Bunsen burner
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A Bunsen burner, named after
Robert Bunsen Robert Wilhelm Eberhard Bunsen (; 30 March 1811 – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. The Bu ...
, is a kind of ambient air
gas burner A gas burner is a device that produces a non-controlled flame by mixing a fuel gas such as acetylene, natural gas, or propane with an oxidizer such as the ambient air or supplied oxygen, and allowing for wikt:ignition, ignition and combustion. ...
used as
laboratory equipment A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratories are found in a variety of settings such as schools, u ...
; it produces a single open gas
flame A flame () is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction made in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density, they are then considered plasm ...
, and is used for heating, sterilization, and combustion. The gas can be
natural gas Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium ...
(which is mainly
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
) or a
liquefied petroleum gas Liquefied petroleum gas, also referred to as liquid petroleum gas (LPG or LP gas), is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, Butane, ''n''-butane and isobutane. It can also contain some ...
, such as
propane Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum ref ...
,
butane Butane () is an alkane with the formula C4H10. Butane exists as two isomers, ''n''-butane with connectivity and iso-butane with the formula . Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at ro ...
, a mixture or, as Bunsen himself used,
coal gas Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous ...
. Combustion temperature achieved depends in part on the adiabatic flame temperature of the chosen fuel mixture.


History

In 1852, the
University of Heidelberg Heidelberg University, officially the Ruprecht Karl University of Heidelberg (; ), is a public university, public research university in Heidelberg, Baden-Württemberg, Germany. Founded in 1386 on instruction of Pope Urban VI, Heidelberg is List ...
hired Bunsen and promised him a new laboratory building. The city of Heidelberg had begun to install coal-gas street lighting, and the university laid gas lines to the new laboratory. The designers of the building intended to use the gas not just for lighting, but also as fuel for burners for laboratory operations. For any burner lamp, it was desirable to maximize the temperature of its flame, and minimize its luminosity (which represented lost heating energy). Bunsen sought to improve existing laboratory burner lamps as regards economy, simplicity, and flame temperature, and adapt them to coal-gas fuel. While the building was under construction in late 1854, Bunsen suggested certain design principles to the university's mechanic, Peter Desaga, and asked him to construct a prototype. Similar principles had been used in an earlier burner design by
Michael Faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English chemist and physicist who contributed to the study of electrochemistry and electromagnetism. His main discoveries include the principles underlying electromagnetic inducti ...
, and in a device patented in 1856 by gas engineer R. W. Elsner. The Bunsen/Desaga design generated a hot, sootless, non-luminous flame by mixing the gas with air in a controlled fashion before combustion. Desaga created adjustable slits for air at the bottom of the cylindrical burner, with the flame issuing at the top. When the building opened early in 1855, Desaga had made 50 burners for Bunsen's students. Two years later Bunsen published a description, and many of his colleagues soon adopted the design. Bunsen burners are now used in laboratories around the world.


