Beryllium bromide is the

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

with the

formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwee ...

BeBr₂. It is very

hygroscopic Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance ...

and dissolves well in

water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...

. The compound is a polymer with tetrahedral coordinated Be centres.

Preparation and reactions

It can be prepared by reacting

beryllium Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form mi ...

metal with elemental

bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simila ...

at temperatures of 500 °C to 700 °C: :Be + Br₂ → BeBr₂ Beryllium bromide is also formed when treating

beryllium oxide Beryllium oxide (BeO), also known as beryllia, is an inorganic compound with the formula BeO. This colourless solid is a notable electrical insulator with a higher thermal conductivity than any other non-metal except diamond, and exceeds that of m ...

with

hydrobromic acid Hydrobromic acid is a strong acid formed by dissolving the diatomic molecule hydrogen bromide (HBr) in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at and contains 47.6% HBr by mass, which is 8.77 mol/L. H ...

: :BeO + 2 HBr → BeBr₂ + H₂O It hydrolyzes slowly in water: BeBr₂ + 2 H₂O → 2 HBr + Be(OH)₂

Structure

Two forms ( polymorphs) of BeBr₂ are known. Both structures consist of tetrahedral Be²⁺ centers interconnected by doubly bridging bromide ligands. One form consist of edge-sharing polytetrahedra. The other form resembles

zinc iodide Zinc iodide is the inorganic compound with the formula ZnI2. It exists both in anhydrous form and as a dihydrate. Both are white and readily absorb water from the atmosphere. It has no major application. Preparation It can be prepared by the dir ...

with interconnected

adamantane Adamantane is an organic compound with a formula C10H16 or, more descriptively, (CH)4(CH2)6. Adamantane molecules can be described as the fusion of three cyclohexane rings. The molecule is both rigid and virtually stress-free. Adamantane is the m ...

-like cages.

Safety

Beryllium compounds are toxic if inhaled or ingested.

References

{{DEFAULTSORT:Beryllium Bromide Beryllium compounds Bromides Alkaline earth metal halides Inorganic polymers