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BTPS
In thermodynamics, the volume of a system is an important extensive parameter for describing its thermodynamic state. The ''specific volume'', an intensive property, is the system's volume per unit mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature. For example, volume is related to the pressure and temperature of an ideal gas by the ideal gas law. The physical region covered by a system may or may not coincide with a ''control volume'' used to analyze the system. Overview The volume of a thermodynamic system typically refers to the volume of the working fluid, such as, for example, the fluid within a piston. Changes to this volume may be made through an application of work, or may be used to produce work. An isochoric process however operates at a constant-volume, thus no work can be produced. Many other thermodynamic processes will result in a change in volume. A polytropic process, in particular, c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metre
The metre (or meter in US spelling; symbol: m) is the base unit of length in the International System of Units (SI). Since 2019, the metre has been defined as the length of the path travelled by light in vacuum during a time interval of of a second, where the second is defined by a hyperfine transition frequency of caesium. The metre was originally defined in 1791 by the French National Assembly as one ten-millionth of the distance from the equator to the North Pole along a great circle, so the Earth's polar circumference is approximately . In 1799, the metre was redefined in terms of a prototype metre bar. The bar used was changed in 1889, and in 1960 the metre was redefined in terms of a certain number of wavelengths of a certain emission line of krypton-86. The current definition was adopted in 1983 and modified slightly in 2002 to clarify that the metre is a measure of proper length. From 1983 until 2019, the metre was formally defined as the length of the pat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isochoric Process
In thermodynamics, an isochoric process, also called a constant-volume process, an isovolumetric process, or an isometric process, is a thermodynamic process during which the volume of the closed system undergoing such a process remains constant. An isochoric process is exemplified by the heating or the cooling of the contents of a sealed, inelastic container: The thermodynamic process is the addition or removal of heat; the isolation of the contents of the container establishes the closed system; and the inability of the container to deform imposes the constant-volume condition. Formalism An isochoric thermodynamic quasi-static process is characterized by constant volume, i.e., .Ansermet, J.-P., Brechet, S.D. (2019). ''Principles of Thermodynamics'', Cambridge University Press, Cambridge UK, p. 113. The process does no pressure-volume work, since such work is defined by W = P \Delta V , where is pressure. The sign convention is such that positive work is performed by the sy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Internal Energy
The internal energy of a thermodynamic system is the energy of the system as a state function, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities as magnetization. It excludes the kinetic energy of motion of the system as a whole and the potential energy of position of the system as a whole, with respect to its surroundings and external force fields. It includes the thermal energy, ''i.e.'', the constituent particles' kinetic energies of motion relative to the motion of the system as a whole. Without a thermodynamic process, the internal energy of an isolated system cannot change, as expressed in the law of conservation of energy, a foundation of the first law of thermodynamics. The notion has been introduced to describe the systems characterized by temperature variations, te ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enthalpy
Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work (physics), work W that was done against constant external pressure P_\text to establish the system's physical dimensions from V_\text=0 to some final volume V_\text (as W=P_\text\Delta V), i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; Bond energy, bond, Lattice energy, lattice, solvation, and other chemical "energies" are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conjugate Variables (thermodynamics)
In thermodynamics, the internal energy of a system is expressed in terms of pairs of conjugate variables such as temperature and entropy, pressure and volume, or chemical potential and particle number. In fact, all thermodynamic potentials are expressed in terms of conjugate pairs. The product of two quantities that are conjugate has units of energy or sometimes power. For a mechanical system, a small increment of energy is the product of a force times a small displacement. A similar situation exists in thermodynamics. An increment in the energy of a thermodynamic system can be expressed as the sum of the products of certain generalized "forces" that, when unbalanced, cause certain generalized "displacements", and the product of the two is the energy transferred as a result. These forces and their associated displacements are called ''conjugate variables''. The thermodynamic force is always an intensive variable and the displacement is always an extensive variable, yiel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Foot (unit)
The foot (standard symbol: ft) is a Units of measurement, unit of length in the imperial units, British imperial and United States customary units, United States customary systems of metrology, measurement. The prime (symbol), prime symbol, , is commonly used to represent the foot. In both customary and imperial units, one foot comprises 12 inches, and one yard comprises three feet. Since international yard and pound, an international agreement in 1959, the foot is defined as equal to exactly 0.3048 meters. Historically, the "foot" was a part of many local systems of units, including the Ancient Greek units of measurement, Greek, Ancient Roman units of measurement, Roman, Chinese units of measurement, Chinese, Units of measurement in France before the French Revolution, French, and English units, English systems. It varied in length from country to country, from city to city, and sometimes from trade to trade. Its length was usually between 250 mm and 335 mm and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Liter
