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Spiegeleisen
Spiegeleisen (literally "mirror-iron", —mirror or specular; —iron) is a ferromanganese alloy containing approximately 15% manganese and small quantities of carbon and silicon. Spiegeleisen is sometimes also referred to as ''specular pig iron'', ''Spiegel iron'', just ''Spiegel'', or ''Bisalloy''. Usage Historically, this was the standard form in which manganese was traded and used in steel making. Manganese is useful in steel manufacture because it binds with phosphorus, sulfur, and silica, removing them (to a degree) from the iron. It was much used in conjunction with the Bessemer process both to introduce carbon and manganese, and also to reduce impurities. Manufacture In the 19th-century spiegeleisen was made either by mixing iron ores with appropriate levels of manganese and smelting them directly, or by adding pyrolusite or manganite to previously smelted iron in a cupellation furnace. Today, manganese is usually traded and used in more concentrated form, 80% mangane ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spiegeleisen
Spiegeleisen (literally "mirror-iron", —mirror or specular; —iron) is a ferromanganese alloy containing approximately 15% manganese and small quantities of carbon and silicon. Spiegeleisen is sometimes also referred to as ''specular pig iron'', ''Spiegel iron'', just ''Spiegel'', or ''Bisalloy''. Usage Historically, this was the standard form in which manganese was traded and used in steel making. Manganese is useful in steel manufacture because it binds with phosphorus, sulfur, and silica, removing them (to a degree) from the iron. It was much used in conjunction with the Bessemer process both to introduce carbon and manganese, and also to reduce impurities. Manufacture In the 19th-century spiegeleisen was made either by mixing iron ores with appropriate levels of manganese and smelting them directly, or by adding pyrolusite or manganite to previously smelted iron in a cupellation furnace. Today, manganese is usually traded and used in more concentrated form, 80% mangane ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferromanganese
Ferromanganese is a ferroalloy with high manganese content (high-carbon ferromanganese can contain as much as 80% Mn by weight). It is made by heating a mixture of the oxides MnO2 and Fe2O3, with carbon (usually as coal and coke) in either a blast furnace or an electric arc furnace-type system, called a submerged arc furnace. The oxides undergo carbothermal reduction in the furnaces, producing the ferromanganese. Ferromanganese is used as a deoxidizer for steel. A North American standard specification is ASTM A99. The ten grades covered under this specification includes; *Standard ferromanganese *Medium-carbon ferromanganese *Low-carbon ferromanganese A similar material is a pig iron with high content of manganese, is called spiegeleisen, or specular pig iron. History 350px, lang=en, Evolution of global manganese production, by processes. In 1856, Robert Forester Mushet "used manganese to improve the ability of steel produced by the Bessemer process to withstand rolling a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spathic Iron Ore
Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and manganese commonly substitute for the iron resulting in the siderite-smithsonite, siderite-magnesite and siderite- rhodochrosite solid solution series. Siderite has Mohs hardness of 3.75-4.25, a specific gravity of 3.96, a white streak and a vitreous lustre or pearly luster. Siderite is antiferromagnetic below its Néel temperature of 37 K which can assist in its identification. It crystallizes in the trigonal crystal system, and are rhombohedral in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese. Siderite is commonly found in hydrothermal veins, and is associated with barite, fluorite, galena, and others. It i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cupellation Furnace
Cupellation is a Refining (metallurgy), refining process in metallurgy where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals, like lead, copper, zinc, arsenic, antimony, or bismuth, present in the ore. The process is based on the principle that precious metals do not oxidise or react chemically, unlike base metals. When they are heated at high temperatures, the precious metals remain apart, and the others react, forming slags or other compounds.Bayley, J. 2008 Since the Early Bronze Age, the process was used to obtain silver from smelted lead ores.Rehren, Th., Eckstein, K. 2002 By the Middle Ages and the Renaissance, cupellation was one of the most common processes for refining precious metals. By then, fire assays were used for assaying minerals: testing fresh metals such as lead and recycled metals to know their purity for jewellery and coin making. Cupellation is stil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Manganite
Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown. The hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent. The mineral contains 89.7% manganese sesquioxide; it dissolves in hydrochloric acid with evolution of chlorine. Occurrence Manganite occurs with other manganese oxides in deposits formed by circulating meteoric water in the weathering environment in clay deposits and laterites. It forms by low temperature hydrothermal action in veins in association with calcite, barite, and siderite. Often associated wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pyrolusite
Pyrolusite is a mineral consisting essentially of manganese dioxide ( Mn O2) and is important as an ore of manganese.. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for ''fire'' and to ''wash'', in reference to its use as a way to remove tints from glass. Occurrence Pyrolusite and romanechite are among the most common manganese minerals. Pyrolusite occurs associated with manganite, hollandite, hausmannite, braunite, chalcophanite, goethite, and hematite under oxidizing conditions in hydrothermal deposits. It also occurs in bogs and often results from alteration of manganite. Use The metal is obtained by reduction of the oxide with sodium, magnesium, aluminium, or by electrolysis. Pyrolusite is extensively used for the manufacture ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bessemer Process
The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is removal of impurities from the iron by oxidation with air being blown through the molten iron. The oxidation also raises the temperature of the iron mass and keeps it molten. Related decarburizing with air processes had been used outside Europe for hundreds of years, but not on an industrial scale. One such process (similar to puddling) was known in the 11th century in East Asia, where the scholar Shen Kuo of that era described its use in the Chinese iron and steel industry. In the 17th century, accounts by European travelers detailed its possible use by the Japanese. The modern process is named after its inventor, the Englishman Henry Bessemer, who took out a patent on the process in 1856. The process was said to be independently discovered in 1851 by the American inventor Willi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear molecule. The starkly different structures of th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Steel Making
Steelmaking is the process of producing steel from iron ore and carbon/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur and excess carbon (the most important impurity) are removed from the sourced iron, and alloying elements such as manganese, nickel, chromium, carbon and vanadium are added to produce different grades of steel. Limiting dissolved gases such as nitrogen and oxygen and entrained impurities (termed "inclusions") in the steel is also important to ensure the quality of the products cast from the liquid steel. Steelmaking has existed for millennia, but it was not commercialized on a massive scale until the mid-19th century. An ancient process of steelmaking was the crucible process. In the 1850s and 1860s, the Bessemer process and the Siemens-Martin process turned steelmaking into a heavy industry. Today there are two major commercial processes for making steel, namely basic oxygen steelmaking, which has liquid pig-iron from the b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phosphorus
Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has a concentration in the Earth's crust of about one gram per kilogram (compare copper at about 0.06 grams). In minerals, phosphorus generally occurs as phosphate. Elemental phosphorus was first isolated as white phosphorus in 1669. White phosphorus emits a faint glow when exposed to oxygen – hence the name, taken from Greek mythology, meaning 'light-bearer' (Latin ), referring to the " Morning Star", the planet Venus. The term '' phosphorescence'', meaning glow after illumination, derives from this property of phosphorus, although the word has since been used for a different physical process that produces a glow. The glow of phosphorus is caused by oxidation of the white (but not red) phosphorus — a process now called chem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
