Mohs Hardness Scale
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The Mohs scale ( ) of mineral hardness is a qualitative
ordinal scale Ordinal data is a categorical, statistical data type where the variables have natural, ordered categories and the distances between the categories are not known. These data exist on an ordinal scale, one of four levels of measurement described ...
, from 1 to 10, characterizing scratch resistance of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s through the ability of harder material to scratch softer material. The scale was introduced in 1812 by the German
geologist A geologist is a scientist who studies the structure, composition, and History of Earth, history of Earth. Geologists incorporate techniques from physics, chemistry, biology, mathematics, and geography to perform research in the Field research, ...
and
mineralogist Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical mineralogy, optical) properties of minerals and mineralized artifact (archaeology), artifacts. Specific s ...
Friedrich Mohs, in his book (English: Attempt at an elementary method for the natural-historical determination and recognition of fossils); it is one of several definitions of
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to plastic deformation, such as an indentation (over an area) or a scratch (linear), induced mechanically either by Pressing (metalworking), pressing or abrasion ...
in
materials science Materials science is an interdisciplinary field of researching and discovering materials. Materials engineering is an engineering field of finding uses for materials in other fields and industries. The intellectual origins of materials sci ...
, some of which are more quantitative. The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned by
Theophrastus Theophrastus (; ; c. 371 – c. 287 BC) was an ancient Greek Philosophy, philosopher and Natural history, naturalist. A native of Eresos in Lesbos, he was Aristotle's close colleague and successor as head of the Lyceum (classical), Lyceum, the ...
in his treatise ''On Stones'', , followed by
Pliny the Elder Gaius Plinius Secundus (AD 23/24 79), known in English as Pliny the Elder ( ), was a Roman Empire, Roman author, Natural history, naturalist, and naval and army commander of the early Roman Empire, and a friend of the Roman emperor, emperor Vesp ...
in his ''
Naturalis Historia The ''Natural History'' () is a Latin work by Pliny the Elder. The largest single work to have survived from the Roman Empire to the modern day, the ''Natural History'' compiles information gleaned from other ancient authors. Despite the work' ...
'', . The Mohs scale is useful for identification of minerals in the field, but is not an accurate predictor of how well materials endure in an industrial setting.


Reference minerals

The Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to visibly scratch another mineral.
Mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s are chemically pure solids found in nature. Rocks are mixtures of one or more minerals. :
Diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
was the hardest known naturally occurring mineral when the scale was designed, and defines the top of the scale, arbitrarily set at 10. The hardness of a material is measured against the scale by finding the hardest material that the given material can scratch, or the softest material that can scratch the given material. For example, if some material is scratched by
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...
but not by
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
, its hardness on the Mohs scale would be between 4 and 5. Technically, "scratching" a material for the purposes of the Mohs scale means creating non-
elastic Elastic is a word often used to describe or identify certain types of elastomer, Elastic (notion), elastic used in garments or stretch fabric, stretchable fabrics. Elastic may also refer to: Alternative name * Rubber band, ring-shaped band of rub ...
dislocations visible to the naked eye. Frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. While these microscopic dislocations are permanent and sometimes detrimental to the harder material's structural integrity, they are not considered "scratches" for the determination of a Mohs scale number. Each of the ten hardness values in the Mohs scale is represented by a ''reference mineral'', most of which are widespread in rocks. The Mohs scale is an
ordinal scale Ordinal data is a categorical, statistical data type where the variables have natural, ordered categories and the distances between the categories are not known. These data exist on an ordinal scale, one of four levels of measurement described ...
. For example,
corundum Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium, and chromium. It is a rock (geology), rock-forming mineral. It is a naturally transparency and translucency, transparent material, but ...
(9) is twice as hard as
topaz Topaz is a silicate mineral made of aluminium, aluminum and fluorine with the chemical formula aluminium, Alsilicon, Sioxygen, O(fluorine, F, hydroxide, OH). It is used as a gemstone in jewelry and other adornments. Common topaz in its natural ...
(8), but diamond (10) is four times as hard as corundum. The table below shows the comparison with the absolute hardness measured by a
sclerometer The sclerometer, also known as the Turner-sclerometer (from meaning "hard"), is an instrument used by metallurgists, material scientists and mineralogists to measure the scratch hardness of materials. It was invented in 1896 by Thomas Turner ( ...
, with images of the reference minerals in the rightmost column. :


