|
Calorimeter Constant
A calorimeter constant (denoted ''C''cal) is a constant that quantifies the heat capacity of a calorimeter. It may be calculated by applying a known amount of heat to the calorimeter and measuring the calorimeter's corresponding change in temperature. In SI units, the calorimeter constant is then calculated by dividing the change in enthalpy (Δ''H'') in joules by the change in temperature (Δ''T'') in kelvins or degrees Celsius: :C_\mathrm = \frac The calorimeter constant is usually presented in units of joules per degree Celsius (J/°C) or joules per kelvin (J/K). Every calorimeter has a unique calorimeter constant. Uses The calorimeter constants are used in constant pressure calorimetry to calculate the amount of heat required to achieve a certain raise in the temperature of the calorimeter's contents. Example To determine the change in enthalpy in a neutralization reaction (Δ''H''neutralization), a known amount of basic solution may be placed in a calorimeter, and the temp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Constant (mathematics)
In mathematics, the word constant conveys multiple meanings. As an adjective, it refers to non-variance (i.e. unchanging with respect to some other value); as a noun, it has two different meanings: * A fixed and well-defined number or other non-changing mathematical object, or the symbol denoting it. The terms '' mathematical constant'' or '' physical constant'' are sometimes used to distinguish this meaning. * A function whose value remains unchanged (i.e., a '' constant function''). Such a constant is commonly represented by a variable which does not depend on the main variable(s) in question. For example, a general quadratic function is commonly written as: :a x^2 + b x + c\, , where , and are constants ( coefficients or parameters), and a variable—a placeholder for the argument of the function being studied. A more explicit way to denote this function is :x\mapsto a x^2 + b x + c \, , which makes the function-argument status of (and by extension the constancy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Capacity
Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property. The corresponding intensive property is the specific heat capacity, found by dividing the heat capacity of an object by its mass. Dividing the heat capacity by the amount of substance in moles yields its molar heat capacity. The volumetric heat capacity measures the heat capacity per volume. In architecture and civil engineering, the heat capacity of a building is often referred to as its '' thermal mass''. Definition Basic definition The heat capacity of an object, denoted by C, is the limit C = \lim_\frac, where \Delta Q is the amount of heat that must be added to the object (of mass ''M'') in order to raise its temperature by \Delta T. The value of this parameter usually varies considerably depending o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calorimeter
A calorimeter is a device used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity. Differential scanning calorimeters, isothermal micro calorimeters, titration calorimeters and accelerated rate calorimeters are among the most common types. A simple calorimeter just consists of a thermometer attached to a metal container full of water suspended above a combustion chamber. It is one of the measurement devices used in the study of thermodynamics, chemistry, and biochemistry. To find the enthalpy change per mole of a substance A in a reaction between two substances A and B, the substances are separately added to a calorimeter and the initial and final temperatures (before the reaction has started and after it has finished) are noted. Multiplying the temperature change by the mass and specific heat capacities of the substances gives a value for the energy given off or absorbed during the reaction. Dividing the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat
In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by such mechanisms as thermal conduction, electromagnetic radiation, and friction, which are microscopic in nature, involving sub-atomic, atomic, or molecular particles, or small surface irregularities, as distinct from the macroscopic modes of energy transfer, which are thermodynamic work and transfer of matter. For a closed system (transfer of matter excluded), the heat involved in a process is the difference in internal energy between the final and initial states of a system, after subtracting the work done in the process. For a closed system, this is the formulation of the first law of thermodynamics. Calorimetry is measurement of quantity of energy transferred as heat by its effect on the states of interacting bodies, for example, by the amount of ice melted or by change in temperature of a body. In the International System of Units (SI), the unit of measurement for he ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making up a substance. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called ''centigrade''), the Fahrenheit scale (°F), and the Kelvin scale (K), with the third being used predominantly for scientific purposes. The kelvin is one of the seven base units in the International System of Units (SI). Absolute zero, i.e., zero kelvin or −273.15 °C, is the lowest point in the thermodynamic temperature scale. Experimentally, it can be approached very closely but not actually reached, as recognized in the third law of thermodynamics. It would be impossible ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enthalpy
Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work (physics), work W that was done against constant external pressure P_\text to establish the system's physical dimensions from V_\text=0 to some final volume V_\text (as W=P_\text\Delta V), i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; Bond energy, bond, Lattice energy, lattice, solvation, and other chemical "energies" are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Joule
