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Cobalt(II) Phosphate
Cobalt phosphate is the inorganic compound with the formula Co3(PO4)2. It is a commercial inorganic pigment known as cobalt violet.Hugo Müller, Wolfgang Müller, Manfred Wehner, Heike Liewald "Artists' Colors" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. Thin films of this material are water oxidation catalysts. : Preparation and structure The tetrahydrate Co3(PO4)2•4H2O precipitates as a solid upon mixing aqueous solutions of cobalt(II) and phosphate salts. Upon heating, the tetrahydrate converts to the anhydrous material. According to X-ray crystallography, the anhydrous Co3(PO4)2 consists of discrete phosphate () anions that link centres. The cobalt ions occupy both octahedral (six-coordinate) and pentacoordinate sites in a 1:2 ratio. See also * List of inorganic pigments The following list includes commercially or artistically important inorganic pigments of natural and synthetic origin.. Purple pigments Aluminosilicate pigments ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pigment
A pigment is a powder used to add or alter color or change visual appearance. Pigments are completely or nearly solubility, insoluble and reactivity (chemistry), chemically unreactive in water or another medium; in contrast, dyes are colored substances which are soluble or go into solution at some stage in their use. Dyes are often organic compounds whereas pigments are often inorganic compound, inorganic. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic chemistry, inorganic, organic chemistry, organic, and special pigments were marketed worldwide. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each yea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Water Oxidation Catalyst
Water oxidation catalysis (WOC) is the acceleration (catalysis) of the conversion of water into oxygen and protons: :2 H2O → 4 H+ + 4 e− + O2 Many catalysts are effective, both homogeneous catalysts and heterogeneous catalysts. The oxygen evolving complex in photosynthesis is the premier example. There is no interest in generating oxygen by water oxidation since oxygen is readily obtained from air. Instead, interest in water oxidation is motivated by its relevance to water splitting, which would provide "solar hydrogen," i.e. water oxidation would generate the electrons and protons for the production of hydrogen. An ideal WOC would operate rapidly at low overpotential, exhibit high stability and be of low cost, derived from nontoxic components. Mechanistic and energetic principles Water is more difficult to oxidize than its conjugate base hydroxide. Hydroxide is stabilized by coordination to metal cations. Some metal hydroxides, those featuring redox-active metal centers, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt(II) Oxide
Cobalt(II) oxide is an inorganic compound that has been described as an olive-green or gray solid. It is used extensively in the ceramics industry as an additive to create blue-colored glazes and enamels, as well as in the chemical industry for producing cobalt(II) salts. A related material is cobalt(II,III) oxide, a black solid with the formula Co3O4. Structure and properties CoO crystals adopt the periclase ( rock salt) structure with a lattice constant of 4.2615 Å. It is antiferromagnetic below 289 K. Preparation Cobalt(II) oxide is prepared by oxidation of cobalt powder with air or by thermal decomposition of cobalt(II) nitrate or the carbonate. Cobalt(II,III) oxide decomposes to cobalt(II) oxide at 950 °C: :2 Co3O4 → 6 CoO + O2 It may also be prepared by precipitating the hydroxide, followed by thermal dehydration: : CoX2 + 2 KOH → Co(OH)2 + 2 KX : Co(OH)2 → CoO + H2O Reactions As can be expected, cobalt(II) oxide reacts with mineral acids to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Crystallography
X-ray crystallography is the experimental science of determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to Diffraction, diffract in specific directions. By measuring the angles and intensities of the X-ray diffraction, a crystallography, crystallographer can produce a three-dimensional picture of the density of electrons within the crystal and the positions of the atoms, as well as their chemical bonds, crystallographic disorder, and other information. X-ray crystallography has been fundamental in the development of many scientific fields. In its first decades of use, this method determined the size of atoms, the lengths and types of chemical bonds, and the atomic-scale differences between various materials, especially minerals and alloys. The method has also revealed the structure and function of many biological molecules, including vitamins, drugs, proteins and nucleic acids such as DNA. X-ray crystall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Octahedral Molecular Geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix '' octa''. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, , which is not octahedral in the mathematical sense due to the orientation of the bonds, is referred to as octahedral. The concept of octahedral coordination geometry was developed by Alfred ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
List Of Inorganic Pigments
The following list includes commercially or artistically important inorganic pigments of natural and synthetic origin.. Purple pigments Aluminosilicate pigments * Ultramarine violet (): a synthetic or naturally occurring sulfur containing silicate mineral. Copper pigments * Han purple: BaCuSi2O6. Cobalt pigments * Cobalt violet (): Co3(PO4)2. Manganese pigments * Manganese violet: NH4MnP2O7 () manganic ammonium pyrophosphate. Blue pigments Aluminosilicate pigments * Ultramarine (): a synthetic or naturally occurring sulfur containing silicate mineral - (generalized formula) * Persian blue: made by grinding up the mineral Lapis lazuli. The most important mineral component of lapis lazuli is lazurite (25% to 40%), a feldspathoid silicate mineral with the formula . Cobalt pigments *Cobalt blue (): cobalt(II) aluminate. * Cerulean blue (): cobalt(II) stannate. * Cerium uranium blue Iron pigments * Prussian blue (): a synthetic inert pigment made of iron and cyanide: C18 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phosphates
Phosphates are the naturally occurring form of the element phosphorus. In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid, phosphoric acid . The phosphate or orthophosphate ion is derived from phosphoric acid by the removal of three protons . Removal of one proton gives the dihydrogen phosphate ion while removal of two protons gives the hydrogen phosphate ion . These names are also used for salts of those anions, such as ammonium dihydrogen phosphate and trisodium phosphate. File:3-phosphoric-acid-3D-balls.png, Phosphoric acid, Phosphoricacid File:2-dihydrogenphosphate-3D-balls.png, Dihydrogen phosphate, Dihydrogenphosphate File:1-hydrogenphosphate-3D-balls.png, Monohydrogen phosphate, Hydrogenphosphate File:0-phosphate-3D-balls.png, Phosphate or orthophosphate In organic chemistry, phosphate or orthophosphate is an organophosphate, an ester ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt(II) Compounds
Cobalt is a chemical element; it has symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, somewhat brittle, gray metal. Cobalt-based blue pigments (cobalt blue) have been used since antiquity for jewelry and paints, and to impart a distinctive blue tint to glass. The color was long thought to be due to the metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue pigment-producing minerals. They were so named because they were poor in known metals and gave off poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), which was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of a number of me ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
