Strontianite ( Sr C O₃) is an important raw material for the extraction of

strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...

. It is a rare

carbonate mineral Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Sider ...

and one of only a few strontium minerals. It is a member of the aragonite group. Aragonite group members:

aragonite Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation fr ...

(CaCO₃),

witherite Witherite is a barium carbonate mineral, Ba C O3, in the aragonite group. Witherite crystallizes in the orthorhombic system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The spec ...

(BaCO₃), strontianite (SrCO₃),

cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate with the chemical formula PbCO3, and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was ...

(PbCO₃) The ideal formula of strontianite is SrCO₃, with

molar mass In chemistry, the molar mass () (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical substance ( element or compound) is defined as the ratio between the mass () and the amount of substance ...

147.63 g, but

calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...

(Ca) can substitute for up to 27% of the strontium (Sr)

cations An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

, and

barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...

(Ba) up to 3.3%. The mineral was named in 1791 for the locality,

Strontian Strontian (; ) is the main village in Sunart, an area in western Lochaber, Scottish Highlands, Highland, Scotland, on the A861 road. Prior to 1975 it was part of Argyllshire. It lies on the north shore of Loch Sunart, close to the head of th ...

, Argyllshire, Scotland, where the element

had been discovered the previous year. Although good mineral specimens of strontianite are rare, strontium is a fairly common

element Element or elements may refer to: Science * Chemical element, a pure substance of one type of atom * Heating element, a device that generates heat by electrical resistance * Orbital elements, parameters required to identify a specific orbit of o ...

, with abundance in the

Earth's crust Earth's crust is its thick outer shell of rock, referring to less than one percent of the planet's radius and volume. It is the top component of the lithosphere, a solidified division of Earth's layers that includes the crust and the upper ...

of 370 parts per million by weight, 87 parts per million by moles, much more common than

copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...

with only 60 parts per million by weight, 19 by moles. Strontium is never found free in nature. The principal strontium ores are

celestine Celestine is a given name and a surname. People Given name * Pope Celestine I (died 432) * Pope Celestine II (died 1144) * Pope Celestine III (c. 1106–1198) * Pope Celestine IV (died 1241) * Pope Celestine V (1215–1296) * Antipope Cel ...

SrSO₄ and strontianite SrCO₃. The main commercial process for strontium metal production is reduction of

strontium oxide Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a st ...

with

aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...

Unit cell

Strontianite is an

orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...

mineral, belonging to the most symmetrical class in this system, 2/m 2/m 2/m, whose general form is a rhombic

dipyramid In geometry, a bipyramid, dipyramid, or double pyramid is a polyhedron formed by fusing two Pyramid (geometry), pyramids together base (geometry), base-to-base. The polygonal base of each pyramid must therefore be the same, and unless otherwise ...

. The

space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...

is Pmcn. There are four formula units per

unit cell In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector In mathematics, a unit vector i ...

(Z = 4) and the unit cell parameters are a = 5.1 Å, b = 8.4 Å, c = 6.0 Å.

Structure

Strontianite is

isostructural Isostructural chemical compounds have similar chemical structures. " Isomorphous" when used in the relation to crystal structures is not synonymous: in addition to the same atomic connectivity that characterises isostructural compounds, isomorphous ...

with

.Klein and Hurlbut (1993) Manual of Mineralogy 21st Edition. Wiley When the CO₃ group is combined with large

divalent In chemistry, the valence (US spelling) or valency (British spelling) of an atom is a measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Valence is generally understood to be the number of chemica ...

with

ionic radii Ionic radius, ''r''ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation ...

greater than 1.0 Å, the radius ratios generally do not permit stable 6-fold coordination. For small cations the structure is

rhombohedral In geometry, a rhombohedron (also called a rhombic hexahedron or, inaccurately, a rhomboid) is a special case of a parallelepiped in which all six faces are congruent rhombus, rhombi. It can be used to define the rhombohedral lattice system, a Ho ...

, but for large cations it is

. This is the aragonite structure type with

Pmcn. In this structure the CO₃ groups lie perpendicular to the c

axis An axis (: axes) may refer to: Mathematics *A specific line (often a directed line) that plays an important role in some contexts. In particular: ** Coordinate axis of a coordinate system *** ''x''-axis, ''y''-axis, ''z''-axis, common names ...

