Ammonium Magnesium Sulfate
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Ammonium Magnesium Sulfate
Ammonium magnesium sulfate is a chemical compound with the chemical formula . It forms hydrates. Synthesis The compound is prepared by reduction of ammonium persulfate with magnesium metal. Physical properties Ammonium magnesium sulfate forms crystals, soluble in water. The compound forms a crystallohydrate containing —colorless crystals of monoclinic system, space group ''P''21''/c'', coordinate parameters ''a'' = 0.928 nm, ''b'' = 1.257 nm, ''c'' = 0.620 nm, ''β'' = 107.1°, Z = 4. Natural occurrence Ammonium magnesium sulfate hexahydrate naturally occurs as Boussingaultite, a rare mineral of picromerite group, originally described from geothermal fields in Tuscany, Italy Tuscany ( ; ) is a Regions of Italy, region in central Italy with an area of about and a population of 3,660,834 inhabitants as of 2025. The capital city is Florence. Tuscany is known for its landscapes, history, artistic legacy, and its in ..., where it occurs together with its iron analogue m ...
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Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken or new bonds formed or both. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, usin ...
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Ammonium Persulfate
Ammonium persulfate (APS) is the inorganic compound with the formula (NH4)2S2O8. It is a colourless (white) salt that is highly soluble in water, much more so than the related potassium salt. It is a strong oxidizing agent that is used as a catalyst in polymer chemistry, as an etchant, and as a cleaning and bleaching agent. Preparation and structure Ammonium persulfate is prepared by electrolysis of a cold concentrated solution of either ammonium sulfate or ammonium bisulfate in sulfuric acid at a high current density.F. Feher, "Potassium Peroxydisulfate" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 390. The method was first described by Hugh Marshall. The ammonium, sodium, and potassium salts adopt very similar structures in the solid state, according to X-ray crystallography. In the ammonium salt, the O-O distance is 1.497Å. The sulfate groups are tetrahedral, with three short S-O distances near 1.44 ...
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CRC Press
The CRC Press, LLC is an American publishing group that specializes in producing technical books. Many of their books relate to engineering, science and mathematics. Their scope also includes books on business, forensics and information technology. CRC Press is now a division of Taylor & Francis, itself a subsidiary of Informa. History The CRC Press was founded as the Chemical Rubber Company (CRC) in 1903 by brothers Arthur, Leo and Emanuel Friedman in Cleveland, Ohio, based on an earlier enterprise by Arthur, who had begun selling rubber laboratory aprons in 1900. The company gradually expanded to include sales of laboratory equipment to chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...s. In 1913 the CRC offered a short (116-page) manual called the ''Rubber Handboo ...
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Butterworth-Heinemann
Butterworth–Heinemann is a British publishing company specialised in professional information and learning materials for higher education and professional training, in printed and electronic forms. It was formed in 1990 by the merger of Heinemann Professional Publishing and Butterworths Scientific, both subsidiaries of Reed International. With its earlier constituent companies, the founding dates back to 1923. It has publishing units in Oxford (UK) and Waltham, Massachusetts (United States). As of 2006, it is an imprint of Elsevier. See also *LexisNexis Butterworths LexisNexis is an American data analytics company headquartered in New York, New York. Its products are various databases that are accessed through online portals, including portals for computer-assisted legal research (CALR), newspaper search, ... References External links * Book publishing companies of the United Kingdom Elsevier imprints {{publish-corp-stub ...
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Monoclinic System
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below organizes the spa ...
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The Journal Of Chemical Thermodynamics
''The Journal of Chemical Thermodynamics'' is a monthly peer-reviewed scientific journal covering experimental thermodynamics and thermophysics including bio-thermodynamics, calorimetry, phase equilibria, equilibrium thermodynamic properties and transport properties. It is published by Elsevier. The editors-in-chief are W.E. Acree Jr., N. Kishore, B. F. Woodfield. Abstracting and indexing The journal is abstracted and indexed in Chemical Abstracts, Chemistry Citation Index, Current Contents/Physics, Chemical, & Earth Sciences, Engineered Materials Abstracts, Physics Abstracts, Reaction Citation Index, Science Citation Index, and Scopus Scopus is a scientific abstract and citation database, launched by the academic publisher Elsevier as a competitor to older Web of Science in 2004. The ensuing competition between the two databases has been characterized as "intense" and is c .... External links * {{DEFAULTSORT:Journal Of Thermodynamics, The Monthly journals Elsevie ...
