Boron
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Boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the '' boron group'' it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral sodium borate, and the ultra-hard crystals of boron carbide and boron nitride. Boron is synthesized entirely by cosmic ray spallation and supernovae and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals. Elemental boron is a meta ...
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Boron Nitride
Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the chemical formula BN. It exists in various crystalline forms that are isoelectronic to a similarly structured carbon lattice. The hexagonal form corresponding to graphite is the most stable and soft among BN polymorphs, and is therefore used as a lubricant and an additive to cosmetic products. The cubic ( zincblende aka sphalerite structure) variety analogous to diamond is called c-BN; it is softer than diamond, but its thermal and chemical stability is superior. The rare wurtzite BN modification is similar to lonsdaleite but slightly softer than the cubic form. Because of excellent thermal and chemical stability, boron nitride ceramics are used in high-temperature equipment and metal casting. Boron nitride has potential use in nanotechnology. Structure Boron nitride exists in multiple forms that differ in the arrangement of the boron and nitrogen atoms, giving rise to ...
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Metalloid
A metalloid is a type of chemical element which has a preponderance of material property, properties in between, or that are a mixture of, those of metals and nonmetals. There is no standard definition of a metalloid and no complete agreement on which elements are metalloids. Despite the lack of specificity, the term remains in use in the literature of chemistry. The six commonly recognised metalloids are boron, silicon, germanium, arsenic, antimony, and tellurium. Five elements are less frequently so classified: carbon, aluminium, selenium, polonium, and astatine. On a standard periodic table, all eleven elements are in a diagonal region of the p-block extending from boron at the upper left to astatine at lower right. Some periodic tables include a dividing line between metals and nonmetals, and the metalloids may be found close to this line. Typical metalloids have a metallic appearance, but they are brittle and only fair electrical conductor, conductors of electricity. Chemica ...
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Boron Carbide
Boron carbide (chemical formula approximately B4C) is an extremely hard boron–carbon ceramic, a covalent material used in tank armor, bulletproof vests, engine sabotage powders, as well as numerous industrial applications. With a Vickers hardness of >30 GPa, it is one of the hardest known materials, behind cubic boron nitride and diamond. History Boron carbide was discovered in the 19th century as a by-product of reactions involving metal borides, but its chemical formula was unknown. It was not until the 1930s that the chemical composition was estimated as B4C. Controversy remained as to whether or not the material had this exact 4:1 stoichiometry, as, in practice the material is always slightly carbon-deficient with regard to this formula, and X-ray crystallography shows that its structure is highly complex, with a mixture of C-B-C chains and B12 icosahedra. These features argued against a very simple exact B4C empirical formula. Because of the B12 structural unit, th ...
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Boron Group
The boron group are the chemical elements in group 13 of the periodic table, comprising boron (B), aluminium (Al), gallium (Ga), indium (In), thallium (Tl), and nihonium (Nh). The elements in the boron group are characterized by having three valence electrons. These elements have also been referred to as the triels. Boron is commonly classified as a (metalloid) while the rest, with the possible exception of nihonium, are considered post-transition metals. Boron occurs sparsely, probably because bombardment by the subatomic particles produced from natural radioactivity disrupts its nuclei. Aluminium occurs widely on earth, and indeed is the third most abundant element in the Earth's crust (8.3%). Gallium is found in the earth with an abundance of 13 ppm. Indium is the 61st most abundant element in the earth's crust, and thallium is found in moderate amounts throughout the planet. Nihonium is not known to occur in nature and therefore is termed a synthetic element. Several gro ...
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Allotropes Of Boron
Boron can be prepared in several crystalline and amorphous forms. Well known crystalline forms are α-rhombohedral (α-R), β-rhombohedral (β-R), and β-tetragonal (β-T). In special circumstances, boron can also be synthesized in the form of its α-tetragonal (α-T) and γ-orthorhombic (γ) allotropes. Two amorphous forms, one a finely divided powder and the other a glassy solid, are also known. Although at least 14 more allotropes have been reported, these other forms are based on tenuous evidence or have not been experimentally confirmed, or are thought to represent mixed allotropes, or boron frameworks stabilized by impurities. Whereas the β-rhombohedral phase is the most stable and the others are metastable, the transformation rate is negligible at room temperature, and thus all five phases can exist at ambient conditions. Amorphous powder boron and polycrystalline β-rhombohedral boron are the most common forms. The latter allotrope is a very hard Vickers hardness compa ...
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Boron Fiber
Boron Fiber (also commonly called boron filament) is an amorphous elemental boron product which represents the major industrial use of elemental (free) boron. Boron fiber manifests a combination of high strength and high elastic modulus. A common use of boron fibers is in the construction of high tensile strength tapes. Boron fiber use results in high-strength, lightweight materials that are used chiefly for advanced aerospace structures as a component of composite materials, as well as limited production consumer and sporting goods such as golf clubs and fishing rods. One of the uses of boron fiber composites was the horizontal tail surfaces of the F-14 Tomcat fighter. This was done because carbon fiber composites were not then developed to the point they could be used, as they were in many subsequent aircraft designs. In the production process, elemental boron is deposited on an even tungsten wire substrate which produces diameters of 4.0 mil (102 micron) and 5.6 mil (14 ...
