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4-nitroaniline
4-Nitroaniline, p-nitroaniline or 1-amino-4-nitrobenzene is an organic compound with the formula C6H6N2O2. A yellow solid, it is one of three isomers of nitroaniline. It is an intermediate in the production of dyes, antioxidants, pharmaceuticals, gasoline, gum inhibitors, poultry medicines, and as a corrosion inhibitor. Synthesis 4-Nitroaniline is produced industrially via the amination of 4-nitrochlorobenzene:] :ClC6H4NO2 + 2 NH3 → H2NC6H4NO2 + NH4Cl Below is a laboratory synthesis of 4-nitroaniline from aniline. The key step in this reaction sequence is an electrophilic aromatic substitution to install the nitro group ''para'' to the amino group. The amino group can be easily protonated and become a meta director. Therefore, a protection of the acetyl group is required. After this reaction, a separation must be performed to remove 2-nitroaniline, which is also formed in a small amount during the reaction. Applications 4-Nitroaniline is mainly consumed industrially as a prec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2,6-Dichloro-4-nitroaniline
2,6-Dichloro-4-nitroaniline is an organic compound with the formula . It is the most widely discussed isomer of dichloronitroaniline, mainly as a precursor to the azo dye disperse brown 1. It is prepared by treatment of 4-nitroaniline with a mixture of hydrochloric acid and hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscosity, viscous than Properties of water, water. It is used as an oxidizer, bleaching agent, and antiseptic, usua ... (a source of chlorine). References {{DEFAULTSORT:Dichloro-4-nitroaniline, 2,6- Anilines ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
1,4-Dinitrobenzene
1,4-Dinitrobenzene is one of three isomers of dinitrobenzene, with the formula C6H4(NO2)2. The 1,4-isomer is most symmetrical. The compound is a yellow solid that is soluble in organic solvents. It is prepared from 4-nitroaniline by diazotization followed by treatment with sodium nitrite Sodium nitrite is an inorganic compound with the chemical formula . It is a white to slightly yellowish crystalline powder that is very soluble in water and is hygroscopic. From an industrial perspective, it is the most important nitrite sa ... in the presence of a copper catalyst. References {{DEFAULTSORT:Dinitrobenzene, 1,4- Nitrobenzenes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
4-Nitrochlorobenzene
4-Nitrochlorobenzene is the organic compound with the formula ClC6H4NO2. It is a pale yellow solid. 4-Nitrochlorobenzene is a common intermediate in the production of a number of industrially useful compounds, including antioxidants commonly found in rubber. Other isomers with the formula ClC6H4NO2 include 2-nitrochlorobenzene and 3-nitrochlorobenzene. Preparation and reactions 4-Nitrochlorobenzene is prepared industrially by nitration of chlorobenzene: : This reaction affords both the 2- and the 4-nitro derivatives, in about a 1:2 ratio. These isomers are separated by a combination of crystallization and distillation. 4-Nitrochlorobenzene was originally prepared by the nitration of 4-bromochlorobenzene by Holleman and coworkers. The chloride substituent in 4-nitrochlorobenzene is more labile than in chlorobenzene. For example, it is readily displaced by sulfide nucleophiles, leading the way to 4-nitrothiophenol. In another example, 4-nitrochlorobenzene is a favored substr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
3-Nitroaniline
3-Nitroaniline is an organic compound with the formula H2NC6H4NO2. A yellow solid, it is a derivative of aniline, carrying a nitro functional group in position 3. It is an isomer of 2-nitroaniline and 4-nitroaniline. It is used as a precursor to dyes. Synthesis and applications 3-Nitroaniline is produced on a commercial scale by reduction of 1,3-dinitrobenzene with hydrogen sulfide, or sodium sulfide (a Zinin reaction). It is used as a chemical intermediate for azo coupling In organic chemistry, an azo coupling is an organic reaction, reaction between a diazonium compound () and another aromatic compound that produces an azo compound (). In this electrophilic aromatic substitution reaction, the aryldiazonium cation ... component and the dyes disperse yellow 5 and acid blue 29. References {{DEFAULTSORT:Nitroaniline, 3- Anilines Nitrobenzene derivatives ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
IARC Group 3 Carcinogens
IARC may refer to: * International Aerial Robotics Competition * International Age Rating Coalition * International Agency for Research on Cancer * International Arctic Research Center * Israel Association of Radio Communication * iArc, South Korean architecture firm * IAR Systems IAR Systems is a Sweden, Swedish computer software company that offers development tools for embedded systems. IAR Systems was founded in 1983, and is listed on Nasdaq Nordic in Stockholm. IAR is an abbreviation of Ingenjörsfirma Anders Rundgren ... C/C++ compiler (IAR C) See also * Indian Association for Research in Computing Science (IARCS) * * {{disambig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dyes