, in two structural planes, with the CO₃ triangular groups of one plane pointing in opposite directions to those of the other. These layers are separated by layers of cations. The CO₃ group is slightly non-planar; the

carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...

atom Atoms are the basic particles of the chemical elements. An atom consists of a atomic nucleus, nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished fr ...

lies 0.007 Å out of the plane of the

oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...

atoms. The groups are tilted such that the angle between a plane drawn through the oxygen atoms and a plane parallel to the a-b unit cell plane is 2°40’.De Villiers, Johan P R (1971) Crystal Structures of Aragonite, Strontianite and Witherite. The American Mineralogist 56:758

Crystal form

Strontianite occurs in several different

habits A habit (or wont, as a humorous and formal term) is a routine of behavior that is repeated regularly and tends to occur subconsciously. A 1903 paper in the ''American Journal of Psychology'' defined a "habit, from the standpoint of psychology,

prismatic An optical prism is a transparent optics, optical element with flat, polished surfaces that are designed to refraction, refract light. At least one surface must be angled—elements with two parallel surfaces are ''not'' prisms. The most fami ...

parallel to the c axis and often acicular.

Acicular (crystal habit)">acicular. Calcium-rich varieties often show steep Pyramid (geometry)">pyramidal A pyramid () is a structure whose visible surfaces are triangular in broad outline and converge toward the top, making the appearance roughly a pyramid in the geometric sense. The base of a pyramid can be of any polygon shape, such as triangu ...

forms. Crystals may be pseudo hexagonal due to equal development of different forms. Prism faces are striated horizontally. The mineral also occurs as columnar to fibrous, granular or rounded masses.

Optical properties

Strontianite is colourless, white, gray, light yellow, green or brown, colourless in transmitted light. It may be longitudinally zoned. It is transparent to translucent, with a vitreous (glassy) lustre, resinous on broken surfaces, and a white streak. It is a biaxial(−) mineral. The direction perpendicular to the plane containing the two optic axes is called the optical direction Y. In strontianite Y is parallel to the b crystal axis. The optical direction Z lies in the plane containing the two optic axes and bisects the acute angle between them. In strontianite Z is parallel to the a crystal axis. The third direction X, perpendicular both to Y and to Z, is parallel to the c crystal axis. The

refractive indices In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...

are close to n_α = 1.52, n_β = 1.66, n_γ = 1.67, with different sources quoting slightly different values: *n_α = 1.520, n_β = 1.667, n_γ = 1.669 *n_α = 1.516 – 1.520, n_β = 1.664 – 1.667, n_γ = 1.666 – 1.668 *n_α = 1.517, n_β = 1.663, n_γ = 1.667 (synthetic material)Speer, J A and Hensley-Dunn, M L (1976) Strontianite composition and physical properties. American Mineralogist 61:1001–1004 The maximum

birefringence Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefrin ...

δ is 0.15 and the measured value of 2V is 7°, calculated 12° to 8°. If the colour of the incident light is changed, then the refractive indices are modified, and the value of 2V changes. This is known as dispersion of the optic axes. For strontianite the effect is weak, with 2V larger for violet light than for red light r < v.

Luminescence

Strontianite is almost always

fluorescent Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with color ...

. It fluoresces bright yellowish white under shortwave, mediumwave and longwave

ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...

radiation. If the luminescence persists after the ultraviolet source is switched off the sample is said to be phosphorescent. Most strontianite phosphoresces a strong, medium duration, yellowish white after exposure to all three wavelengths.The Mineralogical Record (2006) 37-1:44 It is also fluorescent and phosphorescent in

X-rays An X-ray (also known in many languages as Röntgen radiation) is a form of high-energy electromagnetic radiation with a wavelength shorter than those of ultraviolet rays and longer than those of gamma rays. Roughly, X-rays have a wavelength ran ...

and

electron beams Cathode rays are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to electrons emitted from the ca ...

