TAS stands for Total Alkali Silica. The TAS classification can be used to assign names to many common types of
volcanic rock
Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and me ...
s based upon the relationships between the combined
alkali
In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The a ...
and
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
contents. These chemical parameters are useful because the relative proportions of alkalis and silica are important in determining both
normative mineralogy and actual mineralogy. The classification can be simple to use for rocks that have been chemically analyzed. Except for the following quotation from Johannsen (1937), this discussion is based upon Le Maitre et al (2002).
Use of the TAS classification
Before using the TAS or any other classification, some particular guidance by Johannsen (1937) should be kept in mind.
:''Many and peculiar are the classifications that have been proposed for igneous rocks. Their variability depends in part upon the purpose for which each was intended, and in part upon the difficulties arising from the characters of the rocks themselves. The trouble is not with the classifications but with nature which did not make things right. … Rocks must be classified in order to compare them with others, previously described, of similar composition and appearance. If this cannot be done on a genetic basis, then an artificial system must answer in order to serve as a card index to rock descriptions. Although this may be an evil thing, it is, at least, the least of several evils.''
(The subtitle of the classification chapter by Johannsen (1937) is "Chacun a son goût"to each his own taste).
The TAS classification cannot be applied to all volcanic rocksas discussed in detail by Le Maitre et al (2002). Certain rocks cannot be classified/named using the diagram. For others, additional chemical, mineralogic, or
textural criteria must be used, as e.g.
lamprophyre
Lamprophyres () are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica- undersaturated mafic or ultramafic rocks with high magnesium o ...
s.
The TAS classification should be applied only to rocks for which the mineral mode analysis cannot be determined. Otherwise, a scheme based on mineralogy, such as the
QAPF diagram
A QAPF diagram is a doubled-triangle plot diagram used to classify igneous rocks based on their mineralogy. The acronym QAPF stands for "quartz, alkali feldspar, plagioclase, feldspathoid (foid)", which are the four mineral groups used for clas ...
, or one of the other diagrams available for
igneous rock
Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.
The magma can be derived from partial ...
s may be suitable. Before classifying rocks using the TAS diagram, the chemical analyses must be recalculated to 100% excluding water and carbon dioxide.
The TAS diagram
The names provided by Le Maitre et al. (2002) for fields in the TAS diagram are listed below.
B (
Basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
)Use
normative mineralogy to subdivide.
O1 (
Basaltic andesite)
O2 (
Andesite
Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomina ...
)
O3 (
Dacite
Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...
)
R (
Rhyolite
Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture (geology), texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained matri ...
)
T (
Trachyte
Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanite, aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava (or shallow intrus ...
or Trachydacite)Use normative mineralogy to decide.
Ph (
Phonolite)
S1 (
Trachybasalt
Trachybasalt is a volcanic rock with a composition between trachyte and basalt. It resembles basalt but has a high content of alkali metal oxides. Minerals in trachybasalt include alkali feldspar, calcic plagioclase, olivine, clinopyroxene and l ...
)*Sodic and potassic variants are
Hawaiite
Hawaiite is an olivine basalt with a composition between alkali basalt and mugearite. It was first used as a name for some lavas found on the island of Hawaii.
It occurs during the later stages of volcanic activity on oceanic islands such as Ha ...
and Potassic Trachybasalt.
S2 (Basaltic trachyandesite)*Sodic and potassic variants are
Mugearite
Mugearite () is a type of oligoclase-bearing basalt, comprising olivine, apatite, and opaque oxides. The main feldspar in mugearite is oligoclase.
Mugearite is a sodium-rich member of the alkaline magma series. In the TAS classification of volc ...
and
Shoshonite.
S3 (
Trachyandesite*Sodic and potassic variants are
Benmoreite and
Latite.
Pc (
Picrobasalt)
U1 (
Basanite or
Tephrite)Use normative mineralogy to decide.
U2 (
Phonotephrite)
U3 (
Tephriphonolite)
F (
Foidite)When possible, classify/name according to the dominant
feldspathoid
The feldspathoids are a group of tectosilicate minerals which resemble feldspar
Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, pota ...
.
Melilitites also plot in this area and can be distinguished by additional chemical criteria.
:(*)Sodic as used above means that Na
2O - 2 is greater than K
2O, and potassic that Na
2O - 2 is less than K
2O. Yet other names have been applied to rocks particularly rich in either sodium or potassiumas are
ultrapotassic igneous rocks
Ultrapotassic igneous rocks are a class of rare, volumetrically minor, generally ultramafic or mafic silica-depleted igneous rocks.
While there are debates on the exact classifications of ultrapotassic rocks, they are defined by using the chemic ...
.
References
*Albert Johannsen, A Descriptive Petrography of the Igneous Rocks. Volume 1, Introduction, Textures, Classifications, and Glossary. The University of Chicago Press, Chicago, Illinois, 1937.
*R. W. Le Maitre (editor), A. Streckeisen, B. Zanettin, M. J. Le Bas, B. Bonin, P. Bateman, G. Bellieni, A. Dudek, S. Efremova, J. Keller, J. Lamere, P. A. Sabine, R. Schmid, H. Sorensen, and A. R. Woolley, Igneous Rocks: A Classification and Glossary of Terms, Recommendations of the International Union of Geological Sciences, Subcommission of the Systematics of Igneous Rocks. Cambridge University Press, 2002.
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Igneous petrology
Igneous rocks