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Bromocyclopropane
Bromocyclopropane is a organobromine compound with the chemical formula . It is a member of haloalkane family. Synthesis The compound can be obtained by treating silver cyclopropanecarboxylate with bromine: : Chemical properties Reaction with magnesium, using diethyl ether as solvent, only gives about 25–30% of the cyclopropylmagnesium bromide Grignard reagent, with nearly as much cyclopropane formed by alternate reactions on the metal surface. The compound isomerizes on heating to produce 1-bromopropene and 3-bromopropene. Physical properties The compound is a flammable liquid that causes skin irritation and serious eye irritation. It is soluble in chloroform and methanol. Insoluble in water. See also * Bromoalkanes * Bromocyclohexane References {{Bromine compounds Cyclopropyl compounds Organobromides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chlorocyclopropane
Chlorocyclopropane is a organochlorine compound with the chemical formula . The compound is a member of haloalkane family. Synthesis The compound can be obtained by photoreaction of cyclopropane and chlorine gas; the reaction will generate polychlorinated compounds, which can be separated by physical means. Chemical properties The compound isomerizes on heating to 3-Chloropropene. Chlorocyclopropane reacts with lithium Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ... metal in ether to produce bicyclopropane. Also, it reacts with magnesium to obtain cyclopropylmagnesium chloride. See also * Chloroalkanes References {{Chlorine compounds Cyclopropyl compounds Organochlorides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorocyclopropane
Fluorocyclopropane is an organofluorine compound with the chemical formula . The compound is a member of haloalkane family. Synthesis The compound can be produced by reacting imidazolylidene cyclopropyl group with xenon difluoride. Also, a reaction of enantioselective cyclopropanation of fluoro-substituted allylic alcohols using zinc carbenoids. See also * Fluoroalkane Organofluorine chemistry describes the chemistry of organofluorine compounds, organic compounds that contain a carbon–fluorine bond. Organofluorine compounds find diverse applications ranging from oil and water repellents to pharmaceuticals, ...s * Fluorocyclohexane References Extra reading * * {{Fluorine compounds Cyclopropyl compounds Fluorine compounds Organofluorides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodocyclopropane
Iodocyclopropane is a organoiodine compound with the chemical formula . The compound is a member of haloalkane family. Chemical properties The compound reacts with benzoxazole to produce 2-cyclopropylbenzoxazole in presence of palladium catalyst. Uses Iodocyclopropanes are used as synthetic intermediates to synthesize many alkyl, aryl, and acyl substituted cyclopropanes via organometallic Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and so ... reactions. See also * Iodoalkanes References {{Iodine compounds Cyclopropyl compounds Iodine compounds Organoiodides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromocyclohexane
Bromocyclohexane (also called cyclohexyl bromide, abbreviated CXB) is an organic compound with the chemical formula . Uses and reactions It is used to match the refractive index of PMMA for example in confocal microscopy of colloids. A mixture of ''cis''-decalin and CXB can simultaneously match optical index and density of PMMA. Due to the moderate dielectric constant of CXB (ε = 7.9 ), PMMA acquires charges that can be screened by the addition of salt (e.g. tetrabutyl ammonium bromide), leading to a very good approximation of colloidal hard sphere. A drawback is that CXB is a good solvent for PMMA, causing it to swell over time, which may lead to a poor determination of particle radii and determination of solid volume fraction. It is a standard coupling partner of cross coupling reactions. Similarly, cyclohexyl bromide is a standard alkylating agent. Stated applications in drug chemistry include the synthesis of gamfexine, drofenine, trihexyphenidyl, procyclidine, feclem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromoalkane
Organobromine chemistry is the study of the synthesis and properties of organobromine compounds, also called organobromides, which are organic compounds that contain carbon bonded to bromine. The most pervasive is the naturally produced bromomethane. One prominent application of synthetic organobromine compounds is the use of polybrominated diphenyl ethers as fire-retardants, and in fact fire-retardant manufacture is currently the major industrial use of the element bromine. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. General properties Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. Bromine is more electronegative than carbon (2.9 vs 2.5). Consequently, the carbon in a carbon–bromine bond is electrophilic, i.e. alkyl bromides are alkylating agents. Carbon–halogen b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alfa Aesar
Alfa Aesar was a supplier of reagents and materials for use in research and development, and analysis. The company had facilities in a variety of countries and manufactured many of the chemicals they sold. The company was bought by Thermo Fisher Scientific in 2015, having previously existed as part of the Johnson Matthey Fine Chemicals & Catalysts Division. In 2021, Alfa Aesar products were rebranded under the Thermo Scientific brand name. History Alfa Aesar was formed from a series of company mergers: * Alfa Inorganics was founded in 1962 by Alfred Bader, in a 50:50 venture between Aldrich Chemicals and Metal Hydrides Inc. The purpose was to provide a source of inorganic research chemicals to sit alongside the organic chemicals of Bader's other company: Aldrich Chemicals. It was created to market inorganics, organometallics, and others such as organoboron and organoarsenic reagents. Following the amalgamation of Aldrich and the Sigma Chemical Co, the joint venture was termi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Water