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Borax
Borax is a salt (chemistry), salt (ionic compound), a hydration (chemistry), hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a base (chemistry), basic aqueous solution, solution. It is commonly available in powder or granular form, and has many industrial and household uses, including as a pesticide, as a metal soldering flux (metallurgy), flux, as a component of glass, Enamelled glass, enamel, and glaze (pottery), pottery glazes, for tanning (leather), tanning of skins and hide (skin), hides, for artificial aging of wood, as a preservative against wood fungus, and as a pharmaceutic alkalizer. In chemical laboratories, it is used as a buffer solution, buffering agent. The compound is often called sodium tetraborate decahydrate, but that name is not consistent with its structure. The anion is not tetraborate but tetraborate, tetrahydroxy tetraborate , so the more correct formula should be ...
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Boric Acid
Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula . It may also be called hydrogen borate or boracic acid. It is usually encountered as colorless crystals or a white powder, that dissolves in water, and occurs in nature as the mineral sassolite. It is a weak acid that yields various borate anions and salts, and can react with alcohols to form borate esters. Boric acid is often used as an antiseptic, insecticide, flame retardant, neutron absorber, or precursor to other boron compounds. The term "boric acid" is also used generically for any oxoacid of boron, such as metaboric acid and tetraboric acid . History Orthoboric acid was first prepared by Wilhelm Homberg (1652–1715) from borax, by the action of mineral acids, and was given the name ("sedative salt of Homberg"). However boric acid and borates have been used since the time of the ancient Greeks for cleaning, preserving food, and other activities. ...
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Chemical Symbol
Chemical symbols are the abbreviations used in chemistry for chemical elements, functional groups and chemical compounds. Element symbols for chemical elements normally consist of one or two letters from the Latin alphabet and are written with the first letter capitalised. History Earlier symbols for chemical elements stem from classical Latin and Greek vocabulary. For some elements, this is because the material was known in ancient times, while for others, the name is a more recent invention. For example, Pb is the symbol for lead (''plumbum'' in Latin); Hg is the symbol for mercury (''hydrargyrum'' in Greek); and He is the symbol for helium (a new Latin name) because helium was not known in ancient Roman times. Some symbols come from other sources, like W for tungsten (''Wolfram'' in German) which was not known in Roman times. A three-letter temporary symbol may be assigned to a newly synthesized (or not yet synthesized) element. For example, "Uno" was the temporary symbol f ...
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Kernite
Kernite, also known as rasorite, is a hydrated sodium borate hydroxide mineral with formula . It is a colorless to white mineral crystallizing in the monoclinic crystal system typically occurring as prismatic to acicular crystals or granular masses. It is relatively soft with Mohs hardness of 2.5 to 3 and light with a specific gravity of 1.91. It exhibits perfect cleavage and a brittle fracture. Kernite is soluble in cold water and alters to tincalconite when it dehydrates. It undergoes a non-reversible alteration to metakernite () when heated to above 100 °C. Occurrence and history The mineral occurs in sedimentary evaporite deposits in arid regions. Kernite was discovered in 1926 in eastern Kern County, in Southern California, and later renamed after the county. The location was the US Borax Mine at Boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its a ...
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Cosmic Ray Spallation
Cosmic ray spallation, also known as the x-process, is a set of naturally occurring nuclear reactions causing nucleosynthesis; it refers to the formation of chemical elements from the impact of cosmic rays on an object. Cosmic rays are highly energetic charged particles from beyond Earth, ranging from protons, alpha particles, and nuclei of many heavier elements. About 1% of cosmic rays also consist of free electrons. Cosmic rays cause spallation when a ray particle (e.g. a proton) impacts with matter, including other cosmic rays. The result of the collision is the expulsion of particles (protons, neutrons, and alpha particles) from the object hit. This process goes on not only in deep space, but in Earth's upper atmosphere and crustal surface (typically the upper ten meters) due to the ongoing impact of cosmic rays. The process Cosmic ray spallation is thought to be responsible for the abundance in the universe of some light elements—lithium, beryllium, and boron—as wel ...
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Meteoroid
A meteoroid () is a small rocky or metallic body in outer space. Meteoroids are defined as objects significantly smaller than asteroids, ranging in size from grains to objects up to a meter wide. Objects smaller than this are classified as micrometeoroids or space dust. Most are fragments from comets or asteroids, whereas others are collision impact debris ejected from bodies such as the Moon or Mars. When a meteoroid, comet, or asteroid enters Earth's atmosphere at a speed typically in excess of , aerodynamic heating of that object produces a streak of light, both from the glowing object and the trail of glowing particles that it leaves in its wake. This phenomenon is called a meteor or "shooting star". Meteors typically become visible when they are about 100 km above sea level. A series of many meteors appearing seconds or minutes apart and appearing to originate from the same fixed point in the sky is called a meteor shower. A meteorite is the remains of a meteoroid ...
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