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Quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
(QED), a relativistic quantum field theory of electrodynamics, is among the most stringently tested theories in
physics Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which re ...
. The most precise and specific tests of QED consist of measurements of the electromagnetic
fine-structure constant In physics, the fine-structure constant, also known as the Sommerfeld constant, commonly denoted by (the Greek letter ''alpha''), is a fundamental physical constant which quantifies the strength of the electromagnetic interaction between ele ...
, ''α'', in various physical systems. Checking the consistency of such measurements tests the theory. Tests of a theory are normally carried out by comparing experimental results to theoretical predictions. In QED, there is some subtlety in this comparison, because theoretical predictions require as input an extremely precise value of ''α'', which can only be obtained from another precision QED experiment. Because of this, the comparisons between theory and experiment are usually quoted as independent determinations of ''α''. QED is then confirmed to the extent that these measurements of ''α'' from different physical sources agree with each other. The agreement found this way is to within ten parts in a billion (10−8), based on the comparison of the
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...
anomalous magnetic dipole moment In quantum electrodynamics, the anomalous magnetic moment of a particle is a contribution of effects of quantum mechanics, expressed by Feynman diagrams with loops, to the magnetic moment of that particle. (The ''magnetic moment'', also called '' ...
and the
Rydberg constant In spectroscopy, the Rydberg constant, symbol R_\infty for heavy atoms or R_\text for hydrogen, named after the Swedish physicist Johannes Rydberg, is a physical constant relating to the electromagnetic spectra of an atom. The constant first a ...
from atom recoil measurements as described below. This makes QED one of the most accurate physical theories constructed thus far. Besides these independent measurements of the fine-structure constant, many other predictions of QED have been tested as well.


Measurements of the fine-structure constant using different systems

Precision tests of QED have been performed in low-energy
atomic physics Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned wit ...
experiments, high-energy
collider A collider is a type of particle accelerator which brings two opposing particle beams together such that the particles collide. Colliders may either be ring accelerators or linear accelerators. Colliders are used as a research tool in particle ...
experiments, and
condensed matter Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the sub ...
systems. The value of ''α'' is obtained in each of these experiments by fitting an experimental measurement to a theoretical expression (including higher-order radiative corrections) that includes ''α'' as a parameter. The uncertainty in the extracted value of ''α'' includes both experimental and theoretical uncertainties. This program thus requires both high-precision measurements and high-precision theoretical calculations. Unless noted otherwise, all results below are taken from.


Low-energy measurements


Anomalous magnetic dipole moments

The most precise measurement of ''α'' comes from the
anomalous magnetic dipole moment In quantum electrodynamics, the anomalous magnetic moment of a particle is a contribution of effects of quantum mechanics, expressed by Feynman diagrams with loops, to the magnetic moment of that particle. (The ''magnetic moment'', also called '' ...
, or ''g''−2 (pronounced "g minus 2"), of the
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...
. To make this measurement, two ingredients are needed: # A precise measurement of the anomalous magnetic dipole moment, and # A precise theoretical calculation of the anomalous magnetic dipole moment in terms of ''α''. As of February 2007, the best measurement of the anomalous magnetic dipole moment of the electron was made by the group of
Gerald Gabrielse Gerald Gabrielse is an American physicist. He is the Board of Trustees Professor of Physics and Director of the Center for Fundamental Physics at Northwestern University, and Emeritus George Vasmer Leverett Professor of Physics at Harvard Univers ...
at
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of highe ...
, using a single electron caught in a
Penning trap A Penning trap is a device for the storage of charged particles using a homogeneous axial magnetic field and an inhomogeneous quadrupole electric field. This kind of trap is particularly well suited to precision measurements of properties of i ...
. The difference between the electron's cyclotron frequency and its spin precession frequency in a magnetic field is proportional to ''g''−2. An extremely high precision measurement of the quantized energies of the cyclotron orbits, or '' Landau levels'', of the electron, compared to the quantized energies of the electron's two possible
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally b ...
orientations, gives a value for the electron's spin ''g''-factor: : ''g''/2 = , a precision of better than one part in a trillion. (The digits in parentheses indicate the
standard uncertainty Uncertainty refers to epistemic situations involving imperfect or unknown information. It applies to predictions of future events, to physical measurements that are already made, or to the unknown. Uncertainty arises in partially observable or ...
in the last listed digits of the measurement.) The current state-of-the-art theoretical calculation of the anomalous magnetic dipole moment of the electron includes QED diagrams with up to four loops. Combining this with the experimental measurement of ''g'' yields the most precise value of ''α'': : ''α''−1 = , a precision of better than a part in a billion. This uncertainty is ten times smaller than the nearest rival method involving atom-recoil measurements. A value of ''α'' can also be extracted from the anomalous magnetic dipole moment of the
muon A muon ( ; from the Greek letter mu (μ) used to represent it) is an elementary particle similar to the electron, with an electric charge of −1 '' e'' and a spin of , but with a much greater mass. It is classified as a lepton. As ...
. The ''g''-factor of the muon is extracted using the same physical principle as for the electron above – namely, that the difference between the cyclotron frequency and the spin precession frequency in a magnetic field is proportional to ''g''−2. The most precise measurement comes from
Brookhaven National Laboratory Brookhaven National Laboratory (BNL) is a United States Department of Energy national laboratory located in Upton, Long Island, and was formally established in 1947 at the site of Camp Upton, a former U.S. Army base and Japanese internment c ...
's muon g−2 experiment, in which polarized muons are stored in a cyclotron and their spin orientation is measured by the direction of their decay electrons. As of February 2007, the current world average muon ''g''-factor measurement is, : ''g''/2 = , a precision of better than one part in a billion. The difference between the ''g''-factors of the muon and the electron is due to their difference in mass. Because of the muon's larger mass, contributions to the theoretical calculation of its anomalous magnetic dipole moment from
Standard Model The Standard Model of particle physics is the theory describing three of the four known fundamental forces ( electromagnetic, weak and strong interactions - excluding gravity) in the universe and classifying all known elementary particles. It ...
weak interactions and from contributions involving
hadrons In particle physics, a hadron (; grc, ἁδρός, hadrós; "stout, thick") is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules that are held together by the ele ...
are important at the current level of precision, whereas these effects are not important for the electron. The muon's anomalous magnetic dipole moment is also sensitive to contributions from new physics beyond the Standard Model, such as
supersymmetry In a supersymmetric theory the equations for force and the equations for matter are identical. In theoretical and mathematical physics, any theory with this property has the principle of supersymmetry (SUSY). Dozens of supersymmetric theories ...
. For this reason, the muon's anomalous magnetic moment is normally used as a probe for new physics beyond the Standard Model rather than as a test of QED. ''See'' muon ''g''–2 for current efforts to refine the measurement.


