Bone ash is a white material produced by the

calcination Calcination refers to thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), genera ...

bone A bone is a Stiffness, rigid Organ (biology), organ that constitutes part of the skeleton in most vertebrate animals. Bones protect the various other organs of the body, produce red blood cell, red and white blood cells, store minerals, provid ...

s. Typical bone ash consists of about 55.82%

calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, Caustic (substance), caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime (material), lime''" co ...

, 42.39%

phosphorus pentoxide Phosphorus pentoxide is a chemical compound with molecular formula P4 O10 (with its common name derived from its empirical formula, P2O5). This white crystalline solid is the anhydride of phosphoric acid. It is a powerful desiccant and dehydra ...

, and 1.79%

water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...

. The exact composition of these compounds varies depending upon the type of bones being used, but generally the formula for bone ash is: Ca₅(OH)(PO₄)₃. Bone ash usually has a

density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...

around 3.10 g/mL and a

melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ...

of 1670 °C (3038 °F). Most bones retain their cellular structure through calcination.

History

Bible

From

Isaiah Isaiah ( or ; he, , ''Yəšaʿyāhū'', "God is Salvation"), also known as Isaias, was the 8th-century BC Israelite prophet after whom the Book of Isaiah is named. Within the text of the Book of Isaiah, Isaiah himself is referred to as "the ...

: "And the people shall be as the burnings of lime: as thorns cut up shall they be burned in the fire" Its use is mentioned in the

Book of Amos The Book of Amos is the third of the Twelve Minor Prophets in the Old Testament (Tanakh) and the second in the Greek Septuagint tradition. Amos, an older contemporary of Hosea and Isaiah, Harris, Stephen L., ''Understanding the Bible''. Palo Alt ...

(2:1): "I will not turn away the punishment thereof, because he burned the bones of the King of Edom into

lime Lime commonly refers to: * Lime (fruit), a green citrus fruit * Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide * Lime (color), a color between yellow and green Lime may also refer to: Botany ...

." It was used in ancient formulas for white paint and cosmetic pigments, and in the

cupellation Cupellation is a refining process in metallurgy where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals, like lead, copper, zinc, arse ...

process to separate

silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...

from

lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...

Antiquity

Burnt bones have been recovered from numerous Ancient Greek sanctuaries dating from the Late Bronze Age up to the Hellenistic period. The burnt bones are often calcined with a white or blueish color, allowing archaeologists to identify them as sacrificial remains. At the sanctuary to

Artemis In ancient Greek mythology and religion, Artemis (; grc-gre, Ἄρτεμις) is the goddess of the hunt, the wilderness, wild animals, nature, vegetation, childbirth, care of children, and chastity. She was heavily identified wit ...

Eretria Eretria (; el, Ερέτρια, , grc, Ἐρέτρια, , literally 'city of the rowers') is a town in Euboea, Greece, facing the coast of Attica across the narrow South Euboean Gulf. It was an important Greek polis in the 6th and 5th centur ...

a round altar of fieldstones filled with soil was found, dating to the 8th century BC. The upper surface was covered with clay and animal bones were burned on top, then apparently swept off the surface with terracotta, metal objects, and pottery and trampled until the altar was eventually subsumed by the ritual debris. Some scholars have attributed these altars to chthonian rituals, but this is disputed.

Xenocrates of Aphrodisias Xenocrates ( el, Ξενοκράτης; fl. 1st century) a Greek physician of Aphrodisias in Cilicia, who must have lived about the middle of the 1st century, as he was probably a contemporary of Andromachus the Younger. Galen says that he lived in ...

reported its use as a medicinal ingredient, although

cannibalism Cannibalism is the act of consuming another individual of the same species as food. Cannibalism is a common ecological interaction in the animal kingdom and has been recorded in more than 1,500 species. Human cannibalism is well documented, b ...

was, according to

Galen Aelius Galenus or Claudius Galenus ( el, Κλαύδιος Γαληνός; September 129 – c. AD 216), often Anglicized as Galen () or Galen of Pergamon, was a Greek physician, surgeon and philosopher in the Roman Empire. Considered to be one of ...

, prohibited under the laws of the

Roman Empire The Roman Empire ( la, Imperium Romanum ; grc-gre, Βασιλεία τῶν Ῥωμαίων, Basileía tôn Rhōmaíōn) was the post-Republican period of ancient Rome. As a polity, it included large territorial holdings around the Mediterr ...

Uses

Bone china

The raw material for

bone china Bone china is a type of ceramic that is composed of bone ash, feldspathic material, and kaolin. It has been defined as "ware with a translucent body" containing a minimum of 30% of phosphate derived from animal bone and calculated calcium phospha ...

is about 50% bone ash derived from animal bones. These bones undergo multiple processing stages during which all meat is removed and the bone is completely cleaned. Once cleaned, the bone is heated to about 1000 °C (1832 °F) so that all additional organic material is removed from the bone and the bone becomes sterilized. Lastly, the newly sterilized bone is ground with water into fine particles which can be used as a raw material for bone china. Bone ash plays an important role in the creation of bone china, as the

phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phospho ...

of the bone generates beta

tricalcium phosphate Tricalcium phosphate (sometimes abbreviated TCP) is a calcium salt of phosphoric acid with the chemical formula Ca3(PO4)2. It is also known as tribasic calcium phosphate and bone phosphate of lime (BPL). It is a white solid of low solubility. Mo ...

