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Polymer Science
Polymer science or macromolecular science is a subfield of materials science concerned with polymers, primarily synthetic polymers such as plastics and elastomers. The field of polymer science includes researchers in multiple disciplines including chemistry, physics, and engineering. Subdisciplines This science comprises three main sub-disciplines: * Polymer chemistry or macromolecular chemistry is concerned with the chemical synthesis and chemical properties of polymers. * Polymer physics is concerned with the physical properties of polymer materials and engineering applications. Specifically, it seeks to present the mechanical, thermal, electronic and optical properties of polymers with respect to the underlying physics governing a polymer microstructure. Despite originating as an application of statistical physics to chain structures, polymer physics has now evolved into a discipline in its own right. * Polymer characterization is concerned with the analysis of chemical st ...
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Celluloid
Celluloids are a class of materials produced by mixing nitrocellulose and camphor, often with added dyes and other agents. Once much more common for its use as photographic film before the advent of safer methods, celluloid's common contemporary uses are table tennis balls, musical instruments, combs, office equipment, and guitar picks. History Nitrocellulose Nitrocellulose-based plastics slightly predate celluloid. Collodion, invented in 1848 and used as a wound dressing and an emulsion for photographic plates, is dried to a celluloid like film. Alexander Parkes The first celluloid as a bulk material for forming objects was made in 1855 in Birmingham, England, by Alexander Parkes, who was never able to see his invention reach full fruition, after his firm went bankrupt due to scale-up costs. Parkes patented his discovery as Parkesine in 1862 after realising a solid residue remained after evaporation of the solvent from photographic collodion. Parkes patented it as a clothi ...
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Viscose
Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. The fibre is used to make textiles for clothing and other purposes. Rayon production involves solubilizing cellulose to allow turning the fibers into required form. Three common ways to solubilize are the cuprammonium process, not in use today, using ammoniacal solutions of copper salts; the viscose process, the most common today, using alkali and carbon sulfide; and the Lyocell process, using amine oxide. The last avoids the neurotoxic carbon sulfide of the viscose process but is also more expensive. Rayon and its variants Rayon is produced by dissolving cell ...
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Fiber
Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene. Synthetic fibers can often be produced very cheaply and in large amounts compared to natural fibers, but for clothing natural fibers can give some benefits, such as comfort, over their synthetic counterparts. Natural fibers Natural fibers develop or occur in the fiber shape, and include those produced by plants, animals, and geological processes. They can be classified according to their origin: *Vegetable fibers are generally based on arrangements of cellulose, often with lignin: examples include cotton, hemp, jute, flax, abaca, piña, ramie, sisal, bagasse, and banana. Plant fibers are employed in the manufacture of paper and textile (cloth), ...
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Hilaire De Chardonnet
Louis-Marie Hilaire Bernigaud de Grange, Count (''Comte'') de Chardonnet (1 May 1839 – 11 March 1924) was a French engineer and industrialist from Besançon, and inventor of artificial silk. In the late 1870s, Chardonnet was working with Louis Pasteur on a remedy to the epidemic that was destroying French silkworms. Failure to clean up a spill in the darkroom resulted in Chardonnet's discovery of nitrocellulose as a potential replacement for real silk. Realizing the value of such a discovery, Chardonnet began to develop his new product. He called his new invention "Chardonnet silk" (''soie de Chardonnet'') and displayed it in the Paris Exhibition of 1889. Unfortunately, Chardonnet's material was extremely flammable, and was subsequently replaced with other, more stable materials. He was the first to patent artificial silk, although Georges Audemars Georges may refer to: Places *Georges River, New South Wales, Australia *Georges Quay (Dublin) *Georges Township, Fayette C ...
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Thomas Hancock (inventor)
Thomas Hancock (8 May 1786 – 26 March 1865), elder brother of inventor Walter Hancock, was an English self-taught manufacturing engineer who founded the British rubber industry. He invented the masticator, a machine that shredded rubber scraps and which allowed rubber to be recycled after being formed into blocks or sheets. A blue plaque commemoration is placed on No. 4 High Street in Marlborough, Wiltshire in his honour (also one for his brother). Early life Hancock was born in 1786 in Marlborough, Wiltshire, and little is known about his early life. His father was a cabinet maker and it is possible that Thomas Hancock was trained in the same trade: in 1815 he is recorded as being in partnership with his brother, Walter, in London, as a coach builder. Career Hancock's interest in rubber seems to have sprung from a desire to make waterproof fabrics to protect the passengers on his coaches. By 1819 he had begun to experiment with making rubber solutions. In 1820 he patented ...