Atom-recoil measurements

This is an indirect method of measuring ''α'', based on measurements of the masses of the electron, certain atoms, and the
Rydberg constant In spectroscopy, the Rydberg constant, symbol R_\infty for heavy atoms or R_\text for hydrogen, named after the Swedish physicist Johannes Rydberg, is a physical constant relating to the electromagnetic spectra of an atom. The constant first a ...
. The Rydberg constant is known to seven parts in a trillion. The mass of the electron relative to that of
caesium Caesium ( IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...
and
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
atoms is also known with extremely high precision. If the mass of the electron can be measured with sufficiently high precision, then ''α'' can be found from the Rydberg constant according to :R_\infty = \frac. To get the mass of the electron, this method actually measures the mass of an 87 Rb atom by measuring the recoil speed of the atom after it emits a photon of known wavelength in an atomic transition. Combining this with the ratio of electron to 87Rb atom, the result for ''α'' is, : ''α''−1 = . Because this measurement is the next-most-precise after the measurement of ''α'' from the electron's anomalous magnetic dipole moment described above, their comparison provides the most stringent test of QED: the value of ''α'' obtained here is within one standard deviation of that found from the electron's anomalous magnetic dipole moment, an agreement to within ten parts in a billion.


Neutron Compton wavelength

This method of measuring ''α'' is very similar in principle to the atom-recoil method. In this case, the accurately known mass ratio of the electron to the
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons beha ...
is used. The neutron mass is measured with high precision through a very precise measurement of its
Compton wavelength The Compton wavelength is a quantum mechanical property of a particle. The Compton wavelength of a particle is equal to the wavelength of a photon whose energy is the same as the rest energy of that particle (see mass–energy equivalence). It wa ...
. This is then combined with the value of the Rydberg constant to extract ''α''. The result is, : ''α''−1 = .


Hyperfine splitting

Hyperfine splitting In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate energy levels and the resulting splittings in those energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the nuc ...
is a splitting in the energy levels of an
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, ...
caused by the interaction between the
magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagnets ...
of the
nucleus Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to: *Atomic nucleus, the very dense central region of an atom *Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA Nucle ...
and the combined
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally b ...
and orbital magnetic moment of the electron. The hyperfine splitting in
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxi ...
, measured using Ramsey's hydrogen maser, is known with great precision. Unfortunately, the influence of the
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mas ...
's internal structure limits how precisely the splitting can be predicted theoretically. This leads to the extracted value of ''α'' being dominated by theoretical uncertainty: : ''α''−1 = . The hyperfine splitting in
muonium Muonium is an exotic atom made up of an antimuon and an electron, which was discovered in 1960 by Vernon W. Hughes and is given the chemical symbol Mu. During the muon's lifetime, muonium can undergo chemical reactions. Due to the mass diff ...
, an "atom" consisting of an electron and an antimuon, provides a more precise measurement of ''α'' because the muon has no internal structure: : ''α''−1 = .


Lamb shift

The
Lamb shift In physics, the Lamb shift, named after Willis Lamb, is a difference in energy between two energy levels 2''S''1/2 and 2''P''1/2 (in term symbol notation) of the hydrogen atom which was not predicted by the Dirac equation, according to which th ...
is a small difference in the energies of the 2 S1/2 and 2 P1/2 energy levels of hydrogen, which arises from a one-loop effect in quantum electrodynamics. The Lamb shift is proportional to ''α''5 and its measurement yields the extracted value: : ''α''−1 = .


