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Polyurea
Polyurea is a type of elastomer that is derived from the reaction product of an isocyanate component and an amine component. The isocyanate can be aromatic or aliphatic in nature. It can be monomer, polymer, or any variant reaction of isocyanates, quasi-prepolymer or a prepolymer. The prepolymer, or quasi-prepolymer, can be made of an amine-terminated polymer resin, or a hydroxyl-terminated polymer resin. The resin blend may be made up of amine-terminated polymer resins, and/or amine-terminated chain extenders. The amine-terminated polymer resins do not have any intentional hydroxyl Moiety (chemistry), moieties. Any hydroxyls are the result of incomplete conversion to the amine-terminated polymer resins. The resin blend may also contain additives or non-primary components. These additives may contain hydroxyls, such as pre-dispersed pigments in a polyol carrier. Normally, the resin blend does not contain a catalyst(s). This is because the reaction between an isocyanate and amine ...
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Polyurethane
Polyurethane (; often abbreviated PUR and PU) is a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane term does not refer to the single type of polymer but a group of polymers. Unlike polyethylene and polystyrene, polyurethanes can be produced from a wide range of starting materials resulting in various polymers within the same group. This chemical variety produces polyurethanes with different chemical structures leading to many List of polyurethane applications, different applications. These include rigid and flexible foams, and coatings, adhesives, Potting (electronics), electrical potting compounds, and fibers such as spandex and polyurethane laminate (PUL). Foams are the largest application accounting for 67% of all polyurethane produced in 2016. A polyurethane is typically produced by reacting a polymeric isocyanate with a polyol. Since a ...
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Spandex
Spandex, Lycra, or elastane is a synthetic fiber known for its exceptional elasticity. It is a polyether- polyurea copolymer that was invented in 1958 by chemist Joseph Shivers at DuPont. Name The name ''spandex'', which is an anagram of the word "expands", is the preferred name in North America. In continental Europe, it is referred to by variants of ''elastane''. It is primarily known as ''Lycra'' in the UK, Ireland, Portugal, Spain, Latin America, Australia, and New Zealand. Brand names for spandex include Lycra (made by The Lycra Company, previously a division of DuPont Textiles and Interiors), Elaspan (The Lycra Company), Acepora ( Taekwang Group), Creora (Hyosung), INVIYA ( Indorama Corporation), ROICA and Dorlastan (Asahi Kasei), Linel (Fillattice), and ESPA ( Toyobo). Production Unlike many other synthetic fibers, spandex cannot be melt-processed because the polymer degrades upon melting. Spandex fibers are produced by several spinning technologies. Typically ...
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Prepolymer
In polymer chemistry, the term prepolymer or pre-polymer, refers to a monomer or system of monomers that have been reacted to an intermediate-molecular mass state. This material is capable of further polymerization by reactive groups to a fully cured, high-molecular-mass state. As such, mixtures of reactive polymers with un-reacted monomers may also be referred to as pre-polymers. The term "pre-polymer" and "polymer precursor" may be interchanged. Polyurethane and polyurea prepolymers In polyurethane chemistry, prepolymers and oligomers are frequently produced and then further formulated into CASE applications - Coatings, Adhesives, Sealants, and Elastomers. An isocyanate (usually a diisocyanate) is reacted with a polyol. All types of polyol may in theory be used to produce polyurethane prepolymers. These then find use in CASE applications. When polyurethane dispersions are synthesized, a prepolymer is first produced usually modified with DMPA. In polyurea prepolymer productio ...
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Isocyanate
In organic chemistry, isocyanate is the functional group with the formula . Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate. Diisocyanates are manufactured for the production of polyurethanes, a class of polymers. Isocyanates should not be confused with cyanate esters and isocyanides, very different families of compounds. The cyanate (cyanate ester) functional group () is arranged differently from the isocyanate group (). Isocyanides have the connectivity , lacking the oxygen of the cyanate groups. Structure and bonding In terms of bonding, isocyanates are closely related to carbon dioxide (CO2) and carbodiimides (C(NR)2). The C−N=C=O unit that defines isocyanates is planar, and the N=C=O linkage is nearly linear. In phenyl isocyanate, the C=N and C=O distances are respectively 1.195 and 1.173  Å. The C−N=C angle is 134.9° and the N=C=O angle is 173.1 ...