. All materials will glow red hot if they are heated to a high enough temperature (provided they do not decompose first); some materials become luminescent at much lower temperatures, and this is known as

thermoluminescence Thermoluminescence is a form of luminescence that is exhibited by certain crystalline materials, such as some minerals, when previously absorbed energy from electromagnetic radiation or other ionizing radiation is re-emitted as light upon hea ...

. Strontianite is sometimes thermoluminescent.

Physical properties

Cleavage Cleavage may refer to: Science * Cleavage (crystal), the way in which a crystal or mineral tends to split * Cleavage (embryo), the division of cells in an early embryo * Cleavage (geology), foliation of rock perpendicular to stress, a result of ...

is nearly perfect parallel to one set of prism faces, , and poor on . Traces of cleavage have been observed on . Twinning is very common, with twin plane . The twins are usually contact twins; in a contact twin the two individuals appear to be reflections of each other in the twin plane. Penetration twins of strontainite are rarer; penetration twins are made up of interpenetrating individuals that are related to each other by rotation about a twin axis. Repeated twins are made up of three or more individuals twinned according to the same law. If all the twin planes are parallel then the twin is polysynthetic, otherwise it is cyclic. In strontianite repeated twinning forms cyclic twins with three or four individuals, or polysynthetic twins. The mineral is brittle, and breaks with a subconchoidal to uneven

fracture Fracture is the appearance of a crack or complete separation of an object or material into two or more pieces under the action of stress (mechanics), stress. The fracture of a solid usually occurs due to the development of certain displacemen ...

. It is quite soft, with a

Mohs hardness The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...

of , between

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

and

fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...

. The

specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...

of the pure

endmember An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of ...

with no calcium substituting for strontium is 3.78, but most samples contain some calcium, which is lighter than strontium, giving a lower specific gravity, in the range 3.74 to 3.78. Substitutions of the heavier ions

and/or

lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...

increase the specific gravity, although such substitutions are never very abundant. Strontianite is soluble in dilute

hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...

HCl and it is not

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...

Environment and associations

Strontianite is an uncommon low-temperature

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

mineral formed in

veins Veins () are blood vessels in the circulatory system of humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are those of the pulmonary and fetal c ...

limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...

marl Marl is an earthy material rich in carbonate minerals, Clay minerals, clays, and silt. When Lithification, hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. M ...

, and

chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Ch ...

, and in

geode A geode (; ) is a geology, geological secondary formation within sedimentary rock, sedimentary and volcanic rocks. Geodes are hollow, vaguely spherical rocks, in which masses of mineral matter (which may include crystals) are secluded. The crys ...

s and

concretions A concretion is a hard and compact mass formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular shapes a ...

. It occurs rarely in hydrothermal metallic veins but is common in

carbonatite Carbonatite () is a type of intrusive rock, intrusive or extrusive rock, extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geoche ...

s. It most likely crystallises at or near 100 °C. Its occurrence in open

vug A vug, vugh, or vugg () is a small- to medium-sized cavity inside rock. It may be formed through a variety of processes. Most commonly, cracks and fissures opened by tectonic activity ( folding and faulting) are partially filled by quartz, calc ...

s and veins suggests crystallisation at very low pressures, probably at most equal to the

hydrostatic pressure Hydrostatics is the branch of fluid mechanics that studies fluids at hydrostatic equilibrium and "the pressure in a fluid or exerted by a fluid on an immersed body". The word "hydrostatics" is sometimes used to refer specifically to water and o ...

of the

ground water Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available fresh water in the world is groundwater. A unit of rock or an unconsolidat ...

. Under appropriate conditions it alters to

SrSO₄, and it is itself found as an alteration from celestine. These two minerals are often found in association, together with

baryte Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...

harmotome Harmotome is a mineral, one of the rarer zeolites; a hydrated barium silicate with formula: . It forms vitreous white well defined monoclinic crystals, often associated with calcite and other zeolites. It has a Mohs hardness of 4 to 5 and a speci ...

and

sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...

Occurrences

Type locality

The type locality is

, North West Highlands (

Argyllshire Argyll (; archaically Argyle; , ), sometimes called Argyllshire, is a historic county and registration county of western Scotland. The county ceased to be used for local government purposes in 1975 and most of the area now forms part of ...

Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...

, UK. The

type material In biology, a type is a particular wikt:en:specimen, specimen (or in some cases a group of specimens) of an organism to which the scientific name of that organism is formally associated. In other words, a type is an example that serves to ancho ...

occurred in

gneiss Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...

. Other UK localities include Brownley Hill Mine (Bloomsberry Horse Level), Nenthead,

Alston Moor Alston Moor, formerly known as Alston with Garrigill, is a civil parish and electoral ward in the Westmorland and Furness district, in the ceremonial county of Cumbria, England, based around the small town of Alston. It is set in the moorlan ...

District, North Pennines, North and Western Region (Cumberland), Cumbria, England, associated with a suite of primary minerals (

bournonite Bournonite, also ''axotomous antimony glance'',''Robert Jameson''. Manual of Mineralogy: containing an account of simple minerals, and also a description and arrangement of mountain rocks. — Edinburgh, Archibald Constable & Co., 1821. — 49 ...

millerite Millerite or ''nickel blende'' is a nickel sulfide mineral, Ni S. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller ...

and

ullmannite Ullmannite or ''Nickel glance'' (trivial name) is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid soluti ...

) which are not common in other Mississippi Valley-type deposits.The Mineralogical Record (2010) 41-1:62 supplement

Canada

The Francon quarry,

Montréal Montreal is the List of towns in Quebec, largest city in the Provinces and territories of Canada, province of Quebec, the List of the largest municipalities in Canada by population, second-largest in Canada, and the List of North American cit ...

, Québec.
Strontianite is very common at the Francon Quarry, in a great variety of habits. It is a late stage mineral, sometimes found as multiple generations. It is found as translucent to opaque, white to pale yellow or beige generally smooth surfaced spheroids, hemispheres and compact spherical and botryoidal aggregates to 10 cm in diameter, and as spheres consisting of numerous radiating acicular crystals, up to 1 cm across. Also as tufts, parallel bundles, and sheaf-like clusters of fibrous to acicular crystals, and as white, finely granular porcelaneous and waxy globular aggregates. Transparent, pale pink, columnar to tabular sixling twins up to 1 cm in diameter have been found, and aggregates of stacked stellate sixling twins consisting of transparent, pale yellow tabular crystals. Another Canadian occurrence is at Nepean, Ontario, in vein deposits in

Germany

Commercially important deposits occur in

marls Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. Marl makes up the lower part o ...

Westphalia Westphalia (; ; ) is a region of northwestern Germany and one of the three historic parts of the state of North Rhine-Westphalia. It has an area of and 7.9 million inhabitants. The territory of the region is almost identical with the h ...

, and it is also found with

zeolites Zeolites are a group of several Microporous material, microporous, crystalline aluminosilicate minerals commonly used as commercial adsorption, adsorbents and Catalysis, catalysts. They mainly consist of silicon, aluminium, oxygen, and have the ge ...

at Oberschaffhausen, Bötzingen, Kaiserstuhl, Baden-Württemberg.

India

Trichy Tiruchirappalli (), also known as Trichy, is a major tier II city in the Indian state of Tamil Nadu and the administrative headquarters of Tiruchirappalli district. The city is credited with being the best livable and the cleanest city of T ...

(Tiruchirappalli; Tiruchi), Tiruchirapalli District, Tamil Nadu, it occurs with

SrSO₄,

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...

and

phosphate nodule Phosphorite, phosphate rock or rock phosphate is a non- detrital sedimentary rock that contains high amounts of phosphate minerals. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% phosphorus pentox ...

s in

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...

Mexico

It occurs in the

Sierra Mojada Sierra Mojada is a city and seat of the municipality of Sierra Mojada, in the north-eastern Mexican state of Coahuila. Local oral tradition, documented by the priest James Lienert, states that Ambrose Bierce Ambrose Gwinnett Bierce (June 24, 1 ...

District, with

in a

silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...

deposit.

