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Alunite Group
Alunite is a hydroxylated aluminium potassium sulfate mineral, formula K Al3( S O4)2(O H)6. It was first observed in the 15th century at Tolfa, near Rome, where it was mined for the manufacture of alum. First called ''aluminilite'' by J.C. Delamétherie in 1797, this name was contracted by François Beudant three decades later to alunite. Alunite crystals morphologically are rhombohedron, rhombohedra with interfacial angles of 90° 50', causing them to resemble cubes. Crystal symmetry is trigonal. Minute glistening crystals have also been found loose in cavities in altered rhyolite. Alunite varies in color from white to yellow gray. The hardness on the Mohs scale is 4 and the specific gravity is between 2.6 and 2.8. It is insoluble in water or weak acids, but soluble in sulfuric acid. Sodium can substitute for potassium in the mineral, and when the sodium content is high, is called natroalunite. Alunite is an analog of jarosite, where aluminium replaces Fe3+. Alunite o ...
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Sulfate Minerals
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates ** Barite BaSO4 ** Celestite SrSO4 ** Anglesite PbSO4 ** Anhydrite CaSO4 ** Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates ** Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O ** Kieserite MgSO4·H2O ** Starkeyite MgSO4·4H2O ** Hexahydrite MgSO4·6H2O ** Epsomite MgSO4·7H2O ** Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O ** Antlerite Cu3SO4(OH)4 ** ...
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Trigonal
In crystallography, the hexagonal crystal family is one of the six crystal family, crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section hexagonal crystal family#Crystal systems, crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhom ...
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Fumarole
A fumarole (or fumerole) is a vent in the surface of the Earth or another rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcanic activity, but fumarole activity can also precede a volcanic eruption and has been used for eruption prediction. Most fumaroles die down within a few days or weeks of the end of an eruption, but a few are persistent, lasting for decades or longer. An area containing fumaroles is known as a fumarole field. The predominant vapor emitted by fumaroles is steam, formed by the circulation of groundwater through heated rock. This is typically accompanied by volcanic gases given off by magma cooling deep below the surface. These volcanic gases include sulfur compounds, such as various sulfur oxides and hydrogen sulfide, and sometimes hydrogen chloride, hydrogen fluoride, and other gases. A fumarole that emits significant sulfur compounds is some ...
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Oxidation
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. The oxidation and reduction processes occur simultaneously in the chemical reaction. There are two classes of redox reactions: * Electron-transfer – Only one (usually) electron flows from the atom, ion, or molecule being oxidized to the atom, ion, or molecule that is reduced. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * Atom transfer – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously, the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidati ...
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Volcanic Rocks
Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "pyroclastics," and these are also technically sedimentary rocks. Volcanic rocks are among the most common rock types on Earth's surface, particularly in the oceans. On land, they are very common at plate boundaries and in flood basalt provinces. It has been estimated that volcanic rocks cover about 8% of the Earth's current land surface. Ch ...
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Trachyte
Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanite, aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava (or shallow intrusions) enriched with silica and alkali metals. It is the volcanic equivalent of syenite. Trachyte is common wherever alkali magma is erupted, including in late stages of ocean island volcanismMacDonald 1983, pp. 51–52 and in continental rift valleys, above mantle plumes,Philpotts and Ague 2009, pp. 390–394 and in areas of back-arc extension. Trachyte has also been found in Gale crater on Mars. Trachyte has been used as decorative building stone and was extensively used as dimension stone in the Roman Empire and the Republic of Venice. Chemical composition Trachyte has a silica content of 60 to 65% and an alkali oxide content of over 7%. This gives it less SiO2 than rhyolite and more (Na2O plus K2O) than dacite. These chemical differe ...
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Iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's outer and inner core. It is the fourth most abundant element in the Earth's crust, being mainly deposited by meteorites in its metallic state. Extracting usable metal from iron ores requires kilns or furnaces capable of reaching , about 500 °C (900 °F) higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BC and the use of iron tools and weapons began to displace copper alloys – in some regions, only around 1200 BC. That event is considered the transition from the Bronze Age to the Iron Age. In the modern world, iron alloys, such as steel, stainless steel, cast iron and special steels, are by far the most common industrial metals, due to their mechan ...
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Jarosite
Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct during the purification and refining of zinc and is also commonly associated with acid mine drainage and acid sulfate soil environments. Physical properties Jarosite has a trigonal crystal structure and is brittle, with basal cleavage, a hardness of 2.5–3.5, and a specific gravity of 3.15–3.26. It is translucent to opaque with a vitreous to dull luster, and is colored dark yellow to yellowish-brown. It can sometimes be confused with limonite or goethite with which it commonly occurs in the gossan (oxidized cap over an ore body). Jarosite is an iron analogue of the potassium aluminium sulfate, alunite. Solid solution series The alunite supergroup includes the alunite, jarosite, beudantite, crandallite and florencite subgroups. Th ...
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Alunite Crystal Structure
Alunite is a hydroxylated aluminium potassium sulfate mineral, formula K Al3( S O4)2(O H)6. It was first observed in the 15th century at Tolfa, near Rome, where it was mined for the manufacture of alum. First called ''aluminilite'' by J.C. Delamétherie in 1797, this name was contracted by François Beudant three decades later to alunite. Alunite crystals morphologically are rhombohedron, rhombohedra with interfacial angles of 90° 50', causing them to resemble cubes. Crystal symmetry is trigonal. Minute glistening crystals have also been found loose in cavities in altered rhyolite. Alunite varies in color from white to yellow gray. The hardness on the Mohs scale is 4 and the specific gravity is between 2.6 and 2.8. It is insoluble in water or weak acids, but soluble in sulfuric acid. Sodium can substitute for potassium in the mineral, and when the sodium content is high, is called natroalunite. Alunite is an analog of jarosite, where aluminium replaces Fe3+. Alunite o ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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Specific Gravity
Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nearly always measured with respect to water at its densest (at ); for gases, the reference is air at room temperature (). The term "relative density" (abbreviated r.d. or RD) is preferred in SI, whereas the term "specific gravity" is gradually being abandoned. If a substance's relative density is less than 1 then it is less dense than the reference; if greater than 1 then it is denser than the reference. If the relative density is exactly 1 then the densities are equal; that is, equal volumes of the two substances have the same mass. If the reference material is water, then a substance with a relative density (or specific gravity) less than 1 will float in water. For example, an ice cube, with a relative density of about 0.91, will float. ...
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