spin magnetic moment
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In physics, mainly
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
and
particle physics Particle physics or high energy physics is the study of fundamental particles and forces that constitute matter and radiation. The fundamental particles in the universe are classified in the Standard Model as fermions (matter particles) an ...
, a spin magnetic moment is the
magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagnets ...
caused by the
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally b ...
of
elementary particles In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, antiqu ...
. For example, the
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
is an elementary
spin-1/2 In quantum mechanics, spin is an intrinsic property of all elementary particles. All known fermions, the particles that constitute ordinary matter, have a spin of . The spin number describes how many symmetrical facets a particle has in one full ...
fermion In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks an ...
.
Quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
gives the most accurate prediction of the anomalous magnetic moment of the electron. In general, a
magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagnets ...
can be defined in terms of an
electric current An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving pa ...
and the area enclosed by the
current loop In electrical signalling an analog current loop is used where a device must be monitored or controlled remotely over a pair of conductors. Only one current level can be present at any time. A major application of current loops is the industry de ...
. Since angular momentum corresponds to rotational motion, the magnetic moment can be related to the orbital angular momentum of the
charge carrier In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. The term is used ...
s in the constituting current. However, in
magnetic material A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nickel ...
s, the atomic and molecular dipoles have magnetic moments not just because of their quantized orbital angular momentum, but also due to the spin of elementary particles constituting them. "Spin" is a non-classical property of elementary particles, since classically the "spin angular momentum" of a material object is really just the total ''orbital'' angular momenta of the object's constituents about the rotation axis.
Elementary particle In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, an ...
s are conceived as point objects with no axis around which to "spin" (see
wave–particle duality Wave–particle duality is the concept in quantum mechanics that every particle or quantum entity may be described as either a particle or a wave. It expresses the inability of the classical concepts "particle" or "wave" to fully describe the ...
).


History

The idea of a spin angular momentum was first proposed in a 1925 publication by
George Uhlenbeck George Eugene Uhlenbeck (December 6, 1900 – October 31, 1988) was a Dutch-American theoretical physicist. Background and education George Uhlenbeck was the son of Eugenius and Anne Beeger Uhlenbeck. He attended the Hogere Burgerschool (High S ...
and
Samuel Goudsmit Samuel Abraham Goudsmit (July 11, 1902 – December 4, 1978) was a Dutch-American physicist famous for jointly proposing the concept of electron spin with George Eugene Uhlenbeck in 1925. Life and career Goudsmit was born in The Hague, Neth ...
to explain
hyperfine splitting In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate energy levels and the resulting splittings in those energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the nuc ...
in atomic spectra. In 1928,
Paul Dirac Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Univer ...
provided a rigorous theoretical foundation for the concept in the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin- massive particles, called "Dirac part ...
for the
wavefunction A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements mad ...
of the
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
.


Spin in chemistry

Spin magnetic moments create a basis for one of the most important principles in chemistry, the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulated ...
. This principle, first suggested by
Wolfgang Pauli Wolfgang Ernst Pauli (; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and one of the pioneers of quantum physics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics fo ...
, governs most of modern-day chemistry. The theory plays further roles than just the explanations of
doublet Doublet is a word derived from the Latin ''duplus'', "twofold, twice as much",