Superconductivity is a set of physical properties observed in superconductors: materials where
electrical resistance
The electrical resistance of an object is a measure of its opposition to the flow of electric current. Its reciprocal quantity is , measuring the ease with which an electric current passes. Electrical resistance shares some conceptual paral ...
vanishes and
magnetic fields are expelled from the material. Unlike an ordinary metallic
conductor, whose resistance decreases gradually as its temperature is lowered, even down to near
absolute zero
Absolute zero is the lowest possible temperature, a state at which a system's internal energy, and in ideal cases entropy, reach their minimum values. The absolute zero is defined as 0 K on the Kelvin scale, equivalent to −273.15 ° ...
, a superconductor has a characteristic
critical temperature
Critical or Critically may refer to:
*Critical, or critical but stable, medical states
**Critical, or intensive care medicine
*Critical juncture, a discontinuous change studied in the social sciences.
*Critical Software, a company specializing in ...
below which the resistance drops abruptly to zero.
An
electric current
An electric current is a flow of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is defined as the net rate of flow of electric charge through a surface. The moving particles are called charge c ...
through a loop of
superconducting wire can persist indefinitely with no power source.
The superconductivity phenomenon was discovered in 1911 by Dutch physicist
Heike Kamerlingh Onnes. Like
ferromagnetism
Ferromagnetism is a property of certain materials (such as iron) that results in a significant, observable magnetic permeability, and in many cases, a significant magnetic coercivity, allowing the material to form a permanent magnet. Ferromagne ...
and
atomic spectral lines, superconductivity is a phenomenon which can only be explained by
quantum mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
. It is characterized by the
Meissner effect, the complete cancellation of the magnetic field in the interior of the superconductor during its transitions into the superconducting state. The occurrence of the Meissner effect indicates that superconductivity cannot be understood simply as the
idealization of ''
perfect conductivity'' in
classical physics
Classical physics refers to physics theories that are non-quantum or both non-quantum and non-relativistic, depending on the context. In historical discussions, ''classical physics'' refers to pre-1900 physics, while '' modern physics'' refers to ...
.
In 1986, it was discovered that some
cuprate-
perovskite ceramic materials have a critical temperature above .
It was shortly found (by
Ching-Wu Chu) that replacing the lanthanum with
yttrium
Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
, i.e. making
YBCO, raised the critical temperature to , which was important because
liquid nitrogen
Liquid nitrogen (LN2) is nitrogen in a liquid state at cryogenics, low temperature. Liquid nitrogen has a boiling point of about . It is produced industrially by fractional distillation of liquid air. It is a colorless, mobile liquid whose vis ...
could then be used as a refrigerant. Such a high transition temperature is theoretically impossible for a
conventional superconductor, leading the materials to be termed
high-temperature superconductors. The cheaply available coolant
liquid nitrogen
Liquid nitrogen (LN2) is nitrogen in a liquid state at cryogenics, low temperature. Liquid nitrogen has a boiling point of about . It is produced industrially by fractional distillation of liquid air. It is a colorless, mobile liquid whose vis ...
boils at and thus the existence of superconductivity at higher temperatures than this facilitates many experiments and applications that are less practical at lower temperatures.
History

Superconductivity was discovered on April 8, 1911, by Heike Kamerlingh Onnes, who was studying the resistance of solid mercury at
cryogenic temperatures using the recently produced
liquid helium as a
refrigerant. At the temperature of 4.2 K, he observed that the resistance abruptly disappeared. In the same experiment, he also observed the
superfluid
Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortex, vortices that continue to rotate indefinitely. Superfluidity occurs ...
transition of helium at 2.2 K, without recognizing its significance. The precise date and circumstances of the discovery were only reconstructed a century later, when Onnes's notebook was found. In subsequent decades, superconductivity was observed in several other materials. In 1913,
lead
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
was found to superconduct at 7 K, and in 1941
niobium nitride was found to superconduct at 16 K.
Great efforts have been devoted to finding out how and why superconductivity works; the important step occurred in 1933, when
Meissner and
Ochsenfeld discovered that superconductors expelled applied magnetic fields, a phenomenon which has come to be known as the Meissner effect.