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food energy or organic micronutrients. Its chemical formula, , indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. In liquid form, is also called "water" at standard temperature and pressure. Because Earth's environment is relatively close to water's triple point, water exists on Earth as a solid, a liquid, and a gas. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methanol
Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical compound and the simplest aliphatic Alcohol (chemistry), alcohol, with the chemical formula (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a light, Volatility (chemistry), volatile, colorless and flammable liquid with a distinctive alcoholic odor similar to that of ethanol (potable alcohol), but is more acutely toxic than the latter. Methanol acquired the name wood alcohol because it was once produced through destructive distillation of wood. Today, methanol is mainly produced industrially by hydrogenation of carbon monoxide. Methanol consists of a methyl group linked to a polar hydroxyl group. With more than 20 million tons produced annually, it is used as a Precursor (chemistry), precursor to other commodity chemicals, including formaldehyde, acetic acid, methyl tert-butyl ether, methyl ''tert''-butyl ether, methyl benzoate, anisole, peroxyacids, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloroform
Chloroform, or trichloromethane (often abbreviated as TCM), is an organochloride with the formula and a common solvent. It is a volatile, colorless, sweet-smelling, dense liquid produced on a large scale as a precursor to refrigerants and polytetrafluoroethylene (PTFE). Chloroform was once used as an inhalational anesthetic between the 19th century and the first half of the 20th century. It is miscible with many solvents but it is only very slightly soluble in water (only 8 g/L at 20°C). Structure and name The molecule adopts a tetrahedral molecular geometry with C3v symmetry. The chloroform molecule can be viewed as a methane molecule with three hydrogen atoms replaced with three chlorine atoms, leaving a single hydrogen atom. The name "chloroform" is a portmanteau of ''terchloride'' (tertiary chloride, a trichloride) and ''formyle'', an obsolete name for the methylylidene radical (CH) derived from formic acid. Natural occurrence Many kinds of seaweed produce chlor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Communications
''ChemComm'' (or ''Chemical Communications''), formerly known as ''Journal of the Chemical Society D: Chemical Communications'' (1969–1971), ''Journal of the Chemical Society, Chemical Communications'' (1972–1995), is a peer-reviewed scientific journal published by the Royal Society of Chemistry. It covers all aspects of chemistry. In January 2012, the journal moved to publishing 100 issues per year. The current chair of the editorial board is Douglas Stephan (University of Toronto, Canada), while the executive editor is Richard Kelly. Abstracting and indexing The journal is abstracted and indexed in: * Chemical Abstracts * Science Citation Index * Current Contents/Physical, Chemical & Earth Sciences * Scopus * Index Medicus/MEDLINE/PubMed According to the ''Journal Citation Reports'', the journal has a 2023 impact factor of 4.3. See also * '' New Journal of Chemistry'' * ''Chemical Society Reviews ''Chemical Society Reviews'' is a biweekly peer-reviewed scientific journa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclopropane
Cyclopropane is the cycloalkane with the molecular formula (CH2)3, consisting of three methylene groups (CH2) linked to each other to form a triangular ring. The small size of the ring creates substantial ring strain in the structure. Cyclopropane itself is mainly of theoretical interest but many of its derivatives - cyclopropanes - are of commercial or biological significance. Cyclopropane was used as a clinical inhalational anesthetic from the 1930s through the 1980s. The substance's high flammability poses a risk of fire and explosions in operating rooms due to its tendency to accumulate in confined spaces, as its density is higher than that of air. History Cyclopropane was discovered in 1881 by August Freund, who also proposed the correct structure for the substance in his first paper. Freund treated 1,3-Dibromopropane, 1,3-dibromopropane with sodium, causing an intramolecular Wurtz reaction leading directly to cyclopropane. The yield of the reaction was improved by Gustavson ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
3-bromopropene
Allyl bromide (3-bromopropene) is an organic halide. It is an alkylating agent used in synthesis of polymers, pharmaceuticals, perfumes and other organic compounds. Allyl bromide is a colorless liquid, although commercial samples appear yellow or brown. It is an irritant and a potentially dangerous alkylating agent. Allyl bromide is more reactive but more expensive than allyl chloride, and these considerations guide its use. Preparation Hydrohalogenation Allyl bromide is produced commercially from allyl alcohol and hydrobromic acid: :CH2=CHCH2OH + HBr → CH2=CHCH2Br + H2O It can also be prepared by the halogen-exchange reaction between allyl chloride and hydrobromic acid or by the allylic bromination of propene. Reactions and uses Allyl bromide is an electrophilic alkylating agent. It reacts with nucleophiles, such as amines, carbanions, alkoxides, etc., to introduce the allyl group: :CH2=CHCH2Br + Nu− → CH2=CHCH2Nu + Br− (Nu− is a nucleophile) It is used in th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
