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2-nitrodiphenylamine
2-Nitrodiphenylamine, also called NDPA, 2-NDPA, 2NO2DPA, Sudan Yellow 1339, C.I. 10335, CI 10335, phenyl 2-nitrophenylamine, 2-nitro-N-phenylaniline, or N-phenyl-''o''-nitroaniline, is an organic chemical, a nitrated aromatic amine, a derivate of diphenylamine. Its chemical formula is C12H10N2O2, or C6H5NHC6H4NO2. It is a red crystalline solid, usually in form of flakes or powder, with melting point of 74-76 °C and boiling point of 346 °C. It is polar but hydrophobic. 2-Nitrodiphenylamine is used as a stabilizer for synthetic rubbers, explosives, propellants (e.g. in Otto fuel II, smokeless powders, in some US Army double-base propellants in solid rockets, and in other applications involving nitric acid esters), plastics, and lubricants. It is also an intermediate for organic synthesis, and a civilian solvent dye. In some explosives, it is used to control the explosion. One of its major uses is to control the explosion rate of propylene glycol dinitrate. As a stabilizer, ...
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Propylene Glycol Dinitrate
Propylene glycol dinitrate (PGDN, ttup 1,2-propylene glycol dinitrate, or 1,2-propanediol dinitrate) is an organic chemical, an ester of nitric acid and propylene glycol. It is structurally similar to nitroglycerin, except that it has one fewer nitrate group. It is a characteristically and unpleasantly smelling colorless liquid, which decomposes at 121 °C, below its boiling point. It is flammable and explosive. It is shock-sensitive and burns with a clean flame producing water vapor, carbon monoxide, and nitrogen gas. :C3H6(ONO2)2 → 3 CO + 3 H2O + N2 The principal current use of propylene glycol dinitrate is as a propellant in Otto Fuel II, together with 2-nitrodiphenylamine and dibutyl sebacate. Otto Fuel II is used in some torpedoes as a propellant. Nitrates of polyhydric alcohols, of which propylene glycol dinitrate is an example, have been used in medicine for the treatment of angina pectoris, and as explosives since the mid-nineteenth century. PGDN affects bloo ...
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Organic Chemical
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living thi ...
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Lubricant
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity. In addition to industrial applications, lubricants are used for many other purposes. Other uses include cooking ( oils and fats in use in frying pans, in baking to prevent food sticking), bioapplications on humans (e.g. lubricants for artificial joints), ultrasound examination, medical examination, and sexual intercourse. It is mainly used to reduce friction and to contribute to a better and efficient functioning of a mechanism. History Lubricants have been in some use for thousands of years. Calcium soaps have been identified on the axles of chariots dated to 1400 BC. Building stones were slid on oil-impregrated ...
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Nitrobenzenes
Nitrobenzene is an organic compound with the chemical formula C6H5 NO2. It is a water-insoluble pale yellow oil with an almond-like odor. It freezes to give greenish-yellow crystals. It is produced on a large scale from benzene as a precursor to aniline. In the laboratory, it is occasionally used as a solvent, especially for electrophilic reagents. Production Nitrobenzene is prepared by nitration of benzene with a mixture of concentrated sulfuric acid, water, and nitric acid. This mixture is sometimes called "mixed acid." The production of nitrobenzene is one of the most dangerous processes conducted in the chemical industry because of the exothermicity of the reaction (Δ''H'' = −117 kJ/mol). World capacity for nitrobenzene in 1985 was about 1,700,000 tonnes. The nitration process involves formation of the nitronium ion (NO2+), followed by an electrophilic aromatic substitution reaction of it with benzene. The nitronium ion is generated by the reaction of nitric ...
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IMX-101
IMX-101 is a high-performance insensitive high explosive composite mixture developed by BAE Systems and the United States Army to replace TNT in artillery shells, starting as soon as 2011. IMX stands for "Insensitive Munitions eXplosives", which refers to the purpose of IMX-101: to provide explosive force equivalent to TNT without its sensitivity to shocks such as gunfire, explosions from improvised explosive devices, fire, and shrapnel. For example, it is believed that a training incident in Nevada which killed seven Marines would not have occurred with the new explosive. On March 23, 2013, the United States Army ordered $780 million worth of the explosive, with a production of millions of pounds annually, to be produced by BAE at Holston Army Ammunition Plant in Tennessee. The new explosive will cost $8 per pound, compared to $6 per pound for TNT. ''Time Magazine'' called IMX-101 one of the "50 best inventions of 2010". Composition IMX-101 is composed of 2,4-dinitroani ...
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Autocatalysis
A single chemical reaction is said to be autocatalytic if one of the reaction products is also a catalyst for the same or a coupled reaction.Steinfeld J.I., Francisco J.S. and Hase W.L. ''Chemical Kinetics and Dynamics'' (2nd ed., Prentice-Hall 1999) p.151-2 Such a reaction is called an autocatalytic reaction. A ''set'' of chemical reactions can be said to be "collectively autocatalytic" if a number of those reactions produce, as reaction products, catalysts for enough of the other reactions that the entire set of chemical reactions is self-sustaining given an input of energy and food molecules (see autocatalytic set). Chemical reactions A chemical reaction of two reactants and two products can be written as : \alpha A + \beta B \rightleftharpoons \sigma S + \tau T where the Greek letters are stoichiometric coefficients and the capital Latin letters represent chemical species. The chemical reaction proceeds in both the forward and reverse direction. This equation is easily ...
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Nitrogen Oxide
Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral * Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or nitrate radical * Nitrous oxide (), nitrogen(0,II) oxide * Dinitrogen dioxide (), nitrogen(II) oxide dimer * Dinitrogen trioxide (), nitrogen(II,IV) oxide *Dinitrogen tetroxide (), nitrogen(IV) oxide dimer * Dinitrogen pentoxide (), nitrogen(V) oxide, or nitronium nitrate * Nitrosyl azide (), nitrogen(−I,0,I,II) oxide *Nitryl azide () * Oxatetrazole () * Trinitramide ( or ), nitrogen(0,IV) oxide Anions * Nitroxide () * Nitrite ( or ) * Nitrate () * Peroxynitrite ( or ) * Peroxynitrate ( or ) * Orthonitrate (, analogous to phosphate ) * Hyponitrite ( or ) * Trioxodinitrate or hyponitrate ( or ) * Nitroxylate ( or ) * Dinitramide ( or ) Cations * Nitrosonium ( or ) *Nitronium ( or ) Atmospheric sciences In atmospheric chemistry: * ...
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Solvent Dye
A solvent dye is a dye soluble in organic solvents. It is usually used as a solution in an organic solvent. Solvent dyes are used to color organic solvents, hydrocarbon fuels, waxes, lubricants, plastics, and other hydrocarbon-based nonpolar materials. Fuel dyes are one use of solvent dyes. Their molecules are typically nonpolar or little polar, and they do not undergo ionization. They are insoluble in water. They form a colloidal solution in solvents. They have poor (basic dyes) to good (metal complex based) light fastness. Solvent dyes are used for gold imitation (and other transparent metallic effects) of metallized polyester films. Also used in marking inks, inkjet inks, glass coloration, and so on. Names of solvent dyes are often generic, of the scheme "solvent <color> <number>", e.g. Solvent Red 24, Solvent Red 26, Solvent Red 164, Solvent Yellow 124, Solvent Blue 35, etc. Red and yellow solvent dyes are often azo dyes, green and blue ones tend to be ...
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