In 1935,
Fritz
Fritz is a common German language, German male name. The name originated as a German diminutive of Friedrich (given name), Friedrich or Frederick (given name), Frederick (''Der Alte Fritz'', and ''Stary Fryc'' were common nicknames for King Fred ...
and
Heinz London showed that the Meissner effect was a consequence of the minimization of the electromagnetic
free energy carried by superconducting current.
London constitutive equations
The theoretical model that was first conceived for superconductivity was completely classical: it is summarized by
London constitutive equations. It was put forward by the brothers Fritz and Heinz London in 1935, shortly after the discovery that magnetic fields are expelled from superconductors. A major triumph of the equations of this theory is their ability to explain the Meissner effect,
wherein a material exponentially expels all internal magnetic fields as it crosses the superconducting threshold. By using the London equation, one can obtain the dependence of the magnetic field inside the superconductor on the distance to the surface.
The two constitutive equations for a superconductor by London are:
The first equation follows from
Newton's second law for superconducting electrons.
Conventional theories (1950s)
During the 1950s, theoretical
condensed matter physicists arrived at an understanding of "conventional" superconductivity, through a pair of remarkable and important theories: the phenomenological
Ginzburg–Landau theory (1950) and the microscopic BCS theory (1957).
In 1950, the
phenomenological Ginzburg–Landau theory of superconductivity was devised by
Landau and
Ginzburg. This theory, which combined Landau's theory of second-order phase transitions with a
Schrödinger-like wave equation, had great success in explaining the macroscopic properties of superconductors. In particular,
Abrikosov showed that Ginzburg–Landau theory predicts the division of superconductors into the two categories now referred to as Type I and Type II. Abrikosov and Ginzburg were awarded the 2003 Nobel Prize for their work (Landau had received the 1962 Nobel Prize for other work, and died in 1968). The four-dimensional extension of the Ginzburg–Landau theory, the
Coleman-Weinberg model, is important in
quantum field theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct phy ...
and
cosmology
Cosmology () is a branch of physics and metaphysics dealing with the nature of the universe, the cosmos. The term ''cosmology'' was first used in English in 1656 in Thomas Blount's ''Glossographia'', with the meaning of "a speaking of the wo ...
.
Also in 1950, Maxwell and Reynolds et al. found that the critical temperature of a superconductor depends on the
isotopic mass of the constituent element. This important discovery pointed to the
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
–
phonon interaction as the microscopic mechanism responsible for superconductivity.
The complete microscopic theory of superconductivity was finally proposed in 1957 by
Bardeen,
Cooper and
Schrieffer.
This BCS theory explained the superconducting current as a superfluid of Cooper pairs, pairs of electrons interacting through the exchange of phonons. For this work, the authors were awarded the Nobel Prize in 1972.
The BCS theory was set on a firmer footing in 1958, when
N. N. Bogolyubov showed that the BCS wavefunction, which had originally been derived from a variational argument, could be obtained using a canonical transformation of the electronic
Hamiltonian
Hamiltonian may refer to:
* Hamiltonian mechanics, a function that represents the total energy of a system
* Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system
** Dyall Hamiltonian, a modified Hamiltonian ...
. In 1959,
Lev Gor'kov showed that the BCS theory reduced to the Ginzburg–Landau theory close to the critical temperature.
Generalizations of BCS theory for conventional superconductors form the basis for the understanding of the phenomenon of
superfluidity, because they fall into the
lambda transition universality class. The extent to which such generalizations can be applied to
unconventional superconductors is still controversial.
Niobium
The first practical application of superconductivity was developed in 1954 with
Dudley Allen Buck's invention of the
cryotron.
Two superconductors with greatly different values of the critical magnetic field are combined to produce a fast, simple switch for computer elements.
Soon after discovering superconductivity in 1911, Kamerlingh Onnes attempted to make an electromagnet with superconducting windings but found that relatively low magnetic fields destroyed superconductivity in the materials he investigated. Much later, in 1955, G. B. Yntema succeeded in constructing a small 0.7-tesla iron-core electromagnet with superconducting niobium wire windings. Then, in 1961,
J. E. Kunzler, E. Buehler, F. S. L. Hsu, and J. H. Wernick made the startling discovery that, at 4.2 kelvin,
niobium–tin, a compound consisting of three parts niobium and one part tin, was capable of supporting a current density of more than 100,000 amperes per square centimeter in a magnetic field of 8.8 tesla. The alloy was brittle and difficult to fabricate, but niobium–tin proved useful for generating magnetic fields as high as 20 tesla.