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Boussingaultite
Boussingaultite is a rare ammonium magnesium hydrated sulfate mineral of the chemical formula: (NH4)2Mg(SO4)2 · 6 H2O. The formula of boussingaultite is that of Tutton's salts type. It was originally described from geothermal fields in Tuscany, Italy, where it occurs together with its iron analogue mohrite, but is more commonly found on burning coal dumps. The mineral possess monoclinic symmetry and forms clear, often rounded crystals. The mineral is named after the French chemist Jean-Baptiste Boussingault Jean-Baptiste Joseph Dieudonné Boussingault (2 February 1801 – 11 May 1887) was a French chemist who made significant contributions to agricultural science, petroleum science and metallurgy. Biography Jean-Baptiste Boussingault – an agric ... (1802–1887). See also * Mohr's salt * Mohrite References Ammonium minerals Magnesium minerals Sulfate minerals Hexahydrate minerals Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub ...
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Picromerite
Picromerite (synonyms: schoenite, schönite) is a mineral from the class of hydrous Sulfate minerals, sulfates lacking additional anions, and containing medium to large cations according to the Nickel–Strunz classification. Etymology The name comes from the Greek words πικρός [pikros] for "bitter" and μέρος [meros] for "part", and relates to the bitter taste of the mineral. Occurrence Picromerite is found on comparatively few places, currently (2015) only about 40 localities are known. It was first identified in active volcanic fumaroles on Mount Vesuvius by Arcangelo Scacchi in 1855 and has also been found in volcanic deposits on Mount Etna and on Hawaii (island), Hawai'i. It is more commonly found in the kainite zones of some marine salt deposits, among them salt mines in Thuringia, Lower Saxony and Saxony-Anhalt (Germany), near Hall in Tirol, Hallstatt and Bad Ischl (Austria), near Whitby (UK), and in the Carlsbad Potash District (New Mexico), also on salt la ...
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Tuscany, Italy
Tuscany ( ; ) is a Regions of Italy, region in central Italy with an area of about and a population of 3,660,834 inhabitants as of 2025. The capital city is Florence. Tuscany is known for its landscapes, history, artistic legacy, and its influence on high culture. It is regarded as the birthplace of the Italian Renaissance and of the foundations of the Italian language. The prestige established by the Tuscan dialect's use in literature by Dante Alighieri, Petrarch, Giovanni Boccaccio, Niccolò Machiavelli and Francesco Guicciardini led to its subsequent elaboration as the language of culture throughout Italy. It has been home to many figures influential in the history of art and science, and contains well-known museums such as the Uffizi and the Palazzo Pitti. Tuscany is also known for its wines, including Chianti, Vino Nobile di Montepulciano, Morellino di Scansano, Brunello di Montalcino and white Vernaccia di San Gimignano. Having a strong linguistic and cultural identity, ...
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Mohrite
Mohrite, (NH4)2Fe(SO4)2·6 H2O, is a rare ammonium iron(II) sulfate mineral originally found in the geothermal fields of Tuscany, Italy. This Fe-dominant analogue of boussingaultite is sometimes reported from burning coal dumps where it is a product of pyrite oxidation. The mineral crystallizes in the monoclinic crystal system In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic sy ... with space group ''P21/a''. See also * Acid mine drainage, pyrite oxidation * Mohr's salt References Ammonium minerals Iron(II) minerals Sulfate minerals Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub ...
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Ammonium Compounds
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged (cationic) polyatomic ion, molecular ion with the chemical formula or . It is formed by the protonation, addition of a proton (a hydrogen nucleus) to ammonia (). Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by Organic compound, organic or other groups (indicated by R). Not only is ammonium a source of nitrogen and a key metabolite for many living organisms, but it is an integral part of the global nitrogen cycle. As such, human impact in recent years could have an effect on the biological communities that depend on it. Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted–Lowry acid–base theory, Brønsted acids (proton donors): : The ammonium ion is mildly acidic, reacting with Brønsted bases to return ...
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