, and other compounds from the bone create the calcium mineral anorthite. Synthetic alternatives

dicalcium phosphate Dicalcium phosphate is the calcium phosphate with the formula CaHPO4 and its dihydrate. The "di" prefix in the common name arises because the formation of the HPO42– anion involves the removal of two protons from phosphoric acid, H3PO4. It is al ...

and tricalcium phosphate are used as substitutes for bone ash. Most bone china are produced with synthetic alternatives rather than bone ash.

Fertilizers

Bone ash can be used alone as an

organic fertilizer Organic fertilizers are fertilizers that are naturally produced. Fertilizers are materials that can be added to soil or plants, in order to provide nutrients and sustain growth. Typical organic fertilizers include all animal waste including mea ...

or it can be treated with

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...

to form a "single

superphosphate Triple superphosphate is a component of fertilizer that primarily consists of monocalcium phosphate, Ca(H2PO4)2. Triple superphosphate is obtained by treating phosphate rock with phosphoric acid. Traditional routes for extraction of phosphate roc ...

" fertilizer which is more

water soluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solub ...

: : Ca₃(PO₄)₂ + 2 H₂SO₄ + 5 H₂O → 2 CaSO₄·2H₂O + Ca(H₂PO₄)₂· H₂O Similarly,

phosphoric acid Phosphoric acid (orthophosphoric acid, monophosphoric acid or phosphoric(V) acid) is a colorless, odorless phosphorus-containing solid, and inorganic compound with the chemical formula . It is commonly encountered as an 85% aqueous solution, w ...

can be used to form

triple superphosphate Triple superphosphate is a component of fertilizer that primarily consists of monocalcium phosphate, Ca(H2PO4)2. Triple superphosphate is obtained by treating phosphate rock with phosphoric acid. Traditional routes for extraction of phosphate roc ...

, a more concentrated phosphorus fertilizer which excludes the

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...

content found in single superphosphate: :Ca₃(PO₄)₂ + 4 H₃PO₄ → 3 Ca(H₂PO₄)₂

Metal casting

Bone ash is used in

foundries A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals pr ...

for various purposes. Examples include

release agent A release agent (also mold release agent, release coating, or mold release coating) is a chemical used to prevent other materials from bonding to surfaces. It can provide a solution in processes involving mold release, die-cast release, plastic r ...

s and protective barriers for tools exposed to molten metal, and as a

sealant Sealant is a substance used to block the passage of fluids through openings in materials, a type of mechanical seal. In building construction ''sealant'' is sometimes synonymous with ''caulking'' and also serve the purposes of blocking dust, s ...

for seams and cracks. Applied as a powder or water slurry, bone ash has many unique characteristics. First of all, the powder has high

thermal stability In thermodynamics, thermal stability describes the stability of a water body and its resistance to mixing.Schmidt, W. 1928. Über Temperatur und Stabilitätsverhältnisse von Seen. Geogr. Ann 10: 145 - 177. It is the amount of work needed to tr ...

, so it maintains its form in extremely high temperatures. The powder coating itself adheres to metal well and does not drip, run, cause much

corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...

, or create noticeable streaks. Using the bone ash is easy as well, as it comes in a powder form, is easy to clean up, and does not separate into smaller parts (therefore requiring no extra mixing).

Metallurgy

Bone ash is a material often used in

, a process by which

precious metal Precious metals are rare, naturally occurring metallic chemical elements of high economic value. Chemically, the precious metals tend to be less reactive than most elements (see noble metal). They are usually ductile and have a high lustre. ...

s (such as

gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...

and

) are removed from

base metal A base metal is a common and inexpensive metal, as opposed to a precious metal such as gold or silver. In numismatics, coins often derived their value from the precious metal content; however, base metals have also been used in coins in the past ...

s. In cupellation, base metals in an impure sample are oxidized with the help of

and are vaporized and absorbed into a porous cupellation material, typically made of

magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...

. This leaves the precious metals which do not oxidize behind. Bone ash's extremely porous and calcareous structure as well as its high melting point makes it an ideal candidate for cupellation.Bayley, Justine. "Precious Metal Refining." Archeological Datasheet, no. 2, Mar. 1995, pp. 1–1., doi:10.1016/s0026-0576(03)80479-8.

References

External links

* *{{cite web, url=http://digitalfire.com/4sight/material/bone_ash_123.html , title=Ceramic Materials Database , access-date=2013-03-04 Inorganic compounds

Ash Ash or ashes are the solid remnants of fires. Specifically, ''ash'' refers to all non-aqueous, non- gaseous residues that remain after something burns. In analytical chemistry, to analyse the mineral and metal content of chemical samples, ash ...

Organic fertilizers Animal products Types of ash