In 1962, T. G. Berlincourt and R. R. Hake discovered that more ductile alloys of niobium and titanium are suitable for applications up to 10 tesla. Commercial production of
niobium–titanium supermagnet wire immediately commenced at
Westinghouse Electric Corporation and at
Wah Chang Corporation. Although niobium–titanium boasts less-impressive superconducting properties than those of niobium–tin, niobium–titanium became the most widely used "workhorse" supermagnet material, in large measure a consequence of its very high
ductility
Ductility refers to the ability of a material to sustain significant plastic Deformation (engineering), deformation before fracture. Plastic deformation is the permanent distortion of a material under applied stress, as opposed to elastic def ...
and ease of fabrication. However, both niobium–tin and niobium–titanium found wide application in MRI medical imagers, bending and focusing magnets for enormous high-energy-particle accelerators, and other applications. Conectus, a European superconductivity consortium, estimated that in 2014, global economic activity for which superconductivity was indispensable amounted to about five billion euros, with MRI systems accounting for about 80% of that total.
Josephson effect
In 1962,
Josephson made the important theoretical prediction that a supercurrent can flow between two pieces of superconductor separated by a thin layer of insulator. This phenomenon, now called the
Josephson effect, is exploited by superconducting devices such as
SQUIDs. It is used in the most accurate available measurements of the
magnetic flux quantum ''Φ''
0 = ''h''/(2''e''), where ''h'' is the
Planck constant. Coupled with the
quantum Hall resistivity, this leads to a precise measurement of the Planck constant. Josephson was awarded the Nobel Prize for this work in 1973.
In 2008, it was proposed that the same mechanism that produces superconductivity could produce a
superinsulator state in some materials, with almost infinite
electrical resistance
The electrical resistance of an object is a measure of its opposition to the flow of electric current. Its reciprocal quantity is , measuring the ease with which an electric current passes. Electrical resistance shares some conceptual paral ...
. The first development and study of superconducting
Bose–Einstein condensate
In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low Density, densities is cooled to temperatures very close to absolute zero#Relation with Bose–Einste ...
(BEC) in 2020 suggested a "smooth transition between" BEC and
Bardeen-Cooper-Shrieffer regimes.
2D materials
Multiple types of superconductivity are reported in devices made of
single-layer materials. Some of these materials can switch between conducting, insulating, and other behaviors.
Twisting materials imbues them with a “
moiré” pattern involving tiled hexagonal cells that act like atoms and host electrons. In this environment, the electrons move slowly enough for their collective interactions to guide their behavior. When each cell has a single electron, the electrons take on an antiferromagnetic arrangement; each electron can have a preferred location and magnetic orientation. Their intrinsic magnetic fields tend to alternate between pointing up and down. Adding electrons allows superconductivity by causing Cooper pairs to form. Fu and Schrade argued that electron-on-electron action was allowing both antiferromagnetic and superconducting states.
The first success with 2D materials involved a twisted bilayer graphene sheet (2018, Tc ~1.7 K, 1.1° twist). A twisted three-layer graphene device was later shown to superconduct (2021, Tc ~2.8 K). Then an untwisted trilayer graphene device was reported to superconduct (2022, Tc 1-2 K). The latter was later shown to be tunable, easily reproducing behavior found in millions of other configurations. Directly observing what happens when electrons are added to a material or slightly weakening its electric field enables quick testing of an unprecedented number of recipes to see which lead to superconductivity.
These devices have applications in
quantum computing
A quantum computer is a computer that exploits quantum mechanical phenomena. On small scales, physical matter exhibits properties of wave-particle duality, both particles and waves, and quantum computing takes advantage of this behavior using s ...
.
2D materials other than graphene have also been made to superconduct.
Transition metal dichalcogenide (TMD) sheets twisted at 5 degrees intermittently achieved superconduction by creating a Josephson junction. The device used used thin layers of
palladium to connect to the sides of a
tungsten telluride layer surrounded and protected by
boron nitride. Another group demonstrated superconduction in
molybdenum telluride (MoTe₂) in 2D
van der Waals materials using ferroelectric domain walls. The Tc was implied to be higher than typical TMDs (~5–10 K).