The joule ( , or ; symbol: J) is the unit of energy in the International System of Units (SI). In terms of SI base units, one joule corresponds to one kilogram- metre squared per second squared One joule is equal to the amount of work done when a force of one newton displaces a body through a distance of one metre in the direction of that force. It is also the energy dissipated as heat when an electric current of one ampere passes through a resistance of one ohm for one second. It is named after the English physicist James Prescott Joule (1818–1889). Definition According to the International Bureau of Weights and Measures the joule is defined as "the work done when the point of application of 1 MKS unit of force ewtonmoves a distance of 1 metre in the direction of the force." In terms of SI base units and in terms of SI derived units with special names, the joule is defined as One joule is also equivalent to any of the following: * The work required to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kelvin
The kelvin (symbol: K) is the base unit for temperature in the International System of Units (SI). The Kelvin scale is an absolute temperature scale that starts at the lowest possible temperature (absolute zero), taken to be 0 K. By definition, the Celsius scale (symbol °C) and the Kelvin scale have the exact same magnitude; that is, a rise of 1 K is equal to a rise of 1 °C and vice versa, and any temperature in degrees Celsius can be converted to kelvin by adding 273.15. The 19th century British scientist Lord Kelvin first developed and proposed the scale. It was often called the "absolute Celsius" scale in the early 20th century. The kelvin was formally added to the International System of Units in 1954, defining 273.16 K to be the triple point of water. The Celsius, Fahrenheit, and Rankine scales were redefined in terms of the Kelvin scale using this definition. The 2019 revision of the SI now defines the kelvin in terms of energy by setting the Bo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calorimetry
In chemistry and thermodynamics, calorimetry () is the science or act of measuring changes in '' state variables'' of a body for the purpose of deriving the heat transfer associated with changes of its state due, for example, to chemical reactions, physical changes, or phase transitions under specified constraints. Calorimetry is performed with a calorimeter. Scottish physician and scientist Joseph Black, who was the first to recognize the distinction between heat and temperature, is said to be the founder of the science of calorimetry. Indirect calorimetry calculates heat that living organisms produce by measuring either their production of carbon dioxide and nitrogen waste (frequently ammonia in aquatic organisms, or urea in terrestrial ones), or from their consumption of oxygen. Lavoisier noted in 1780 that heat production can be predicted from oxygen consumption this way, using multiple regression. The dynamic energy budget theory explains why this procedure is corre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Neutralization Reaction
In chemistry, neutralization or neutralisation (see spelling differences) is a chemical reaction in which acid and a base react with an equivalent quantity of each other. In a reaction in water, neutralization results in there being no excess of hydrogen or hydroxide ions present in the solution. The pH of the neutralized solution depends on the acid strength of the reactants. Meaning of "neutralization" In the context of a chemical reaction the term neutralization is used for a reaction between an acid and a base or alkali. Historically, this reaction was represented as :acid + base (alkali) → salt + water : For example: :HCl + NaOH → NaCl + H2O The statement is still valid as long as it is understood that in an aqueous solution the substances involved are subject to dissociation, which changes the ionization state of the substances. The arrow sign, →, is used because the reaction is complete, that is, neutralization is a quantitative reaction. A more general def ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Base (chemistry)
In chemistry, there are three definitions in common use of the word "base": '' Arrhenius bases'', '' Brønsted bases'', and '' Lewis bases''. All definitions agree that bases are substances that react with acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...s, as originally proposed by Guillaume-François Rouelle, G.-F. Rouelle in the mid-18th century. In 1884, Svante Arrhenius proposed that a base is a substance which dissociates in aqueous solution to form hydroxide ions OH−. These ions can react with Hydron (chemistry), hydrogen ions (H+ according to Arrhenius) from the dissociation of acids to form water in an acid–base reaction. A base was therefore a metal hydroxide such as NaOH or Calcium hydroxide, Ca(OH)2. Such aqueous hydroxide solutions were also described by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acid (chemistry)
An acid is a molecule or ion capable of either donating a proton (i.e. hydrogen cation, H+), known as a Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid. The first category of acids are the proton donors, or Brønsted–Lowry acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Arrhenius acids. Brønsted and Lowry generalized the Arrhenius theory to include non-aqueous solvents. A Brønsted–Lowry or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+. Aqueous Arrhenius acids have characteristic properties that provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and react with bases and certain metals (like calcium) to form salts. The word ''acid'' is derived from the Latin , meaning 'sour'. An aqueous solution of an acid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
