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Thermal Cracking
In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of a large alkane into smaller, more useful alkenes. Simply put, hydrocarbon cracking is the process of breaking a long chain of hydrocarbons into short ones. This process requires high temperatures. More loosely, outside the field of petroleum chemistry, the term "cracking" is used to describe any type of splitting of molecules under the influence of heat, catalysts and solvents, such as in processes of destructive distillation or pyrolysis. Fluid catalytic cracking produces a high yield of petrol and LPG, while hydrocracking is a major source of jet fuel, diese ...
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Petrochemistry
Petrochemicals (sometimes abbreviated as petchems) are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sources such as maize, palm fruit or sugar cane. The two most common petrochemical classes are olefins (including ethylene and propylene) and aromatics (including benzene, toluene and xylene isomers). Oil refineries produce olefins and aromatics by fluid catalytic cracking of petroleum fractions. Chemical plants produce olefins by steam cracking of natural gas liquids like ethane and propane. Aromatics are produced by catalytic reforming of naphtha. Olefins and aromatics are the building-blocks for a wide range of materials such as solvents, detergents, and adhesives. Olefins are the basis for polymers and oligomers used in plastics, resins, fibers, elastomers, lubricants, and gels. Global ethylene production was 190 million tonnes and ...
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Liquefied Petroleum Gas
Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cooking equipment, and vehicles. It is increasingly used as an aerosol propellant and a refrigerant, replacing chlorofluorocarbons in an effort to reduce damage to the ozone layer. When specifically used as a vehicle fuel, it is often referred to as autogas or even just as gas. Varieties of LPG that are bought and sold include mixes that are mostly propane (), mostly butane (), and, most commonly, mixes including both propane and butane. In the northern hemisphere winter, the mixes contain more propane, while in summer, they contain more butane. In the United States, mainly two grades of LPG are sold: commercial propane and HD-5. These specifications are published by the Gas Processors Association (GPA) and the American Society of Testing and M ...
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Visbreaker
A visbreaker is a processing unit in an oil refinery whose purpose is to reduce the quantity of residual oil produced in the distillation of crude oil and to increase the yield of more valuable middle distillates (heating oil and diesel) by the refinery. A visbreaker thermally cracks large hydrocarbon molecules in the oil by heating in a furnace to reduce its viscosity and to produce small quantities of light hydrocarbons. ( LPG and gasoline). The process name of "visbreaker" refers to the fact that the process reduces (i.e., breaks) the viscosity of the residual oil. The process is non- catalytic. Process objectives The objectives of visbreaking are: * Reduce the viscosity of the feed stream: Typically this is the residue from vacuum distillation of crude oil but can also be the residue from hydroskimming operations, natural bitumen from seeps in the ground or tar sands, and even certain high viscosity crude oils. * Reduce the amount of residual fuel oil produced by a ref ...
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Fluid Catalytic Cracking
Fluid Catalytic Cracking (FCC) is the conversion process used in petroleum refineries to convert the high-boiling point, high-molecular weight hydrocarbon fractions of petroleum (crude oils) into gasoline, olefinic gases, and other petroleum products. The cracking of petroleum hydrocarbons was originally done by thermal cracking, now virtually replaced by catalytic cracking, which yields greater volumes of high octane rating gasoline; and produces by-product gases, with more carbon-carbon double bonds (i.e. olefins), that are of greater economic value than the gases produced by thermal cracking. The feedstock to the FCC conversion process usually is heavy gas oil (HGO), which is that portion of the petroleum (crude oil) that has an initial boiling-point temperature of or higher, at atmospheric pressure, and that has an average molecular weight that ranges from about 200 to 600 or higher; heavy gas oil also is known as “heavy vacuum gas oil” (HVGO). In the fluid catalytic ...
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Russian Civil War
{{Infobox military conflict , conflict = Russian Civil War , partof = the Russian Revolution and the aftermath of World War I , image = , caption = Clockwise from top left: {{flatlist, *Soldiers of the Don Army *Soldiers of the Siberian Army *Suppression of the Kronstadt rebellion *American troop in Vladivostok during the intervention *Victims of the Red Terror in Crimea *Hanging of workers in Yekaterinoslav by the Austrians *A review of Red Army troops in Moscow. , date = 7 November 1917 – 16 June 1923{{Efn, The main phase ended on 25 October 1922. Revolt against the Bolsheviks continued in Central Asia and the Far East through the 1920s and 1930s.{{cite book, last=Mawdsley, first=Evan, title=The Russian Civil War, location=New York, publisher=Pegasus Books, year=2007, isbn=9781681770093, url=https://archive.org/details/russiancivilwar00evan, url-access=registration{{rp, 3,230(5 years, 7 months and 9 day ...
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Russian Revolution
The Russian Revolution was a period of political and social revolution that took place in the former Russian Empire which began during the First World War. This period saw Russia abolish its monarchy and adopt a socialist form of government following two successive revolutions and a bloody civil war. The Russian Revolution can also be seen as the precursor for the other European revolutions that occurred during or in the aftermath of WWI, such as the German Revolution of 1918. The Russian Revolution was inaugurated with the February Revolution in 1917. This first revolt focused in and around the then-capital Petrograd (now Saint Petersburg). After major military losses during the war, the Russian Army had begun to mutiny. Army leaders and high ranking officials were convinced that if Tsar Nicholas II abdicated, the domestic unrest would subside. Nicholas agreed and stepped down, ushering in a new government led by the Russian Duma (parliament) which became the Russian Pr ...