Juan de Guillebon, better known by his stage name DyE, is a French musician. He is known for the music video of the single "Fantasy (DyE song), Fantasy" from his first album ''Taki 183 (album), Taki 183''. This video became popular, attracting over 65 million views, 49 million of those within two years. Discography Albums *''Taki 183 (album), Taki 183'' (2011) *''Cocktail Citron'' (2014) *''Inside Out (2018)'' *''MySpace (2024)'' EPs *''Imperator'' (2009) *''Emo Machine'' (2017) References External linksDyE at Myspace French musicians Living people Year of birth missing (living people) {{France-musician-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosion
An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated by a slower expansion that would normally not be forceful, but is not allowed to expand, so that when whatever is containing the expansion is broken by the pressure that builds as the matter inside tries to expand, the matter expands forcefully. An example of this is a Volcano, volcanic eruption created by the expansion of magma in a magma chamber as it rises to the surface. Supersonic explosions created by high explosives are known as detonations and travel through shock waves. wikt:subsonic, Subsonic explosions are created by low explosives through a slower combustion process known as deflagration. Causes For an explosion to occur, there must be a rapid, forceful expansion of matter. There are numerous ways this can happen, both natura ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
American Chemical Society
The American Chemical Society (ACS) is a scientific society based in the United States that supports scientific inquiry in the field of chemistry. Founded in 1876 at New York University, the ACS currently has more than 155,000 members at all degree levels and in all fields of chemistry, chemical engineering, and related fields. It is one of the world's largest scientific societies by membership. The ACS is a 501(c) organization, 501(c)(3) non-profit organization and holds a congressional charter under Title 36 of the United States Code. Its headquarters are located in Washington, D.C., and it has a large concentration of staff in Columbus, Ohio. The ACS is a leading source of scientific information through its peer-reviewed scientific journals, national conferences, and the Chemical Abstracts Service. Its publications division produces over 80 Scientific journal, scholarly journals including the prestigious ''Journal of the American Chemical Society'', as well as the weekly tr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fumehood
A fume hood (sometimes called a fume cupboard or fume closet, not to be confused with Extractor hood) is a type of local exhaust ventilation device that is designed to prevent users from being exposed to hazardous fumes, vapors, and dusts. The device is an enclosure with a movable sash window on one side that traps and exhausts gases and particulates either out of the area (through a duct) or back into the room (through air filtration), and is most frequently used in laboratory settings. The first fume hoods, constructed from wood and glass, were developed in the early 1900s as a measure to protect individuals from harmful gaseous reaction by-products. Later developments in the 1970s and 80s allowed for the construction of more efficient devices out of epoxy powder-coated steel and flame-retardant plastic laminates. Contemporary fume hoods are built to various standards to meet the needs of different laboratory practices. They may be built to different sizes, with some demons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Snake
The carbon snake is a demonstration of the dehydration reaction of sugar by concentrated sulfuric acid. With concentrated sulfuric acid, granulated table sugar (sucrose) performs a degradation reaction which changes its form to a black solid-liquid mixture. The carbon snake experiment can sometimes be misidentified as the Black snake (firework), black snake, "sugar snake", or "burning sugar" reaction, all of which involve Sodium bicarbonate, baking soda rather than sulfuric acid. Explanation Concentrated sulfuric acid can perform a dehydration reaction with table sugar. After mixing, the color changes from white to brownish and eventually to black. The expansion of the mixture is the result of vaporization of water and Carbon dioxide, CO2 inside the container. The gases inflate the mixture to form a snake-like shape, and give off a burned sugar smell. The granularity of the sugar can greatly affect the reaction: powdered sugar reacts very quickly but sugar cubes take longer t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nucleophilic Aromatic Substitution
A nucleophilic aromatic substitution (SNAr) is a substitution reaction in organic chemistry in which the nucleophile displaces a good leaving group, such as a halide, on an aromatic ring. Aromatic rings are usually nucleophilic, but some aromatic compounds do undergo nucleophilic substitution. Just as normally nucleophilic alkenes can be made to undergo conjugate substitution if they carry electron-withdrawing substituents, so normally nucleophilic aromatic rings also become electrophilic if they have the right substituents.This reaction differs from a common SN2 reaction, because it happens at a trigonal carbon atom (sp2 hybridization). The mechanism of SN2 reaction does not occur due to steric hindrance of the benzene ring. In order to attack the C atom, the nucleophile must approach in line with the C-LG (leaving group) bond from the back, where the benzene ring lies. It follows the general rule for which SN2 reactions occur only at a tetrahedral carbon atom. The SN1 mechani ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