Russia

It occurs in the Kirovskii

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...

mine, Kukisvumchorr Mt,

Khibiny Massif The Khibiny Mountains ( ; ) is one of the two main mountain ranges of the Kola Peninsula, Russia, within the Arctic Circle, located between Imandra and Umbozero lakes. The range is also known as Khibiny Massif, Khibinsky Mountains, Khibinsky Tu ...

Kola Peninsula The Kola Peninsula (; ) is a peninsula in the extreme northwest of Russia, and one of the largest peninsulas of Europe. Constituting the bulk of the territory of Murmansk Oblast, it lies almost completely inside the Arctic Circle and is border ...

, Murmanskaja Oblast', Northern Region, in late hydrothermal assemblages in cavities in

pegmatites A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...

, associated with kukharenkoite-(La),

microcline Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during s ...

albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...

nenadkevichite Nenadkevichite is a rare silicate mineral containing niobium with the chemical formula . It forms brown to yellow to rose colored orthorhombic dipyramidal crystals with a dull to earthy luster. It has a Mohs hardness of 5 and a specific gravity ...

, hilairite,

catapleiite Catapleiite (·2) is a dimorph of gaidonnayite rarely found by itself. Its name derives from the Greek words "κατα" (kata) and "πλειον" (pleion) meaning "with more" as it is mostly accompanied by a number of rare minerals. When pure it ...

donnayite-(Y) Donnayite-(Y) is a rare-earth carbonate mineral containing the rare-earth metal yttrium. It was first discovered in 1978 at Mont Saint-Hilaire, Quebec. Donnayite was subsequently identified and named after Joseph D. H. Donnay and his wife, Gabri ...

synchysite-(Ce) Synchysite-(Ce) is a carbonate mineral and an end member of the synchysite group. The general chemical formula is . Discovery and naming Synchysite-(Ce) was discovered in 1900 by Gustaf Flink. The name is derived from the Greek "σύγχΰσις" ...

pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...

and others.The Mineralogical Record (2004) 35-4:355 It also occurs at Yukspor Mountain, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, in an

aegerine Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine–augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite ser ...

natrolite Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany. It was named natrolite by Martin Heinrich Klaprot ...

vein in foyaite, associated with

aegirine Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine– augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite se ...

anatase Anatase is a metastable mineral form of titanium dioxide (TiO2) with a Tetragonal crystal system, tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other Pol ...

, ancylite-(Ce), barylite,

, cerite-(Ce), cerite-(La), chabazite-(Ca),

edingtonite Edingtonite is a white, gray, brown, colorless, pink or yellow zeolite mineral. Its chemical formula is Ba Al2 Si3 O10·4 H2O. It has varieties with tetragonal, orthorhombic or triclinic crystals. The mineral occurs within cavities in nepheline ...

fluorapatite Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blu ...

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...

ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printi ...

sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...

and

vanadinite Vanadinite is a mineral belonging to the apatite group of Phosphate minerals, phosphates, with the chemical formula lead, Pb5(vanadium, Voxygen, O4)3chlorine, Cl. It is one of the main industrial ores of the metal vanadium and a minor source of ...

.The Mineralogical Record (2004) 35-2:176 At the same locality it was found in

alkaline In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The ...

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...

veins associated with clinobarylite,

titanite Titanite, or sphene (), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly rep ...

annite Annite is a phyllosilicate mineral in the mica family. It has a chemical formula of KFe32+AlSi3O10(OH)2. Annite is the iron end member of the biotite mica group, the iron rich analogue of magnesium rich phlogopite. Annite is monoclinic and contai ...

astrophyllite Astrophyllite is a very rare, brown to golden-yellow hydrous potassium iron titanium silicate mineral. Belonging to the astrophyllite group, astrophyllite may be classed either as an inosilicate, phyllosilicate, or an intermediate between the tw ...

lorenzenite Lorenzenite is a rare sodium titanium silicate mineral with the formula Na2 Ti2 Si2 O9 It is an orthorhombic mineral, variously found as colorless, grey, pinkish, or brown crystals. It was first identified in 1897 in rock samples from Narsarsuk ...

