact Explosive
A contact explosive is a chemical substance that explodes violently when it is exposed to a relatively small amount of energy (e.g. friction, pressure, sound, light). Though different contact explosives have varying amounts of Sensitivity (explosives), energy sensitivity, they are all much more sensitive relative to other kinds of explosives. Contact explosives are a part of a group of explosives called primary explosives, which are also very sensitive to stimuli but not to the degree of contact explosives. The extreme sensitivity of contact explosives is due to either chemical composition, Chemical bond, bond type, or Chemical structure, structure. Types These are some common contact explosives. Reasons for instability Composition Presence of nitrogen Explosives that are nitrogen-based are incredibly volatile due to the stability of nitrogen in its diatomic state, N2.Senese, Fred. "Why Is Nitroglycerin Explosive?" General Chemistry Online: FAQ: Redox Reactions:. N.p., ...
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Detonating Nitrogen Triiodide
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds about 1 km/sec and differ from deflagrations which have subsonic flame speeds about 1 m/sec. Detonation may form from an explosion of fuel-oxidizer mixture. Compared with deflagration, detonation doesn't need to have an external oxidizer. Oxidizers and fuel mix when deflagration occurs. Detonation is more destructive than deflagrations. In detonation, the flame front travels through the air-fuel faster than sound; while in deflagration, the flame front travels through the air-fuel slower than sound. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. TNT, dynamite, and C4 are examples of high power explosives that detonate. The velocity of detonation in solid and liquid explosives i ...
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Fulminate
Fulminates are chemical compounds which include the fulminate ion (). The fulminate ion is a pseudohalic ion because its charge and reactivity are similar to those of the halogens. The name is derived from the Latin ''fulminātus'', meaning to explode like lightning, and reflects that fulminate salts are friction-sensitive explosives due to the instability of the ion. The best known is mercury(II) fulminate, which has been used as a primary explosive in detonators. Fulminates can be formed from metals, such as silver and mercury, dissolved in nitric acid, and reacted with ethanol. The weak single nitrogen-oxygen bond is responsible for their instability. Nitrogen very easily forms a stable triple bond to another nitrogen atom, forming nitrogen gas. Historical notes Fulminates were discovered by Edward Charles Howard in 1800. The use of fulminates for firearms was first demonstrated by a Scottish minister, Alexander John Forsyth, who patented his scent-bottle lock in 1807; th ...
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Fuel
A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work (physics), work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as Nuclear power, nuclear energy (via nuclear fission and nuclear fusion). The heat energy released by reactions of fuels can be converted into mechanical energy via a heat engine. Other times, the heat itself is valued for warmth, cooking, or industrial processes, as well as the illumination that accompanies combustion. Fuels are also used in the Cell (biology), cells of organisms in a process known as cellular respiration, where organic molecules are oxidized to release usable energy. Hydrocarbons and related organic molecules are by far the most common source of fuel used by humans, but other substances, including radioactive metals, are also utilized. Fu ...
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Oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ''electron donor''). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to ...
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Triple Bond
A triple bond in chemistry is a chemical bond between two atoms involving six Electron pair bond, bonding electrons instead of the usual two in a covalent bond, covalent single bond. Triple bonds are stronger than the equivalent covalent bond, single bonds or double bond, double bonds, with a bond order of three. The most common triple bond is in a nitrogen N2 molecule; the second most common is that between two carbon atoms, which can be found in alkynes. Other functional groups containing a triple bond are cyanides and isocyanides. Some diatomic molecules, such as diphosphorus and carbon monoxide, are also triple bonded. In skeletal formula, skeletal formulae the triple bond is drawn as three parallel lines (≡) between the two connected atoms. Bonding Triple bonding can be explained in terms of orbital hybridization. In the case of acetylene, each carbon atom has two sp orbital, sp-orbitals and two p-orbitals. The two sp-orbitals are linear, with 180° bond angles, and occupy ...
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Nitro Compound
In organic chemistry, nitro compounds are organic compounds that contain one or more nitro functional groups (). The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally. The nitro group is also strongly electron-withdrawing. Because of this property, bonds alpha (adjacent) to the nitro group can be acidic. For similar reasons, the presence of nitro groups in aromatic compounds retards electrophilic aromatic substitution but facilitates nucleophilic aromatic substitution. Nitro groups are rarely found in nature. They are almost invariably produced by nitration reactions starting with nitric acid. Synthesis Preparation of aromatic nitro compounds Aromatic nitro compounds are typically synthesized by nitration. Nitration is achieved using a mixture of nitric acid and sulfuric acid, which produce the nitronium ion (), which is the electrophile: + The nitration product produced on the largest scale, by f ...
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Nitrogen
Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. It is a common element in the universe, estimated at Abundance of the chemical elements, seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element chemical bond, bond to form N2, a colourless and odourless diatomic molecule, diatomic gas. N2 forms about 78% of Atmosphere of Earth, Earth's atmosphere, making it the most abundant chemical species in air. Because of the volatility of nitrogen compounds, nitrogen is relatively rare in the solid parts of the Earth. It was first discovered and isolated by Scottish physician Daniel Rutherford in 1772 and independently by Carl Wilhelm Scheele and Henry Cavendish at about the same time. The name was suggested by French chemist ...
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Silver Nitride
Silver nitride is an explosive chemical compound with symbol Ag3N. It is a black, metallic-looking solid which is formed when silver oxide or silver nitrate is dissolved in concentrated solutions of ammonia, causing formation of the diammine silver complex which subsequently breaks down to Ag3N. The standard free energy of the compound is about +315 kJ/mol, making it an endothermic compound which decomposes explosively to metallic silver and nitrogen gas. History Silver nitride was formerly referred to as fulminating silver, but this can cause confusion with silver fulminate or silver azide, other compounds which have also been referred to by this name. The fulminate and azide compounds do not form from ammoniacal solutions of Ag2O. Fulminating silver was first prepared in 1788 by the French chemist Claude Louis Berthollet. 70 years earlier, in 1716 Johann Kunckel von Löwenstern had already described the preparation. Properties Silver nitride is poorly soluble in water, bu ...
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Flash Powder
Flash powder is a pyrotechnic composition, a mixture of an oxidizer and a metallic fuel, which burns quickly (deflagrates) and produces a loud noise, regardless of confinement in some formulations. It is widely used in theatrical and display pyrotechnics and consumer fireworks (namely firecrackers, professional salutes, and formerly in banned items such as cherry bombs and M-80s) and was once used for flashes in photography. Different varieties of flash powder are made from different compositions; most common are potassium perchlorate and aluminium powder. Early formulations used potassium chlorate instead of potassium perchlorate. Flash powder compositions are also used in military pyrotechnics when production of large amount of noise or light is required, e.g., stun grenades, battle simulator devices, and photoflash bombs. History Lycopodium powder is a yellow-tan dust-like powder historically used as a flash powder. Today, the principal use of the powder is to create ...
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Tetrasulfur Tetranitride
Tetrasulfur tetranitride is an inorganic compound with the formula . This vivid orange, opaque, crystalline explosive is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding. Nitrogen and sulfur have similar electronegativities. When the properties of atoms are so highly similar, they often form extensive families of covalently bonded structures and compounds. Indeed, a large number of S-N and S-NH compounds are known with as their parent. Structure adopts an unusual "extreme cradle" structure, with D2d point group symmetry. It can be viewed as a derivative of a (hypothetical) eight-membered ring (or more simply a 'deformed' eight-membered ring) of alternating sulfur and nitrogen atoms. The pairs of sulfur atoms across the ring are separated by 2.586  Å, resulting in a cage-like structure as determine ...
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