A Cornell group added a 3.5-degree twist to an insulator that allowed electrons to slow down and interact strongly, leaving one electron per cell, exhibiting superconduction. Existing theories do not explain this behavior.
Fu and collaborators proposed that electrons arrange to form a repeating crystal that allows the electron grid to float independently of the background atomic nuclei and the electron grid to relax. Its ripples pair electrons the way phonons do, although this is unconfirmed.
Classification
Superconductors are classified according to many criteria. The most common are:
Response to a magnetic field
A superconductor can be ''
Type I'', meaning it has a single
critical field, above which superconductivity is lost and below which the magnetic field is completely expelled from the superconductor; or ''
Type II'', meaning it has two critical fields, between which it allows partial penetration of the magnetic field through isolated points called
vortices. Furthermore, in multicomponent superconductors it is possible to combine the two behaviours. In that case the superconductor is of
Type-1.5.
Theory of operation
A superconductor is ''
conventional'' if it is driven by electron–phonon interaction and explained by the
BCS theory or its extension, the Eliashberg theory. Otherwise, it is ''
unconventional''. Alternatively, a superconductor is called unconventional if the superconducting
order parameter transforms according to a non-trivial
irreducible representation of the system's
point group or
space group.
Critical temperature
A superconductor is generally considered ''
high-temperature'' if it reaches a superconducting state above a temperature of 30 K (−243.15 °C); as in the initial discovery by
Georg Bednorz and
K. Alex Müller.
It may also reference materials that transition to superconductivity when cooled using
liquid nitrogen
Liquid nitrogen (LN2) is nitrogen in a liquid state at cryogenics, low temperature. Liquid nitrogen has a boiling point of about . It is produced industrially by fractional distillation of liquid air. It is a colorless, mobile liquid whose vis ...
– that is, at only ''T''
c > 77 K, although this is generally used only to emphasize that liquid nitrogen coolant is sufficient. Low temperature superconductors refer to materials with a critical temperature below 30 K, and are cooled mainly by
liquid helium (''T''
c > 4.2 K). One exception to this rule is the
iron pnictide group of superconductors that display behaviour and properties typical of high-temperature superconductors, yet some of the group have critical temperatures below 30 K.
Material

Superconductor material classes include
chemical elements
A chemical element is a chemical substance whose atoms all have the same number of protons. The number of protons is called the atomic number of that element. For example, oxygen has an atomic number of 8: each oxygen atom has 8 protons in i ...
(e.g.
mercury or
lead
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
),
alloys (such as
niobium–titanium,
germanium–niobium, and
niobium nitride),
ceramics (
YBCO and
magnesium diboride),
superconducting pnictides (like fluorine-doped LaOFeAs),
single-layer materials such as
graphene and
transition metal dichalcogenides, or
organic superconductors (
fullerenes and
carbon nanotubes
A carbon nanotube (CNT) is a tube made of carbon with a diameter in the nanometre range (nanoscale). They are one of the allotropes of carbon. Two broad classes of carbon nanotubes are recognized:
* ''Single-walled carbon nanotubes'' (''SWC ...
; though perhaps these examples should be included among the chemical elements, as they are composed entirely of
carbon
Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
).
Elementary properties
Several physical properties of superconductors vary from material to material, such as the critical temperature, the value of the
superconducting gap, the critical magnetic field, and the critical current density at which superconductivity is destroyed. On the other hand, there is a class of properties that are independent of the underlying material. The Meissner effect, the quantization of the
magnetic flux or permanent currents, i.e. the state of zero resistance are the most important examples. The existence of these "universal" properties is rooted in the nature of the
broken symmetry of the superconductor and the emergence of
off-diagonal long range order. Superconductivity is a
thermodynamic phase, and thus possesses certain distinguishing properties which are largely independent of microscopic details. Off diagonal long range order is closely connected to the formation of
Cooper pairs.
Zero electrical DC resistance

The simplest method to measure the
electrical resistance
The electrical resistance of an object is a measure of its opposition to the flow of electric current. Its reciprocal quantity is , measuring the ease with which an electric current passes. Electrical resistance shares some conceptual paral ...
of a sample of some material is to place it in an
electrical circuit
An electrical network is an interconnection of electrical components (e.g., battery (electricity), batteries, resistors, inductors, capacitors, switches, transistors) or a model of such an interconnection, consisting of electrical elements (e. ...
in series with a
current source ''I'' and measure the resulting
voltage
Voltage, also known as (electrical) potential difference, electric pressure, or electric tension, is the difference in electric potential between two points. In a Electrostatics, static electric field, it corresponds to the Work (electrical), ...