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Polyol
In organic chemistry, a polyol is an organic compound containing multiple hydroxyl groups (). The term "polyol" can have slightly different meanings depending on whether it is used in food science or polymer chemistry. Polyols containing two, three and four hydroxyl groups are diols, triols, and tetrols, respectively. Classification Polyols may be classified according to their chemistry. Some of these chemistries are polyether, polyester, polycarbonate and also acrylic polyols. Polyether polyols may be further subdivided and classified as polyethylene oxide or polyethylene glycol (PEG), polypropylene glycol (PPG) and Polytetrahydrofuran or PTMEG. These have 2, 3 and 4 carbons respectively per oxygen atom in the repeat unit. Polycaprolactone polyols are also commercially available. There is also an increasing trend to use biobased (and hence renewable) polyols. Uses Polyether polyols have numerous uses. As an example, polyurethane foam is a big user of polyether polyols. ...
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Synthetic Resins
Synthetic resins are industrially produced resins, typically viscosity, viscous substances that convert into rigid polymers by the process of curing (chemistry), curing. In order to undergo curing, resins typically contain reactive end groups, such as acrylates or epoxides. Some synthetic resins have properties similar to natural plant resins, but many do not. Synthetic resins are of several classes. Some are manufactured by esterification of organic compounds. Some are thermosetting plastics in which the term "resin" is loosely applied to the reactant(s), the product, or both. "Resin" may be applied to one of two monomers in a copolymer, the other being called a "hardener", as in epoxy resins. For thermosetting plastics that require only one monomer, the monomer compound is the "resin". For example, liquid methyl methacrylate is often called the "resin" or "casting resin" while in the liquid state, before it polymerizes and "sets". After setting, the resulting poly(methyl methac ...
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Narrowboat
A narrowboat is a particular type of Barge, canal boat, built to fit the narrow History of the British canal system, locks of the United Kingdom. The UK's canal system provided a nationwide transport network during the Industrial Revolution, but with the advent of the railways, commercial canal traffic gradually diminished and the last regular long-distance transportation of goods by canal had virtually disappeared by 1970. However, some commercial traffic continued. From the 1970s onward narrowboats were gradually being converted into permanent residences or as holiday lettings. Currently, about 8,580 narrowboats are registered as 'permanent homes' on Britain's waterway system and represent a growing alternative community living on semi-permanent moorings or continuously cruising. For any boat to enter a narrow lock, it must be under wide, so most narrowboats are nominally wide. A narrowboat's maximum length is generally , as anything longer will be unable to navigate much ...
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Plastics
Plastics are a wide range of synthetic or semisynthetic materials composed primarily of polymers. Their defining characteristic, plasticity, allows them to be molded, extruded, or pressed into a diverse range of solid forms. This adaptability, combined with a wide range of other properties such as low weight, durability, flexibility, chemical resistance, low toxicity, and low-cost production, has led to their widespread use around the world. While most plastics are produced from natural gas and petroleum, a growing minority are produced from renewable resources like polylactic acid. Between 1950 and 2017, 9.2 billion metric tons of plastic are estimated to have been made, with more than half of this amount being produced since 2004. In 2023 alone, preliminary figures indicate that over 400 million metric tons of plastic were produced worldwide. If global trends in plastic demand continue, it is projected that annual global plastic production will exceed 1.3 billion tons ...
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Organic Compound
Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-containing compounds such as alkanes (e.g. methane ) and its derivatives are universally considered organic, but many others are sometimes considered inorganic, such as certain compounds of carbon with nitrogen and oxygen (e.g. cyanide ion , hydrogen cyanide , chloroformic acid , carbon dioxide , and carbonate ion ). Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, and even ...
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Copolymer
In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are sometimes called ''bipolymers''. Those obtained from three and four monomers are called ''terpolymers'' and ''quaterpolymers'', respectively. Copolymers can be characterized by a variety of techniques such as NMR spectroscopy and size-exclusion chromatography to determine the molecular size, weight, properties, and composition of the material. Commercial copolymers include acrylonitrile butadiene styrene (ABS), styrene/butadiene co-polymer (SBR), nitrile rubber, styrene-acrylonitrile, styrene-isoprene-styrene (SIS) and ethylene-vinyl acetate, all of which are formed by chain-growth polymerization. Another production mechanism is step-growth polymerization, which is used to produce the nylon-12/6/66 copolymer of nylon 12, nylon 6 a ...
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