Examples

Below is a table of more materials by Mohs scale. Some of them have a hardness between two of the Mohs scale reference minerals. Some solid substances that are not minerals have been assigned a hardness on the Mohs scale. Hardness may be difficult to determine, or may be misleading or meaningless, if a material is a mixture of multiple substances. For example,
granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
has been assigned by some sources a Mohs hardness between 6 and 7, but it is a rock made of several minerals, each with its own Mohs hardness. Topaz-rich granite is mainly composed of topaz (Mohs 8), quartz (Mohs 7), orthoclase (Mohs 6), plagioclase (Mohs 6–6.5), and mica (Mohs 2–4). :


Use

Despite its lack of precision, the Mohs scale is relevant for field geologists, who use it to roughly identify minerals using scratch kits. The Mohs scale hardness of minerals can be commonly found in reference sheets. Mohs hardness is useful in
milling Milling may refer to: * Milling (minting), forming narrow ridges around the edge of a coin * Milling (grinding), breaking solid materials into smaller pieces by grinding, crushing, or cutting in a mill * Milling (machining), a process of using ro ...
. It allows the assessment of which type of mill and grinding medium will best reduce a given product whose hardness is known. Electronic manufacturers use the scale for testing the resilience of flat panel display components (such as cover glass for
LCD A liquid-crystal display (LCD) is a flat-panel display or other electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers to display information. Liquid crystals do not em ...
s or encapsulation for
OLED An organic light-emitting diode (OLED), also known as organic electroluminescent (organic EL) diode, is a type of light-emitting diode (LED) in which the emissive electroluminescent layer is an organic compound film that emits light in respon ...
s), as well as to evaluate the hardness of touch screens in consumer electronics.


Comparison with Vickers scale

Comparison between Mohs hardness and
Vickers hardness The Vickers hardness test was developed in 1921 by Robert L. Smith and George E. Sandland at Vickers Ltd as an alternative to the Brinell method to measure the hardness of materials. The Vickers test is often easier to use than other hardness ...
: :


Footnotes


See also

*
Brinell scale The Brinell hardness test (pronounced /brəˈnɛl/) measures the indentation hardness of materials. It determines hardness through the scale of penetration of an indenter, loaded on a material test-piece. It is one of several definitions of hard ...
* Geological Strength Index *
Hardnesses of the elements (data page) Notes References See also *Mohs scale of mineral hardness *Mohs hardness of materials (data page) *Vickers hardness test *Brinell scale The Brinell hardness test (pronounced /brəˈnɛl/) measures the indentation hardness of materials ...
*
Knoop hardness test The Knoop hardness test is a microhardness test – a test for mechanical hardness used particularly for very brittle materials or thin sheets, where only a small indentation may be made for testing purposes. A pyramidal diamond point is pressed ...
* Meyer hardness test * Pencil hardness *
Rockwell scale The Rockwell hardness test is a hardness test based on indentation hardness of a material. The Rockwell test measures the depth of penetration of an indenter under a large load (major load) compared to the penetration made by a preload (minor loa ...
* Rosiwal scale *
Scratch hardness Scratch hardness refers to the hardness of a material in terms of resistance to scratches and abrasion by a harder material forcefully drawn over its surface. Scratch hardness test or scratch test refers to any of a number of methods of measuring s ...
*
Superhard material A superhard material is a material with a hardness value exceeding 40 gigapascals (GPa) when measured by the Vickers hardness test. They are virtually incompressible solids with high electron density and high Covalent bond, bond covalency. As a res ...


References


Further reading

* * {{Mineral identification Materials science Mineralogy Hardness tests 1812 in science 1812 in the Confederation of the Rhine de:Härte#Härteprüfung nach Mohs