''V'' across the sample. The resistance of the sample is given by
Ohm's law
Ohm's law states that the electric current through a Electrical conductor, conductor between two Node (circuits), points is directly Proportionality (mathematics), proportional to the voltage across the two points. Introducing the constant of ...
as ''R = V / I''. If the voltage is zero, this means that the resistance is zero.
Superconductors are also able to maintain a current with no applied voltage whatsoever, a property exploited in
superconducting electromagnets such as those found in
MRI machines. Experiments have demonstrated that currents in superconducting coils can persist for years without any measurable degradation. Experimental evidence points to a lifetime of at least 100,000 years. Theoretical estimates for the lifetime of a persistent current can exceed the estimated lifetime of the universe, depending on the wire geometry and the temperature.
In practice, currents injected in superconducting coils persisted for 28 years, 7 months, 27 days in a superconducting gravimeter in Belgium, from August 4, 1995 until March 31, 2024. In such instruments, the measurement is based on the monitoring of the levitation of a superconducting niobium sphere with a mass of four grams.
In a normal conductor, an electric current may be visualized as a fluid of
electrons
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
moving across a heavy ionic lattice. The electrons are constantly colliding with the ions in the lattice, and during each collision some of the energy carried by the current is absorbed by the lattice and converted into
heat, which is essentially the vibrational
kinetic energy
In physics, the kinetic energy of an object is the form of energy that it possesses due to its motion.
In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2.Resnick, Rober ...
of the lattice ions. As a result, the energy carried by the current is constantly being dissipated. This is the phenomenon of electrical resistance and
Joule heating.
The situation is different in a superconductor. In a conventional superconductor, the electronic fluid cannot be resolved into individual electrons. Instead, it consists of bound ''pairs'' of electrons known as
Cooper pairs. This pairing is caused by an attractive force between electrons from the exchange of
phonons. This pairing is very weak, and small thermal vibrations can fracture the bond. Due to
quantum mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
, the
energy spectrum of this Cooper pair fluid possesses an ''
energy gap'', meaning there is a minimum amount of energy Δ''E'' that must be supplied in order to excite the fluid. Therefore, if Δ''E'' is larger than the
thermal energy
The term "thermal energy" is often used ambiguously in physics and engineering. It can denote several different physical concepts, including:
* Internal energy: The energy contained within a body of matter or radiation, excluding the potential en ...
of the lattice, given by ''kT'', where ''k'' is the
Boltzmann constant and ''T'' is the
temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
, the fluid will not be scattered by the lattice. The Cooper pair fluid is thus a
superfluid
Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortex, vortices that continue to rotate indefinitely. Superfluidity occurs ...
, meaning it can flow without energy dissipation.
In the class of superconductors known as
type II superconductors, including all known
high-temperature superconductors, an extremely low but non-zero resistivity appears at temperatures not too far below the nominal superconducting transition when an electric current is applied in conjunction with a strong magnetic field, which may be caused by the electric current. This is due to the motion of
magnetic vortices in the electronic superfluid, which dissipates some of the energy carried by the current. If the current is sufficiently small, the vortices are stationary, and the resistivity vanishes. The resistance due to this effect is minuscule compared with that of non-superconducting materials, but must be taken into account in sensitive experiments. However, as the temperature decreases far enough below the nominal superconducting transition, these vortices can become frozen into a disordered but stationary phase known as a "vortex glass". Below this vortex glass transition temperature, the resistance of the material becomes truly zero.
Phase transition

In superconducting materials, the characteristics of superconductivity appear when the temperature ''T'' is lowered below a critical temperature ''T''
c. The value of this critical temperature varies from material to material. Conventional superconductors usually have critical temperatures ranging from around 20
K to less than 1 K. Solid
mercury, for example, has a critical temperature of 4.2 K. As of 2015, the highest critical temperature found for a conventional superconductor is 203 K for H
2S, although high pressures of approximately 90 gigapascals were required.
