Cordierite (

mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical mineralogy, optical) properties of minerals and mineralized artifact (archaeology), artifacts. Specific s ...

) or iolite (

gemology Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is a specific interdisciplinary branch of mineralogy. Some jewellery, jewelers (and many non-jewelers) are academically trained gemologists and are qua ...

) is a

magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...

iron

aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...

cyclosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...

Iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

is almost always present, and a

solid solution A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...

exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-temperature polymorph exists, indialite, which is isostructural with

beryl Beryl ( ) is a mineral composed of beryllium aluminium Silicate minerals#Cyclosilicates, silicate with the chemical formula Be3Al2(SiO3)6. Well-known varieties of beryl include emerald and Aquamarine (gem), aquamarine. Naturally occurring Hex ...

and has a random distribution of Al in the rings. Cordierite is also synthesized and used in high temperature applications such as catalytic converters and pizza stones.

Name and discovery

Cordierite, which was discovered in 1813, in specimens from Níjar, Almería,

Spain Spain, or the Kingdom of Spain, is a country in Southern Europe, Southern and Western Europe with territories in North Africa. Featuring the Punta de Tarifa, southernmost point of continental Europe, it is the largest country in Southern Eur ...

, is named after the French

geologist A geologist is a scientist who studies the structure, composition, and History of Earth, history of Earth. Geologists incorporate techniques from physics, chemistry, biology, mathematics, and geography to perform research in the Field research, ...

Louis Cordier Pierre Louis Antoine Cordier (31 March 1777 – 30 March 1861)
Annales.org, accessed 20 September 2009 was a French

(1777–1861).

Occurrence

Cordierite typically occurs in contact or regional

metamorphism Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...

of pelitic rocks. It is especially common in

hornfels Hornfels is the group name for a set of Metamorphism#Contact .28thermal.29, contact metamorphic rocks that have been baked and hardened by the heat of Intrusive rock, intrusive igneous masses and have been rendered massive, hard, splintery, and in ...

produced by contact metamorphism of pelitic rocks. Two common metamorphic mineral assemblages include

sillimanite Sillimanite or fibrolite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut ...

-cordierite-

spinel Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , a diminutive form of ''spine,'' in reference to its pointed crystals. Prop ...

and cordierite-spinel-

plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...

- orthopyroxene. Other associated minerals include

garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...

(cordierite-garnet-sillimanite

gneiss Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...

es) and anthophyllite. Cordierite also occurs in some

granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...

s, and norites in gabbroic magmas. Alteration products include

mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...

chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...

, and

talc Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...

. Cordierite occurs, for example, in the granite contact zone at Geevor Tin Mine in

Cornwall Cornwall (; or ) is a Ceremonial counties of England, ceremonial county in South West England. It is also one of the Celtic nations and the homeland of the Cornish people. The county is bordered by the Atlantic Ocean to the north and west, ...

Commercial use

Catalytic converter A catalytic converter part is an vehicle emissions control, exhaust emission control device which converts toxic gases and pollutants in exhaust gas from an internal combustion engine into less-toxic pollutants by catalysis, catalyzing a redox ...

s are commonly made from

ceramic A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcela ...

s containing a large proportion of synthetic cordierite. The manufacturing process deliberately aligns the cordierite crystals to make use of the very low thermal expansion along one axis. This prevents thermal shock cracking from taking place when the catalytic converter is used.

Gem variety

As the transparent variety iolite, it is often used as a

gemstone A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewellery, jewelry or other adornments. Certain Rock (geology), rocks (such ...

. The name "iolite" comes from the Greek word for violet. Another old name is ''dichroite'', a Greek word meaning "two-colored rock", a reference to cordierite's strong

pleochroism Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with Polarization (waves), polarized light. Etymology The roots of the word are from Greek (). It was first made compou ...

. It has also been called "water-sapphire" and "Vikings' Compass" because of its usefulness in determining the direction of the sun on overcast days, the Vikings having used it for this purpose. This works by determining the direction of polarization of the sky overhead. Light scattered by air molecules is polarized, and the direction of the polarization is at right angles to a line to the sun, even when the sun's disk itself is obscured by dense fog or lies just below the horizon. Gem quality iolite varies in color from

sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name ''sapphire ...

blue to blue violet to yellowish gray to light blue as the light angle changes. Iolite is sometimes used as an inexpensive substitute for sapphire. It is much softer than sapphires and is abundantly found in Australia (Northern Territory), Brazil, Burma, Canada (Yellowknife area of the Northwest Territories), India, Madagascar, Namibia, Sri Lanka, Tanzania and the United States (Connecticut). The largest iolite crystal found weighed more than 24,000 carats (4,800g), and was discovered in Wyoming, US. File:Cordierite.jpg, ''Left'': rough specimen showing dichroism; ''right'': cut stone File:Iolite.JPG, Facet cut iolite gemstone File:Cordierite_pléochroïsme.jpg,

Pleochroism Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with Polarization (waves), polarized light. Etymology The roots of the word are from Greek (). It was first made compou ...

of cordierite Another name for blue iolite is steinheilite, after Fabian Steinheil, the Russian military governor of Finland who observed that it was a different mineral from

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

. Praseolite is another iolite variety which results from heat treatment. It should not be confused with prasiolite.

Applications

Cordierite is used in manufacturing kiln furniture for its impressive thermal shock resistance, which allows it to withstand rapid temperature changes without cracking. It is also employed to produce insulation equipment and

electric heating Electric heating is a process in which electrical energy is converted directly to heat energy. Common applications include space heating, cooking, water heating and industrial processes. An electric heater is an electricity, electrical device t ...

elements in

fuses Munitions, Fuse or FUSE may refer to: Devices * Fuse (electrical), a device used in electrical systems to protect against excessive current ** Fuse (automotive), a class of fuses for vehicles * Fuse (hydraulic), a device used in hydraulic systems ...

, thermostats, and lighting technology. In the automotive industry, cordierite is used in catalytic converters due to its excellent thermal stability and low thermal expansion. It forms the honeycomb substrates within the converters, which support the catalytic coating that reduces harmful emissions.

References

External links

Mineral galleries
*https://www.gemstone.org/education/gem-by-gem/222-iolite {{Authority control Magnesium minerals Iron(II) minerals Aluminium minerals Cyclosilicates Orthorhombic minerals Minerals in space group 66 Gemstones