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Wüstite
Wüstite ( Fe O, sometimes also written as Fe0.95O) is a mineral form of mostly iron(II) oxide found with meteorites and native iron. It has a grey colour with a greenish tint in reflected light. Wüstite crystallizes in the isometric-hexoctahedral crystal system in opaque to translucent metallic grains. It has a Mohs hardness of 5 to 5.5 and a specific gravity of 5.88. Wüstite is a typical example of a non-stoichiometric compound. Wüstite was named after Fritz Wüst (1860–1938), a German metallurgist and founding director of the ''Kaiser-Wilhelm-Institut für Eisenforschung'' (presently Max Planck Institute for Iron Research GmbH). In addition to its type locality in Germany, it has been reported from Disko Island, Greenland; the Jharia coalfield, Jharkhand, India; and as inclusions in diamonds in a number of kimberlite pipes. It also is reported from deep sea manganese nodules. Its presence indicates a highly reducing environment. Wüstite redox buffer I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a permanent magnet itself. With the exception of extremely rare native iron deposits, it is the most magnetic of all the naturally occurring minerals on Earth. Naturally magnetized pieces of magnetite, called lodestone, will attract small pieces of iron, which is how ancient peoples first discovered the property of magnetism. Magnetite is black or brownish-black with a metallic luster, has a Mohs scale of mineral hardness, Mohs hardness of 5–6 and leaves a black streak (mineralogy), streak. Small grains of magnetite are very common in igneous rocks, igneous and metamorphic rocks. The chemical IUPAC name is iron(II,III) oxide and the common chemical name is ''ferrous-ferric oxide''. Properties In addition to igneous rocks, magnetite als ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Periclase
Periclase is a magnesium mineral that occurs naturally in contact metamorphic rocks and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide ( Mg O). In nature it usually forms a solid solution with wüstite (FeO) and is then referred to as ferropericlase or magnesiowüstite. It was first described in 1840 and named from the Greek περικλάω (to break around) in allusion to its cleavage. The type locality is Monte Somma, Somma-Vesuvius Complex, Naples Province, Campania, Italy. The old term for the mineral is ''magnesia''. Stones from the Magnesia region in ancient Anatolia contained both magnesium oxide and hydrated magnesium carbonate as well as iron oxides (such as magnetite). Thus these stones, called ''Stones from Magnesia'' in antiquity, with their unusual magnetic properties were the reason the terms ''magnet'' and ''magnetism'' were coined. Periclase is usually found in marble produced by metamorphism of dolomitic lim ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's outer and inner core. It is the fourth most abundant element in the Earth's crust, being mainly deposited by meteorites in its metallic state. Extracting usable metal from iron ores requires kilns or furnaces capable of reaching , about 500 °C (900 °F) higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BC and the use of iron tools and weapons began to displace copper alloys – in some regions, only around 1200 BC. That event is considered the transition from the Bronze Age to the Iron Age. In the modern world, iron alloys, such as steel, stainless steel, cast iron and special steels, are by far the most common industrial metals, due to their mechan ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Non-stoichiometric Compound
Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogeneous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometric examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula , whereas the more common material is nonstoichiometric, w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other chemical compound, compounds. Oxygen is abundance of elements in Earth's crust, the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. It is abundance of chemical elements, the third-most abundant element in the universe after hydrogen and helium. At standard temperature and pressure, two oxygen atoms will chemical bond, bind covalent bond, covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron(II) Oxide
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite. One of several iron oxides, it is a black-colored powder that is sometimes confused with rust, the latter of which consists of hydrated iron(III) oxide (ferric oxide). Iron(II) oxide also refers to a family of related non-stoichiometric compounds, which are typically iron deficient with compositions ranging from Fe0.84O to Fe0.95O. Preparation FeO can be prepared by the thermal decomposition of iron(II) oxalate. : The procedure is conducted under an inert atmosphere to avoid the formation of iron(III) oxide (). A similar procedure can also be used for the synthesis of manganous oxide and stannous oxide. Stoichiometric FeO can be prepared by heating Fe0.95O with metallic iron at 770 °C and 36 kbar.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford University Press Reactions FeO is thermodynamically unstable below 575 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . It has the same crystal structure as corundum () and ilmenite (). With this it forms a complete solid solution at temperatures above . Hematite occurs naturally in black to steel or silver-gray, brown to reddish-brown, or red colors. It is mined as an important ore mineral of iron. It is electrically conductive. Hematite varieties include ''kidney ore'', ''martite'' ( pseudomorphs after magnetite), ''iron rose'' and ''specularite'' ( specular hematite). While these forms vary, they all have a rust-red streak. Hematite is not only harder than pure iron, but also much more brittle. The term ''kidney ore'' may be broadly used to describe botryoidal, mammillary, or reniform hematite. Maghemite is a polymorph of hematite (γ-) with the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reducing Environment
A reducing atmosphere is an atmosphere in which oxidation is prevented by the absence of oxygen and other oxidizing gases or vapours, and which may contain actively reductant gases such as hydrogen, carbon monoxide, methane and hydrogen sulfide that would be readily oxidized to remove any free oxygen. Although Early Earth had a reducing prebiotic atmosphere prior to the Proterozoic eon, starting at about 2.5 billion years ago in the late Neoarchaean period, the Earth's atmosphere experienced a significant rise in oxygen and transitioned to an oxidizing atmosphere with a surplus of molecular oxygen (dioxygen, O2) as the primary oxidizing agent. Foundry operations The principal mission of an iron foundry is the conversion of iron oxides (purified iron ores) to iron metal. This reduction is usually effected using a reducing atmosphere consisting of some mixture of natural gas, hydrogen (H2), and carbon monoxide. The byproduct is carbon dioxide. Metal processing In metal pro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Manganese Nodule
Polymetallic nodules, also called manganese nodules, are mineral concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. As nodules can be found in vast quantities, and contain valuable metals, deposits have been identified as a potential economic interest. Depending on their composition and authorial choice, they may also be called ferromanganese nodules. Ferromanganese nodules are mineral concretions composed of silicates and insoluble iron and manganese oxides that form on the ocean seafloor and terrestrial soils. The formation mechanism involves a series of redox oscillations driven by both abiotic and biotic processes. As a byproduct of pedogenesis, the specific composition of a ferromanganese nodule depends on the composition of the surrounding soil. The formation mechanisms and composition of the nodules allow for couplings with biogeochemical cycles beyond iron and manganese. The high relative abundance of nickel, cop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known as the main host matrix for diamonds. It is named after the town of Kimberley, Northern Cape, Kimberley in South Africa, where the discovery of an 83.5-Carat (mass), carat (16.70 g) diamond called the Star of South Africa (diamond), Star of South Africa in 1869 spawned a diamond rush and led to the excavation of the open-pit mine called the Big Hole. Previously, the term kimberlite has been applied to olivine lamproites as Kimberlite II, however this has been in error. Kimberlite occurs in the Earth's Crust (geology), crust in vertical structures known as Volcanic pipe, kimberlite pipes, as well as igneous Dike (geology), dykes and can also occur as horizontal Sill (geology), sills. Kimberlite pipes are the most important source of mined diamonds today. The consensus on kimberlites is that they are formed deep within Earth's mantle. Formation occurs at depths between 150 and 450 kilometres ( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