Positronium

Positronium Positronium (Ps) is a system consisting of an electron and its anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two particles annihi ...
is an "atom" consisting of an electron and a
positron The positron or antielectron is the antiparticle or the antimatter counterpart of the electron. It has an electric charge of +1 '' e'', a spin of 1/2 (the same as the electron), and the same mass as an electron. When a positron collides ...
. Whereas the calculation of the energy levels of ordinary hydrogen is contaminated by theoretical uncertainties from the proton's internal structure, the particles that make up positronium have no internal structure so precise theoretical calculations can be performed. The measurement of the splitting between the 2 3S1 and the 1 3S1 energy levels of positronium yields : ''α''−1 = . Measurements of ''α'' can also be extracted from the positronium decay rate. Positronium decays through the annihilation of the electron and the positron into two or more
gamma-ray A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically ...
photons. The decay rate of the singlet ("para-positronium") 1S0 state yields : ''α''−1 = , and the decay rate of the triplet ("ortho-positronium") 3S1 state yields : ''α''−1 = . This last result is the only serious discrepancy among the numbers given here, but there is some evidence that uncalculated higher-order quantum corrections give a large correction to the value quoted here.


High-energy QED processes

The cross sections of higher-order QED reactions at high-energy electron-positron colliders provide a determination of ''α''. In order to compare the extracted value of ''α'' with the low-energy results, higher-order QED effects including the running of ''α'' due to vacuum polarization must be taken into account. These experiments typically achieve only percent-level accuracy, but their results are consistent with the precise measurements available at lower energies. The cross section for e^+e^- \to e^+e^-e^+e^- yields : ''α''−1 = , and the cross section for e^+e^- \to e^+e^- \mu ^+\mu ^- yields : ''α''−1 = .


Condensed matter systems

The
quantum Hall effect The quantum Hall effect (or integer quantum Hall effect) is a quantized version of the Hall effect which is observed in two-dimensional electron systems subjected to low temperatures and strong magnetic fields, in which the Hall resistance exhi ...
and the AC
Josephson effect In physics, the Josephson effect is a phenomenon that occurs when two superconductors are placed in proximity, with some barrier or restriction between them. It is an example of a macroscopic quantum phenomenon, where the effects of quantum me ...
are exotic quantum interference phenomena in condensed matter systems. These two effects provide a standard
electrical resistance The electrical resistance of an object is a measure of its opposition to the flow of electric current. Its reciprocal quantity is , measuring the ease with which an electric current passes. Electrical resistance shares some conceptual parallel ...
and a standard
frequency Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is e ...
, respectively, which measure the charge of the electron with corrections that are strictly zero for macroscopic systems. The quantum Hall effect yields : ''α''−1 = , and the AC Josephson effect yields : ''α''−1 = .


Other tests

*QED predicts that the
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are Massless particle, massless ...
is a
massless particle In particle physics, a massless particle is an elementary particle whose invariant mass is zero. There are two known gauge boson massless particles: the photon (carrier of electromagnetism) and the gluon (carrier of the strong force). However, gl ...
. A variety of highly sensitive tests have proven that the photon mass is either zero, or else extraordinarily small. One type of these tests, for example, works by checking
Coulomb's law Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is convention ...
at high accuracy, as the photon's mass would be nonzero if Coulomb's law were modified. See '. *QED predicts that when electrons get very close to each other, they behave as if they had a higher electric charge, due to vacuum polarization. This prediction was experimentally verified in 1997 using the
TRISTAN Tristan (Latin/ Brythonic: ''Drustanus''; cy, Trystan), also known as Tristram or Tristain and similar names, is the hero of the legend of Tristan and Iseult. In the legend, he is tasked with escorting the Irish princess Iseult to wed ...
particle accelerator in Japan. *QED effects like vacuum polarization and
self-energy In quantum field theory, the energy that a particle has as a result of changes that it causes in its environment defines self-energy \Sigma, and represents the contribution to the particle's energy, or effective mass, due to interactions betwee ...
influence the electrons bound to a nucleus in a heavy atom due to extreme electromagnetic fields. A recent experiment on the ground state hyperfine splitting in 209Bi80+ and 209Bi82+ ions revealed a deviation from the theory by more than 7 standard uncertainties. Indications show that this deviation may originate from a wrong value of the
nuclear magnetic moment The nuclear magnetic moment is the magnetic moment of an atomic nucleus and arises from the spin of the protons and neutrons. It is mainly a magnetic dipole moment; the quadrupole moment does cause some small shifts in the hyperfine structure a ...
of 209Bi.


See also

* QED vacuum * Eötvös experiment, another very high accuracy test, of gravitation


References


External links


Particle Data Group (PDG)PDG Review of the Muon Anomalous Magnetic Moment as of July 2007PDG 2007 Listing of particle properties for electronPDG 2007 Listing of particle properties for muon
{{QED Quantum electrodynamics Electrodynamics