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Sinclair Oil Corporation
Sinclair Oil Corporation was an American petroleum corporation, founded by Harry F. Sinclair on May 1, 1916, the Sinclair Oil and Refining Corporation combined, amalgamated, the assets of 11 small petroleum companies. Originally a New York corporation, Sinclair Oil reincorporated in Wyoming in 1976. The corporation's logo featured the silhouette of a large green sauropod dinosaur, based on the then-common idea that oil deposits beneath the earth came from the dead bodies of dinosaurs. It was ranked on the list of largest privately owned American corporations. It owned and operated refineries, gas stations, hotels, a ski resort, and a cattle ranch. History Sinclair has long been a fixture on American roads with its dinosaur logo and mascot, a ''Brontosaurus''. 1916–1969 During September 1919, Harry Sinclair restructured Sinclair Oil and Refining Corporation, Sinclair Gulf Corporation, and 26 other related entities into Sinclair Consolidated Oil Corporation. In 1932, this n ...
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William Merriam Burton
William Merriam Burton (November 17, 1865 – December 29, 1954) was an American chemist who developed a widely used thermal cracking process for crude oil. Burton was born in Cleveland, Ohio. In 1886, he received a Bachelor of Science degree at Western Reserve University. He earned a PhD at Johns Hopkins University in 1889. Burton initially worked for the Standard Oil refinery at Whiting, Indiana. He became president of Standard Oil from 1918 to 1927, when he retired. The process of thermal cracking invented by Burton, which became on January 7, 1913, doubled the yield of gasoline that can be extracted from crude oil. The first thermal cracking method, the Shukhov cracking process, was invented by Russian engineer Vladimir Shukhov (1853-1939), in the Russian empire, Patent No. 12926, November 27, 1891. Burton died in Miami, Florida. See also *Cracking (chemistry) *Burton process *Shukhov cracking process The Shukhov cracking process is a thermal cracking pro ...
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Vladimir Shukhov
Vladimir Grigoryevich Shukhov (russian: link=no, Влади́мир Григо́рьевич Шу́хов; – 2 February 1939) was a Russian Empire and Soviet engineer-polymath, scientist and architect renowned for his pioneering works on new methods of analysis for structural engineering that led to breakthroughs in industrial design of the world's first hyperboloid structures, diagrid shell structures, tensile structures, gridshell structures, oil reservoirs, pipelines, boilers, ships and barges. He is also the inventor of the first cracking method. Besides the innovations he brought to the oil industry and the construction of numerous bridges and buildings, Shukhov was the inventor of a new family of doubly curved structural forms. These forms, based on non-Euclidean hyperbolic geometry, are known today as hyperboloids of revolution. Shukhov developed not only many varieties of light-weight hyperboloid towers and roof systems, but also the mathematics for their analysis. ...
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Burton Process
The Burton process is a thermal cracking process invented by William Merriam Burton and Robert E. Humphreys, each of whom held a PhD in chemistry from Johns Hopkins University. The process they developed is often called the Burton process. More fairly, though, it should be known as the Burton-Humphreys process, since both men played key roles in its development. This issue was settled in court, although the decision gave primary recognition to Burton. The process uses the destructive distillation of crude oil heated in a still under pressure. In this revolutionary still, different products emerging from a bubble tower at different temperatures and pressures. Of critical importance, the use of these stills more than doubled the production of gasoline from most kinds of oil. The first large-scale use of these towers began with the decision by Standard Oil of Indiana to build 120 stills for an appropriation of $709,000, authorized in 1911. This decision was taken just as the US Supreme ...
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Shukhov Cracking Process
The Shukhov cracking process is a thermal cracking process invented by Vladimir Shukhov and Sergei Gavrilov. Shukhov designed and built the first thermal cracking device for the petrochemical industry. His patent (Shukhov cracking process – patent of Russian empire No. 12926 from November 27, 1891) on cracking was used to invalidate Standard Oil's patents (Burton process – Patent of United States No. 1,049,667 on January 7, 1913) on oil refineries. In 1937 the Shukhov cracking process was superseded by catalytic cracking. It is still in use today to produce diesel. See also * Cracking (chemistry) * Timeline of historic inventions * Burton process The Burton process is a thermal cracking process invented by William Merriam Burton and Robert E. Humphreys, each of whom held a PhD in chemistry from Johns Hopkins University. The process they developed is often called the Burton process. More fai ... References Information on cracking in oil refining* "Vladimir G. Suchov 1 ...
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Russian Cracking
Russian(s) refers to anything related to Russia, including: * Russians (, ''russkiye''), an ethnic group of the East Slavic peoples, primarily living in Russia and neighboring countries *Rossiyane (), Russian language term for all citizens and people of Russia, regardless of ethnicity *Russophone, Russian-speaking person (, ''russkogovoryashchy'', ''russkoyazychny'') * Russian language, the most widely spoken of the Slavic languages * Russian alphabet * Russian cuisine * Russian culture * Russian studies Russian may also refer to: *Russian dressing *''The Russians'', a book by Hedrick Smith *Russian (comics), fictional Marvel Comics supervillain from ''The Punisher'' series *Russian (solitaire), a card game * "Russians" (song), from the album ''The Dream of the Blue Turtles'' by Sting *"Russian", from the album ''Tubular Bells 2003'' by Mike Oldfield *"Russian", from the album '' '' by Caravan Palace *Nik Russian, the perpetrator of a con committed in 2002 *The South African name ...
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