Corex Process
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The Corex Process is a smelting reduction process created by
Primetals Technologies Primetals Technologies Limited, is an engineering and plant construction company headquartered in London, United Kingdom, with numerous locations worldwide. It serves clients in the metals industry, both the ferrous and the nonferrous metals sec ...
as a more environmentally friendly alternative to the
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being supplied above atmospheric pressure. In a ...
. Presently, the majority of steel production is through the blast furnace which has to rely on
coking coal Coke is a grey, hard, and porous coal-based fuel with a high carbon content. It is made by heating coal or petroleum in the absence of air. Coke is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves ...
and requires a
sinter plant Sinter plants agglomerate iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty r ...
in order to prepare the iron ore for reduction. Unlike the blast furnace, smelting reduction processes are typical smaller and use coal and oxygen directly to reduce iron ore into a usable product. Smelting reduction processes come in two basic varieties, two-stage or single-stage. In a single-stage system the iron ore is both reduced and melted in the same container. In a two-stage process, like Corex, the ore is reduced in one shaft and melted and purified in another. Plants using the Corex process have been put use in areas such as
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
,
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
, and
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
. First COREX process was installed in 1988 at South Africa.


Process

The Corex process consists of two main parts: a ''Reduction Shaft'' and a ''Melter-Gasifier''. The main reagents for the Corex process are
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the f ...
, non-coking coal, and
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
. Unlike a blast furnace, the Corex process does not use a hot blast of
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, thereby greatly reducing
NOx In atmospheric chemistry, is shorthand for nitric oxide () and nitrogen dioxide (), the nitrogen oxides that are most relevant for air pollution. These gases contribute to the formation of smog and acid rain, as well as affecting tro ...
gas emissions, but instead uses oxygen. In addition, the Corex process can use iron oxides containing up to 80% lump ore and uses non-coking coal directly as a reducing agent. In the reduction shaft the iron ore, along with
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
and dolomite additives, is added and then reduced by reduction gas into 95% direct reduced iron, DRI. The DRI is then redirected via six discharge screws into the melter-gasifier. The melter-gasifier has three main sections, the gaseous free board zone, the char bed, and the hearth zone, and it has an effect on several stages in the process. First it serves to create the reduction gas by gasifying the coal with oxygen and then cooling it. After being reduced, the DRI is redirected to the char bed where the iron and slag are melted and then directed to the hearth zone. The heat inside the metal gasifier keeps the amount of phenols small, keeping them out of the atmosphere. Meanwhile,
carbon monoxide Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
and
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
gas from the original gasification of the coal exit the gasifier while other byproducts are captured in the metallic slag. The rest of the hot gas is then cooled and sent into the reduction shaft resulting in the Corex export gas which is used to control pressure in the plant. Many of the gases resulting from this process can then be recycled or used to produce electricity. Dust particles also appear in these gases and the melter-gasifier recycles them with four dust burners.


Advantages

There are many advantages to the Corex Process, for example
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
emissions are up to 20% lower than with the conventional blast furnace, and the Corex process produces far less SO2 and dust than the blast furnace. In addition Corex plants do not release as many phenols or sulfides limiting
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
contamination.


Disadvantages

There are drawbacks. For example, at the JSW Steel plant in India it was found that to be viable the Corex process still needed about 15% coke. Furthermore, it has also been found that Corex plants require large amounts of oxygen which can be expensive. Also the export gas can make the process highly inefficient. However, this particular problem can be mitigated by using the export gas in electricity production.


References

{{Reflist Smelting Siemens