, labuntsovite-Mn, kuzmenkoite-Mn, cerite-(Ce),

and

.The Mineralogical Record 35-4:347 (2004)

United States

In the

Gulf coast The Gulf Coast of the United States, also known as the Gulf South or the South Coast, is the coastline along the Southern United States where they meet the Gulf of Mexico. The coastal states that have a shoreline on the Gulf of Mexico are Tex ...

Louisiana Louisiana ( ; ; ) is a state in the Deep South and South Central regions of the United States. It borders Texas to the west, Arkansas to the north, and Mississippi to the east. Of the 50 U.S. states, it ranks 31st in area and 25 ...

and

Texas Texas ( , ; or ) is the most populous U.S. state, state in the South Central United States, South Central region of the United States. It borders Louisiana to the east, Arkansas to the northeast, Oklahoma to the north, New Mexico to the we ...

, strontianite occurs with

cap rock Caprock or cap rock is a hard, resistant, and impermeable layer of rock that overlies and protects a reservoir of softer organic material, similar to the crust on a pie where the crust (caprock) prevents leakage of the soft filling (softer material ...

salt domes A salt dome is a type of structural dome formed when salt (or other evaporite minerals) intrudes into overlying rocks in a process known as diapirism. Salt domes can have unique surface and subsurface structures, and they can be discovered usi ...

. At the Minerva Number 1 Mine (Ozark-Mahoning Number 1 Mine) Ozark-Mahoning Group,

Cave-in-Rock, Illinois Cave-In-Rock is a village in Hardin County, Illinois, Hardin County, Illinois, United States. Its principal feature and tourist attraction is nearby Cave-in-Rock State Park, Cave-In-Rock, on the banks of the Ohio River. In 1816, the earliest kno ...

, in the Kentucky

Fluorspar Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...

District, Hardin County strontanite occurs as white, brown or rarely pink tufts and bowties of acicular crystals with slightly curved terminations.Rocks & Minerals (2010) 85-3:212 In the

Silurian The Silurian ( ) is a geologic period and system spanning 23.5 million years from the end of the Ordovician Period, at million years ago ( Mya), to the beginning of the Devonian Period, Mya. The Silurian is the third and shortest period of t ...

Lockport Group, Central and Western

New York New York most commonly refers to: * New York (state), a state in the northeastern United States * New York City, the most populous city in the United States, located in the state of New York New York may also refer to: Places United Kingdom * ...

strontianite is observed in cavities in eastern Lockport, where it occurs as small white radiating sprays of acicular crystals.Rocks & Minerals (2009) 84-4:332 In

Schoharie County Schoharie County ( ) is a county in the U.S. state of New York. As of the 2020 census, the population was 29,714, making it the state's fifth-least populous county. The county seat is Schoharie. "Schoharie" comes from a Mohawk word meaning " ...

, New York, it occurs in

s and

with

and

, and in

Mifflin County Mifflin County is a county in the Commonwealth of Pennsylvania. As of the 2020 census, the population was 46,143. Its county seat is Lewistown. The county was created on September 19, 1789, from parts of Cumberland County and Northumberland ...

, Pennsylvania, it occurs with

, again in

. Strontianite-118172.jpg, Strontianite from Strontian, Scotland Dresserite-Strontianite-lor03a.jpg,

Dresserite Dresserite is a mineral of the dresserite group, named in honor of John Alexander Dresser, geologist. It was approved by the IMA in 1968, but only a year after was it published. The rare mineral can only be found in Francon quarry, Canada. The qua ...

and Strontianite from the Francon quarry, Canada Strontianite-Baryte-160390.jpg, Strontianite from the Dreislar Mine, North Rhine-Westphalia, Germany Strontianite-170614.jpg, Strontianite from Texas, US Strontianite-208781.jpg, Strontianite from Illinois, US Strontianite Strontium carbonate Barstow San Bernardino County California 1845.jpg, Strontianite from California

References

External links

JMol
{{Authority control Lochaber Strontium minerals Carbonate minerals Aragonite group Orthorhombic minerals Minerals in space group 62 Luminescent minerals Geology of Scotland Minerals described in 1791

Unit cell

Structure

Crystal form

Optical properties

Luminescence

Physical properties

Environment and associations

Occurrences

Type locality

Canada

Germany

India

Mexico

Russia

United States

See also

References

External links