Operation

The device in use today safely burns a continuous stream of a flammable gas such as
natural gas Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium ...
(which is principally
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
) or a
liquefied petroleum gas Liquefied petroleum gas, also referred to as liquid petroleum gas (LPG or LP gas), is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, Butane, ''n''-butane and isobutane. It can also contain some ...
such as
propane Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum ref ...
,
butane Butane () is an alkane with the formula C4H10. Butane exists as two isomers, ''n''-butane with connectivity and iso-butane with the formula . Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at ro ...
, or a mixture of both. The hose barb is connected to a gas nozzle on the laboratory bench with rubber tubing. Most laboratory benches are equipped with multiple gas nozzles connected to a central gas source, as well as vacuum,
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, and steam nozzles. The gas then flows up through the base through a small hole at the bottom of the barrel and is directed upward. There are open slots in the side of the tube bottom to admit air into the stream using the Venturi effect, and the gas burns at the top of the tube once ignited by a flame or spark. The most common methods of lighting the burner are using a
match A match is a tool for starting a fire. Typically, matches are made of small wooden sticks or stiff paper. One end is coated with a material that can be ignited by friction generated by striking the match against a suitable surface. Wooden matc ...
or a spark lighter. The amount of air mixed with the gas stream affects the completeness of the
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
reaction. Less air yields an incomplete and thus cooler reaction, while a gas stream well mixed with air provides oxygen in a
stoichiometric Stoichiometry () is the relationships between the masses of reactants and products before, during, and following chemical reactions. Stoichiometry is based on the law of conservation of mass; the total mass of reactants must equal the total m ...
amount and thus a complete and hotter reaction. The air flow can be controlled by opening or closing the slot openings at the base of the barrel, similar in function to the choke in a
carburettor A carburetor (also spelled carburettor or carburetter) is a device used by a gasoline internal combustion engine to control and mix air and fuel entering the engine. The primary method of adding fuel to the intake air is through the Vent ...
. If the collar at the bottom of the tube is adjusted so more air can mix with the gas before combustion, the flame will burn hotter, appearing blue as a result. If the holes are closed, the gas will only mix with ambient air at the point of combustion, that is, only after it has exited the tube at the top. This reduced mixing produces an incomplete reaction, producing a cooler but brighter yellow, which is often called the "safety flame" or " luminous flame". The yellow flame is luminous due to small
soot Soot ( ) is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons. Soot is considered a hazardous substance with carcinogenic properties. Most broadly, the term includes all the particulate matter produced b ...
particles in the flame, which are heated to
incandescence Thermal radiation is electromagnetic radiation emitted by the thermal motion of particles in matter. All matter with a temperature greater than absolute zero emits thermal radiation. The emission of energy arises from a combination of electron ...
. The yellow flame is considered "dirty" because it leaves a layer of carbon on whatever it is heating. When the burner is regulated to produce a hot, blue flame, it can be nearly invisible against some backgrounds. The hottest part of the flame is the tip of the inner flame, while the coolest is the whole inner flame. Increasing the amount of fuel gas flow through the tube by opening the
needle valve A needle valve is a type of valve with a small port and a screw thread, threaded, needle-shaped plunger. It allows wikt:precision, precise regulation of Fluid dynamics, flow, although it is generally only capable of relatively low flow rates. ...
will increase the size of the flame. However, unless the airflow is adjusted as well, the flame temperature will decrease because an increased amount of gas is now mixed with the same amount of air, starving the flame of oxygen. Generally, the burner is placed underneath a laboratory tripod, which supports a beaker or other container. The burner will often be placed on a suitable heatproof mat to protect the laboratory bench surface. A Bunsen burner is also used in
microbiology Microbiology () is the branches of science, scientific study of microorganisms, those being of unicellular organism, unicellular (single-celled), multicellular organism, multicellular (consisting of complex cells), or non-cellular life, acellula ...
laboratories to sterilise pieces of equipment and to produce an updraft that forces airborne contaminants away from the working area.


Variants

Other burners based on the same principle exist. The most important alternatives to the Bunsen burner are: * Teclu burner – The lower part of its tube is conical, with a round screw nut below its base. The gap, set by the distance between the nut and the end of the tube, regulates the influx of the air in a way similar to the open slots of the Bunsen burner. The Teclu burner provides better mixing of air and fuel and can achieve higher flame temperatures than the Bunsen burner. * Meker burner – The lower part of its tube has more openings with larger total cross-section, admitting more air and facilitating better mixing of air and gas. The tube is wider and its top is covered with a wire grid. The grid separates the flame into an array of smaller flames with a common external envelope, and also prevents flashback to the bottom of the tube, which is a risk at high air-to-fuel ratios and limits the maximum rate of air intake in a conventional Bunsen burner. Flame temperatures of up to are achievable if properly used. The flame also burns without noise, unlike the Bunsen or Teclu burners. * Tirrill burner – The base of the burner has a needle valve which allows the regulation of gas intake directly from the burner, rather than from the gas source. Maximum temperature of flame can reach 1560 °C.


See also

* Alcohol burner * Heating mantle * Meker-Fisher burner


References


External links

* * {{DEFAULTSORT:Bunsen Burner Burners Combustion engineering German inventions Laboratory equipment