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Boron Carbides
Boron carbides are boron–carbon compounds. Boron carbide (B4C) B13C2 α-tetragonal boron α-tetragonal boron is a boron-rich isotropic boron carbide (B50C2). Borafullerenes Borafullerenes are a class of heterofullerenes in which the element substituting for carbon is boron. See also * Crystal structure of boron-rich metal borides Metals, and specifically rare-earth elements, form numerous chemical complexes with boron. Their crystal structure and chemical bonding depend strongly on the metal element M and on its atomic ratio to boron. When B/M ratio exceeds 12, boron atom ... References Sources * * * * {{boron compounds Inorganic carbon compounds Boron compounds ...
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Boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the '' boron group'' it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral sodium borate, and the ultra-hard crystals of boron carbide and boron nitride. Boron is synthesized entirely by cosmic ray spallation and supernovae and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals. Elemental boron is a meta ...
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Carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three isotopes occur naturally, C and C being stable, while C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity. Carbon is the 15th most abundant element in the Earth's crust, and the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. Carbon's abundance, its unique diversity of organic compounds, and its unusual ability to form polymers at the temperatures commonly encountered on Earth, enables this element to serve as a common element of Carbon-based life, all known life. It is the second most abundant element in the human body by mass (about 18.5%) after oxygen. Th ...
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Borafullerene
Borafullerenes are a class of heterofullerenes in which the element substituting for carbon is boron. They are also a member of the boron carbides Boron carbides are boron–carbon compounds. Boron carbide (B4C) B13C2 α-tetragonal boron α-tetragonal boron is a boron-rich isotropic boron carbide (B50C2). Borafullerenes Borafullerenes are a class of heterofullerenes in which the elem ... class of materials that include Tetrabor (B4C). References Fullerenes {{chemistry-stub ...
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Heterofullerene
Heterofullerenes are classes of fullerenes, at least one carbon atom is replaced by another element. Based on spectroscopy, substitutions have been reported with boron ( borafullerenes), nitrogen (azafullerenes), oxygen, arsenic, germanium, phosphorus, silicon, iron, copper, nickel, rhodium and iridium Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of .... Reports on isolated heterofullerenes are limited to those based on nitrogen and oxygen. References Fullerenes {{Chemistry-stub ...
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Crystal Structure Of Boron-rich Metal Borides
Metals, and specifically rare-earth elements, form numerous chemical complexes with boron. Their crystal structure and chemical bonding depend strongly on the metal element M and on its atomic ratio to boron. When B/M ratio exceeds 12, boron atoms form B12 icosahedra which are linked into a three-dimensional boron framework, and the metal atoms reside in the voids of this framework. Those icosahedra are basic structural units of most allotropes of boron and boron-rich rare-earth borides. In such borides, metal atoms donate electrons to the boron polyhedra, and thus these compounds are regarded as electron-deficient solids. The crystal structures of many boron-rich borides can be attributed to certain types including MgAlB14, YB66, REB41Si1.2, B4C and other, more complex types such as RExB12C0.33Si3.0. Some of these formulas, for example B4C, YB66 and MgAlB14, historically reflect the idealistic structures, whereas the experimentally determined composition is nonstoichiometric ...
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Inorganic Carbon Compounds
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of moder ...
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