The litre ( Commonwealth spelling) or liter ( American spelling) (SI symbols L and l, other symbol used: ℓ) is a metric unit of volume. It is equal to 1 cubic decimetre (dm3), 1000 cubic centimetres (cm3) or 0.001 cubic metres (m3). A cubic decimetre (or litre) occupies a volume of (see figure) and is thus equal to one-thousandth of a cubic metre. The original French metric system used the litre as a base unit. The word ''litre'' is derived from an older French unit, the '' litron'', whose name came from Byzantine Greek—where it was a unit of weight, not volume—via Late Medieval Latin, and which equalled approximately 0.831 litres. The litre was also used in several subsequent versions of the metric system and is accepted for use with the SI, despite it not being an SI unit. The SI unit of volume is the cubic metre (m3). The spelling used by the International Bureau of Weights and Measures is "litre", [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Meter
The metre (or meter in US spelling; symbol: m) is the base unit of length in the International System of Units (SI). Since 2019, the metre has been defined as the length of the path travelled by light in vacuum during a time interval of of a second, where the second is defined by a hyperfine transition frequency of caesium. The metre was originally defined in 1791 by the French National Assembly as one ten-millionth of the distance from the equator to the North Pole along a great circle, so the Earth's polar circumference is approximately . In 1799, the metre was redefined in terms of a prototype metre bar. The bar used was changed in 1889, and in 1960 the metre was redefined in terms of a certain number of wavelengths of a certain emission line of krypton-86. The current definition was adopted in 1983 and modified slightly in 2002 to clarify that the metre is a measure of proper length. From 1983 until 2019, the metre was formally defined as the length of the path t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
States Of Matter
In physics, a state of matter is one of the distinct forms in which matter can exist. Four states of matter are observable in everyday life: solid, liquid, gas, and plasma. Different states are distinguished by the ways the component particles (atoms, molecules, ions and electrons) are arranged, and how they behave collectively. In a solid, the particles are tightly packed and held in fixed positions, giving the material a definite shape and volume. In a liquid, the particles remain close together but can move past one another, allowing the substance to maintain a fixed volume while adapting to the shape of its container. In a gas, the particles are far apart and move freely, allowing the substance to expand and fill both the shape and volume of its container. Plasma is similar to a gas, but it also contains charged particles (ions and free electrons) that move independently and respond to electric and magnetic fields. Beyond the classical states of matter, a wide variety o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vapor-compression Refrigeration
Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles. It is also used in domestic and commercial refrigerators, large-scale warehouses for chilled or frozen storage of foods and meats, refrigerated trucks and railroad cars, and a host of other commercial and industrial services. Oil refineries, petrochemical and chemical processing plants, and natural gas processing plants are among the many types of industrial plants that often utilize large vapor-compression refrigeration systems. Cascade refrigeration systems may also be implemented using two compressors. Refrigeration may be defined as lowering the temperature of an enclosed space by removing heat from that space and transferring it elsewhere. A device that performs this function may also be called an air conditioner, ref ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Cycle
A thermodynamic cycle consists of linked sequences of thermodynamic processes that involve heat transfer, transfer of heat and work (physics), work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the thermodynamic system, system to its initial state. In the process of passing through a cycle, the working fluid (system) may convert heat from a warm source into useful work, and dispose of the remaining heat to a cold sink, thereby acting as a heat engine. Conversely, the cycle may be reversed and use work to move heat from a cold source and transfer it to a warm sink thereby acting as a heat pump. If at every point in the cycle the system is in thermodynamic equilibrium, the cycle is reversible. Whether carried out reversible or irreversibly, the net entropy change of the system is zero, as entropy is a state function. During a closed cycle, the system returns to its original thermodynamic stat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Expansion
Thermal expansion is the tendency of matter to increase in length, area, or volume, changing its size and density, in response to an increase in temperature (usually excluding phase transitions). Substances usually contract with decreasing temperature (thermal contraction), with rare exceptions within limited temperature ranges ('' negative thermal expansion''). Temperature is a monotonic function of the average molecular kinetic energy of a substance. As energy in particles increases, they start moving faster and faster, weakening the intermolecular forces between them and therefore expanding the substance. When a substance is heated, molecules begin to vibrate and move more, usually creating more distance between themselves. The relative expansion (also called strain) divided by the change in temperature is called the material's coefficient of linear thermal expansion and generally varies with temperature. Prediction If an equation of state is available, it can be used t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