Cuprate superconductors can have much higher critical temperatures:
YBa2Cu3O7, one of the first cuprate superconductors to be discovered, has a critical temperature above 90 K, and mercury-based cuprates have been found with critical temperatures in excess of 130 K. The basic physical mechanism responsible for the high critical temperature is not yet clear. However, it is clear that a two-electron pairing is involved, although the nature of the pairing (
wave vs.
wave) remains controversial.
Similarly, at a fixed temperature below the critical temperature, superconducting materials cease to superconduct when an external
magnetic field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
is applied which is greater than the ''critical magnetic field''. This is because the
Gibbs free energy of the superconducting phase increases quadratically with the magnetic field while the free energy of the normal phase is roughly independent of the magnetic field. If the material superconducts in the absence of a field, then the superconducting phase free energy is lower than that of the normal phase and so for some finite value of the magnetic field (proportional to the square root of the difference of the free energies at zero magnetic field) the two free energies will be equal and a phase transition to the normal phase will occur. More generally, a higher temperature and a stronger magnetic field lead to a smaller fraction of electrons that are superconducting and consequently to a longer
London penetration depth of external magnetic fields and currents. The penetration depth becomes infinite at the phase transition.
The onset of superconductivity is accompanied by abrupt changes in various physical properties, which is the hallmark of a
phase transition
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic Sta ...
. For example, the electronic
heat capacity is proportional to the temperature in the normal (non-superconducting) regime. At the superconducting transition, it suffers a discontinuous jump and thereafter ceases to be linear. At low temperatures, it varies instead as ''e''
−''α''/''T'' for some constant, ''α''. This exponential behavior is one of the pieces of evidence for the existence of the
energy gap.
The
order of the superconducting
phase transition
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic Sta ...
was long a matter of debate. Experiments indicate that the transition is second-order, meaning there is no
latent heat. However, in the presence of an external magnetic field there is latent heat, because the superconducting phase has a lower entropy below the critical temperature than the normal phase. It has been experimentally demonstrated that, as a consequence, when the magnetic field is increased beyond the critical field, the resulting phase transition leads to a decrease in the temperature of the superconducting material.
Calculations in the 1970s suggested that it may actually be weakly first-order due to the effect of long-range fluctuations in the electromagnetic field. In the 1980s it was shown theoretically with the help of a
disorder field theory, in which the
vortex lines of the superconductor play a major role, that the transition is of second order within the
type II regime and of first order (i.e.,
latent heat) within the
type I regime, and that the two regions are separated by a
tricritical point. The results were strongly supported by Monte Carlo computer simulations.
Meissner effect
When a superconductor is placed in a weak external magnetic field ''H'', and cooled below its transition temperature, the magnetic field is ejected. The Meissner effect does not cause the field to be completely ejected but instead, the field penetrates the superconductor but only to a very small distance, characterized by a parameter ''λ'', called the
London penetration depth, decaying exponentially to zero within the bulk of the material. The Meissner effect is a defining characteristic of superconductivity. For most superconductors, the London penetration depth is on the order of 100 nm.
The Meissner effect is sometimes confused with the kind of
diamagnetism one would expect in a perfect electrical conductor: according to
Lenz's law, when a ''changing'' magnetic field is applied to a conductor, it will induce an electric current in the conductor that creates an opposing magnetic field. In a perfect conductor, an arbitrarily large current can be induced, and the resulting magnetic field exactly cancels the applied field.
The Meissner effect is distinct from thisit is the spontaneous expulsion that occurs during transition to superconductivity. Suppose we have a material in its normal state, containing a constant internal magnetic field. When the material is cooled below the critical temperature, we would observe the abrupt expulsion of the internal magnetic field, which we would not expect based on Lenz's law.
The Meissner effect was given a phenomenological explanation by the brothers
Fritz
Fritz is a common German language, German male name. The name originated as a German diminutive of Friedrich (given name), Friedrich or Frederick (given name), Frederick (''Der Alte Fritz'', and ''Stary Fryc'' were common nicknames for King Fred ...
and
Heinz London, who showed that the electromagnetic
free energy in a superconductor is minimized provided
where ''H'' is the magnetic field and ''λ'' is the London penetration depth.
This equation, which is known as the
London equation, predicts that the magnetic field in a superconductor
decays exponentially from whatever value it possesses at the surface.