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Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production ...
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Vulcanization
Vulcanization (British: Vulcanisation) is a range of processes for hardening rubbers. The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to include the hardening of other (synthetic) rubbers via various means. Examples include silicone rubber via room temperature vulcanizing and chloroprene rubber (neoprene) using metal oxides. Vulcanization can be defined as the curing of elastomers, with the terms 'vulcanization' and 'curing' sometimes used interchangeably in this context. It works by forming cross-links between sections of polymer chain which results in increased rigidity and durability, as well as other changes in the mechanical and electrical properties of the material. Vulcanization, in common with the curing of other thermosetting polymers, is generally irreversible. The word vulcanization is derived from Vulcan, the Roman god of fire and forge. History Rubber—latex� ...
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Charles Goodyear
Charles Goodyear (December 29, 1800 – July 1, 1860) was an American self-taught chemist and manufacturing engineer who developed vulcanized rubber, for which he received patent number 3633 from the United States Patent Office on June 15, 1844. Goodyear is credited with inventing the chemical process to create and manufacture pliable, waterproof, moldable rubber. Goodyear's discovery of the vulcanization process followed five years of searching for a more stable rubber and stumbling upon the effectiveness of heating after Thomas Hancock. His discovery initiated decades of successful rubber manufacturing in the Lower Naugatuck Valley in Connecticut, as rubber was adopted to multiple applications, including footwear and tires. The Goodyear Tire and Rubber Company is named after him. Early life Charles Goodyear was born on 29 December 1800, in New Haven, Connecticut, the son of Amasa Goodyear, and the oldest of six children. His father was a descendant of Stephen Goodyear, s ...
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Isoprene
Isoprene, or 2-methyl-1,3-butadiene, is a common volatile organic compound with the formula CH2=C(CH3)−CH=CH2. In its pure form it is a colorless volatile liquid. Isoprene is an unsaturated hydrocarbon. It is produced by many plants and animals (including humans) and its polymers are the main component of natural rubber. C. G. Williams named the compound in 1860 after obtaining it from thermal decomposition (pyrolysis) of natural rubber; he correctly deduced the empirical formula C5H8. Natural occurrences Isoprene is produced and emitted by many species of trees (major producers are oaks, poplars, eucalyptus, and some legumes). Yearly production of isoprene emissions by vegetation is around 600 million metric tons, half from tropical broadleaf trees and the remainder primarily from shrubs. This is about equivalent to methane emissions and accounts for around one-third of all hydrocarbons released into the atmosphere. In deciduous forests, isoprene makes up approximately 80 ...
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Rubber
Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, and Indonesia are three of the leading rubber producers. Types of polyisoprene that are used as natural rubbers are classified as elastomers. Currently, rubber is harvested mainly in the form of the latex from the rubber tree (''Hevea brasiliensis'') or others. The latex is a sticky, milky and white colloid drawn off by making incisions in the bark and collecting the fluid in vessels in a process called "tapping". The latex then is refined into the rubber that is ready for commercial processing. In major areas, latex is allowed to coagulate in the collection cup. The coagulated lumps are collected and processed into dry forms for sale. Natural rubber is used extensively in many applications and products, either alone or in combination ...
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Nathaniel Hayward
Nathaniel Manley Hayward (January 19, 1808 – July 18, 1865) was a US businessman and inventor best known for selling a patent to Charles Goodyear that Goodyear later used to develop the process of vulcanization Biography Nathaniel Hayward was born in Easton, Massachusetts on January 19, 1808. Hayward met Goodyear in 1837 and shared with him the discovery he had made, almost accidentally, while working at a rubber factory in Roxbury, Connecticut. He bought some mills in Stoneham, Massachusetts, from Elisha S. Converse, which later became a small settlement called Haywardville. He died in Colchester, Connecticut on July 18, 1865. Hayward's former home in Colchester has been listed on the National Register of Historic Places The National Register of Historic Places (NRHP) is the United States federal government's official list of districts, sites, buildings, structures and objects deemed worthy of preservation for their historical significance or "great artist ...
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