Uranopilite is a minor
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
of
uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
with the chemistry (
U O2)
6 SO
4(O
H)
6O
2·14
H2O or, hydrated uranyl sulfate hydroxide.
As with many uranyl minerals, it is
fluorescent
Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with color ...
and
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
. It is straw yellow in normal light. Uranopilite fluoresces a bright green under
ultraviolet light
Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of th ...
. Uranopilite contains clusters of six uranyl pentagonal bipyramids that share equatorial edges and vertices, with the clusters cross-linked to form chains by sharing vertices with sulfate tetrahedra. In uranopilite, the chains are linked directly by hydrogen bonds, as well as to interstitial H
2O groups.
Uranopilite is associated with other uranyl minerals such as
zippeite
Zippeite is a hydrous potassium uranium sulfate mineral with formula: K4( U O2)6( SO4)3(O H)10·4( H2O). It forms yellow to reddish brown monoclinic-prismatic crystals with perfect cleavage. The typical form is as encrustations and pulverulent ea ...
and
johannite and, like them, is usually found as an
efflorescent
In chemistry, efflorescence (Derived from the Latin verb 'efflorescere' roughly meaning 'to flower') is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process involves the dissolving of an i ...
crust in uranium mines.
Notable occurrences include:
*
Wheal Owles,
Cornwall
Cornwall (; or ) is a Ceremonial counties of England, ceremonial county in South West England. It is also one of the Celtic nations and the homeland of the Cornish people. The county is bordered by the Atlantic Ocean to the north and west, ...
,
England
England is a Countries of the United Kingdom, country that is part of the United Kingdom. It is located on the island of Great Britain, of which it covers about 62%, and List of islands of England, more than 100 smaller adjacent islands. It ...
*
San Juan County,
Utah
Utah is a landlocked state in the Mountain states, Mountain West subregion of the Western United States. It is one of the Four Corners states, sharing a border with Arizona, Colorado, and New Mexico. It also borders Wyoming to the northea ...
,
US
*
Northwest Territories
The Northwest Territories is a federal Provinces and territories of Canada, territory of Canada. At a land area of approximately and a 2021 census population of 41,070, it is the second-largest and the most populous of Provinces and territorie ...
,
Canada
Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...
*
Bohemia
Bohemia ( ; ; ) is the westernmost and largest historical region of the Czech Republic. In a narrow, geographic sense, it roughly encompasses the territories of present-day Czechia that fall within the Elbe River's drainage basin, but historic ...
n region of
Europe
Europe is a continent located entirely in the Northern Hemisphere and mostly in the Eastern Hemisphere. It is bordered by the Arctic Ocean to the north, the Atlantic Ocean to the west, the Mediterranean Sea to the south, and Asia to the east ...
See also
*
Uranyl sulfate
Uranyl sulfate describes a family of inorganic compounds with the formula UO2SO4(H2O)n. These salts consist of sulfate, the uranyl ion, and water. They are lemon-yellow solids. Uranyl sulfates are intermediates in some extraction methods used for ...
*
List of minerals
This is a list of minerals which have Wikipedia articles.
Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a mineral speci ...
References
Progress in Solid State ChemistryATHENA MINERAL: Mineral Data
Uranium(VI) minerals
Sulfate minerals
Triclinic minerals
Minerals in space group 2
{{Sulfate-mineral-stub