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2,3-Dimethylbutane
2,3-Dimethylbutane is an isomer of hexane. It has the chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ... (CH3)2CHCH(CH3)2. It is a colorless liquid which boils at 57.9 °C. References Alkanes {{Hydrocarbon-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Neopentane
Neopentane, also called 2,2-dimethylpropane, is a double-branched-chain alkane with five carbon atoms. Neopentane is a flammable gas at room temperature and pressure which can condense into a highly volatile liquid on a cold day, in an ice bath, or when compressed to a higher pressure. Neopentane is the simplest alkane with a quaternary carbon, and has achiral tetrahedral symmetry. It is one of the three structural isomers with the molecular formula C5H12 (pentanes), the other two being ''n''-pentane and isopentane. Out of these three, it is the only one to be a gas at standard conditions; the others are liquids. It was first synthesized by Russian chemist in 1870. Nomenclature The traditional name neopentane, coined by William Odling in 1876, was still retained in the 1993 IUPAC recommendations, but is no longer recommended according to the 2013 recommendations. The preferred IUPAC name is the systematic name 2,2-dimethylpropane, but the substituent numbers are su ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2,2-Dimethylbutane
2,2-Dimethylbutane, trivially known as neohexane at William Odling's 1876 suggestion, is an organic compound with formula C6H14 or (H3C-)3-C-CH2-CH3. It is therefore an alkane, indeed the most compact and branched of the hexane isomers — the only one with a quaternary carbon and a butane (C4) backbone. Synthesis Butlerov's student V. Goryainov originally discovered neohexane in 1872 by cross-coupling of zinc ethyl with tert-butyl iodide. 2,2-Dimethylbutane can be synthesised by the hydroisomerisation of 2,3-dimethylbutane using an acid catalyst. It can also be synthesised by isomerization of ''n''-pentane in the presence of a catalyst containing combinations of one or more of palladium, platinum, rhodium and rhenium on a matrix of zeolite, alumina, silicon dioxide or other materials. Such reactions create a mixture of final products including isopentane, ''n''-hexane, 3-methylpentane, 2-methylpentane, 2,3-dimethylbutane and 2,2-dimethylbutane. Since the composition of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triptane
Triptane, or 2,2,3-trimethylbutane, is an organic chemical compound with the molecular formula C7 H16 or (H3C-)3C-C(-CH3)2H. It is therefore an alkane, specifically the most compact and heavily branched of the heptane isomers, the only one with a butane (C4) backbone. It was first synthesized in 1922 by Belgian chemists Georges Chavanne (1875–1941) and B. Lejeune, who called it trimethylisopropylmethane. Due to its high octane rating (112–113 RON, 101 MON) triptane was produced on alkylation units starting from 1943 for use as an anti-knock additive in gasoline. It was extensively researched for this role and received the modern name in the late 1930s at a joint laboratory of NACA, National Bureau of Standards, US Army Air Corps and the Bureau of Aeronautics. As of 2011, it was not a significant component of US automobile gasoline, present only in trace amounts (0.05–0.1%). See also *List of gasoline additives Gasoline additives may increase gasoline's octane rating ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetramethylbutane
Tetramethylbutane, sometimes called hexamethylethane, is a hydrocarbon with formula C8H18 or (H3C-)3C-C(-CH3)3. It is the most heavily branched and most compact of the octane isomers, the only one with a butane (C4) backbone. Because of its highly symmetrical structure, it has a very high melting point and a short liquid range; in fact, it is the smallest saturated acyclic hydrocarbon that appears as a solid at a room temperature of 25 °C. (Among cyclic hydrocarbons, cubane, C8H8, norbornane, C7H12 and norbornene, C7H10 are even smaller and are also solid at room temperature.) It is also the most stable C8H18 isomer, with a heat of formation lower than that of ''n''-octane, a fact that has been attributed to stabilizing dispersive interactions (electron correlation) between the methyl groups (protobranching). The compound can be obtained from ethyl bromide, ''tert''-butyl bromide, and magnesium metal in the presence of manganese( II) ions. Despite conditions amenable to t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetraethylmethane
Tetraethylmethane is a branched alkane with 9 carbon atoms. It is a colorless, highly flammable, and volatile liquid at room temperature. It is one of the isomers of nonane. References See also *Neopentane Neopentane, also called 2,2-dimethylpropane, is a double-branched-chain alkane with five carbon atoms. Neopentane is a flammable gas at room temperature and pressure which can condense into a highly volatile liquid on a cold day, in an ice bat ... * Tetraethynylmethane * Tetramethoxymethane External links * {{cite journal , doi = 10.1021/jo981779m , title = Molecular Structure of 3,3-Diethylpentane (Tetraethylmethane) in the Gas Phase as Determined by Electron Diffraction and ab Initio Calculations , journal = The Journal of Organic Chemistry , volume = 64 , issue = 12 , pages = 4226–4232 , year = 1999 , last1 = Alder , first1 = Roger W. , last2 = Allen , first2 = Paul R. , last3 = Hnyk , first3 = Drahomír , last4 = Rankin , first4 = David W. H. , ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2,2,4-Trimethylpentane
2,2,4-Trimethylpentane, also known as isooctane or iso-octane, is an organic compound with the formula (CH3)3CCH2CH(CH3)2. It is one of several isomers of octane (C8H18). This particular isomer is the standard 100 point on the octane rating scale (the zero point is ''n''-heptane). It is an important component of gasoline, frequently used in relatively large proportions (around 10%) to increase the knock resistance of fuel. Strictly speaking, if the standard meaning of ‘iso’ is followed, the name ''isooctane'' should be reserved for the isomer 2-methylheptane. However, 2,2,4-trimethylpentane is by far the most important isomer of octane and historically it has been assigned this name. Production Isooctane is produced on a massive scale in the petroleum industry by alkylation of isobutene with isobutane. This process is conducted in alkylation units in the presence of acid catalysts. : It can also be produced from isobutylene by dimerization using an Amberlyst cataly ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2,3,3-Trimethylpentane
2,3,3-Trimethylpentane is a chemical compound in the family of hydrocarbons which has a formula of C8H18. It is an isomer of octane. It has a role as a human metabolite, a bacterial metabolite and a mammalian metabolite. It is an alkane and a volatile organic compound Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-co .... References Alkanes {{Hydrocarbon-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2,3,4-Trimethylpentane
2,3,4-Trimethylpentane is a branched alkane. It is one of the isomers of octane Octane is a hydrocarbon and also an alkane with the chemical formula C8H18, and the condensed structural formula CH3(CH2)6CH3. Octane has many structural isomers that differ by the location of branching in the carbon chain. One of these isomers .... References External links2,3,4-Trimethylpentaneat environmentalchemistry.com Alkanes {{Hydrocarbon-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetra-tert-butylmethane
Tetra-''tert''-butylmethane is a hypothetical organic compound with formula C17H36, consisting of four ''tert''-butyl groups bonded to a central carbon atom. It would be an alkane, specifically the most compact branched isomer of heptadecane. Some calculations suggest this compound cannot exist due to the steric hindrance among the closely packed ''tert''-butyl groups, which would make it one of the smallest, if not the smallest itself, saturated and acyclic hydrocarbon that cannot exist. Other calculations suggest that the molecule would be stable, with the C–C bonds to the central ("methane") carbon having a length of 166.1 pm — longer than the typical C−C bond in order to reduce steric effects, but still shorter than those found in some other real molecules. See also * Neopentane * Tetrakis(trimethylsilyl)methane * Tetrafluoromethane * Tetrachloromethane * Tetrabromomethane * Tetraiodomethane * Tetraazidomethane * Tetracyanomethane * Tetraethynylmethane * Tetranitr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hexane
Hexane () or ''n''-hexane is an organic compound, a straight-chain alkane with six carbon atoms and the molecular formula C6H14. Hexane is a colorless liquid, odorless when pure, and with a boiling point of approximately . It is widely used as a cheap, relatively safe, largely unreactive, and easily evaporated non-polar solvent, and modern gasoline blends contain about 3% hexane. The term hexanes refers to a mixture, composed largely (>60%) of ''n''-hexane, with varying amounts of the isomeric compounds 2-methylpentane and 3-methylpentane, and possibly, smaller amounts of nonisomeric C5, C6, and C7 (cyclo)alkanes. These "hexanes" mixtures are cheaper than pure hexane and are often used in large-scale operations not requiring a single isomer (e.g., as cleaning solvent or for chromatography). Isomers Uses In industry, hexanes are used in the formulation of adhesive, glues for shoes, leather products, and roofing. They are also used to extract cooking oils (such as canola oil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name since it does not contain any words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called '' empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of atoms ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