A superconductor with little or no magnetic field within it is said to be in the Meissner state. The Meissner state breaks down when the applied magnetic field is too large. Superconductors can be divided into two classes according to how this breakdown occurs. In Type I superconductors, superconductivity is abruptly destroyed when the strength of the applied field rises above a critical value ''H''
c. Depending on the geometry of the sample, one may obtain an intermediate state consisting of a baroque pattern of regions of normal material carrying a magnetic field mixed with regions of superconducting material containing no field. In Type II superconductors, raising the applied field past a critical value ''H''
c1 leads to a mixed state (also known as the vortex state) in which an increasing amount of
magnetic flux penetrates the material, but there remains no resistance to the flow of electric current as long as the current is not too large. At a second critical field strength ''H''
c2, superconductivity is destroyed. The mixed state is actually caused by vortices in the electronic superfluid, sometimes called
fluxons because the flux carried by these
vortices is
quantized. Most pure
elemental superconductors, except
niobium
Niobium is a chemical element; it has chemical symbol, symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and Ductility, ductile transition metal. Pure niobium has a Mohs scale of mineral hardness, Mohs h ...
and
carbon nanotubes
A carbon nanotube (CNT) is a tube made of carbon with a diameter in the nanometre range (nanoscale). They are one of the allotropes of carbon. Two broad classes of carbon nanotubes are recognized:
* ''Single-walled carbon nanotubes'' (''SWC ...
, are Type I, while almost all impure and compound superconductors are Type II.
London moment
Conversely, a spinning superconductor generates a magnetic field, precisely aligned with the spin axis. The effect, the London moment, was put to good use in
Gravity Probe B. This experiment measured the magnetic fields of four superconducting gyroscopes to determine their spin axes. This was critical to the experiment since it is one of the few ways to accurately determine the spin axis of an otherwise featureless sphere.
High-temperature superconductivity
Applications
Superconductors are promising candidate materials for devising fundamental circuit elements of electronic, spintronic, and quantum technologies. One such example is a superconducting diode, in which supercurrent flows along one direction only, that promise dissipationless superconducting and semiconducting-superconducting hybrid technologies.
Superconducting magnets are some of the most powerful
electromagnets known. They are used in
MRI/
NMR machines,
mass spectrometers, the beam-steering magnets used in
particle accelerators
A particle accelerator is a machine that uses electromagnetic fields to propel electric charge, charged particles to very high speeds and energies to contain them in well-defined particle beam, beams. Small accelerators are used for fundamental ...
and plasma confining magnets in some
tokamaks. They can also be used for magnetic separation, where weakly magnetic particles are extracted from a background of less or non-magnetic particles, as in the
pigment
A pigment is a powder used to add or alter color or change visual appearance. Pigments are completely or nearly solubility, insoluble and reactivity (chemistry), chemically unreactive in water or another medium; in contrast, dyes are colored sub ...
industries. They can also be used in large wind turbines to overcome the restrictions imposed by high electrical currents, with an industrial grade 3.6 megawatt superconducting windmill generator having been tested successfully in Denmark.
In the 1950s and 1960s, superconductors were used to build experimental digital computers using
cryotron switches. More recently, superconductors have been used to make
digital circuits based on
rapid single flux quantum technology and
RF and microwave filters for
mobile phone
A mobile phone or cell phone is a portable telephone that allows users to make and receive calls over a radio frequency link while moving within a designated telephone service area, unlike fixed-location phones ( landline phones). This rad ...
base stations.
Superconductors are used to build
Josephson junctions which are the building blocks of
SQUIDs (superconducting quantum interference devices), the most sensitive
magnetometers known. SQUIDs are used in
scanning SQUID microscopes and
magnetoencephalography
Magnetoencephalography (MEG) is a functional neuroimaging technique for mapping brain activity by recording magnetic fields produced by electric current, electrical currents occurring naturally in the human brain, brain, using very sensitive magn ...
. Series of Josephson devices are used to realize the
SI volt
The volt (symbol: V) is the unit of electric potential, Voltage#Galvani potential vs. electrochemical potential, electric potential difference (voltage), and electromotive force in the International System of Units, International System of Uni ...
. Superconducting photon detectors can be realised in a variety of device configurations. Depending on the particular mode of operation, a
superconductor–insulator–superconductor Josephson junction can be used as a photon
detector or as a
mixer. The large resistance change at the transition from the normal to the superconducting state is used to build thermometers in cryogenic
micro-calorimeter photon
detectors. The same effect is used in ultrasensitive
bolometers made from superconducting materials.
Superconducting nanowire single-photon detectors offer high speed, low noise single-photon detection and have been employed widely in advanced
photon-counting applications.
Other early markets are arising where the relative efficiency, size and weight advantages of devices based on
high-temperature superconductivity outweigh the additional costs involved. For example, in
wind turbines the lower weight and volume of superconducting generators could lead to savings in construction and tower costs, offsetting the higher costs for the generator and lowering the total
levelized cost of electricity (LCOE).
Promising future applications include high-performance
smart grid
The smart grid is an enhancement of the 20th century electrical grid, using two-way communications and distributed so-called intelligent devices. Two-way flows of electricity and information could improve the delivery network. Research is main ...
,
electric power transmission,
transformers
''Transformers'' is a media franchise produced by American toy company Hasbro and Japanese toy company Tomy, Takara Tomy. It primarily follows the heroic Autobots and the villainous Decepticons, two Extraterrestrials in fiction, alien robot fac ...
,
power storage devices,
compact fusion power devices,
electric motors (e.g. for vehicle propulsion, as in
vactrains or
maglev trains),
magnetic levitation devices,
fault current limiters, enhancing spintronic devices with superconducting materials, and superconducting
magnetic refrigeration. However, superconductivity is sensitive to moving magnetic fields, so applications that use
alternating current
Alternating current (AC) is an electric current that periodically reverses direction and changes its magnitude continuously with time, in contrast to direct current (DC), which flows only in one direction. Alternating current is the form in w ...
(e.g. transformers) will be more difficult to develop than those that rely upon
direct current
Direct current (DC) is one-directional electric current, flow of electric charge. An electrochemical cell is a prime example of DC power. Direct current may flow through a conductor (material), conductor such as a wire, but can also flow throug ...
. Compared to traditional power lines,
superconducting transmission lines are more efficient and require only a fraction of the space, which would not only lead to a better environmental performance but could also improve public acceptance for expansion of the electric grid. Another attractive industrial aspect is the ability for high power transmission at lower voltages.
Advancements in the efficiency of cooling systems and use of cheap coolants such as liquid nitrogen have also significantly decreased cooling costs needed for superconductivity.
Nobel Prizes
As of 2022, there have been five
Nobel Prizes in Physics for superconductivity related subjects:
*
Heike Kamerlingh Onnes (1913), "for his investigations on the properties of matter at low temperatures which led, inter alia, to the production of liquid helium".
*
John Bardeen
John Bardeen (; May 23, 1908 – January 30, 1991) was an American solid-state physicist. He is the only person to be awarded the Nobel Prize in Physics twice: first in 1956 with William Shockley and Walter Houser Brattain for their inventio ...
,
Leon N. Cooper, and
J. Robert Schrieffer (1972), "for their jointly developed theory of superconductivity, usually called the
BCS-theory".
*
Leo Esaki,
Ivar Giaever, and
Brian D. Josephson (1973), "for their experimental discoveries regarding tunneling phenomena in semiconductors and superconductors, respectively" and "for his theoretical predictions of the properties of a supercurrent through a tunnel barrier, in particular those phenomena which are generally known as the Josephson effects".
*
Georg Bednorz and
K. Alex Müller (1987), "for their important break-through in the discovery of superconductivity in ceramic materials".
*
Alexei A. Abrikosov,
Vitaly L. Ginzburg, and
Anthony J. Leggett (2003), "for pioneering contributions to the theory of superconductors and superfluids".
See also
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*
*
References
Further reading
*
IEC standar
60050-815:2000, International Electrotechnical Vocabulary (IEV) – Part 815: Superconductivity.
*
*
*
*
*
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*
*
* Charlie Wood,
Quanta Magazine (2022)
"High-Temperature Superconductivity Understood at Last"
External links
Video about Type I Superconductors: R=0/transition temperatures/ B is a state variable/ Meissner effect/ Energy gap(Giaever)/ BCS modelLectures on Superconductivity (series of videos, including interviews with leading experts)YouTube Video Levitating magnetDoITPoMS Teaching and Learning Package – "Superconductivity"
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