|
Pharmacolite
Pharmacolite is an uncommon calcium arsenate mineral with formula CaHAsO4·2(H2O). It occurs as soft, white clusters of fibrous crystals and encrustations which crystallize in the monoclinic system. It is the arsenate analogue of the sulfate mineral, sulfate gypsum and the Phosphate mineral, phosphate brushite. Discovery and occurrence Pharmacolite was first described in 1800 for an occurrence in the Sophia Mine in the Böckelsbach Valley of Wittichen, Schenkenzell, Black Forest, Baden-Württemberg, Germany. The name is from the Greek φάρμακον ("pharmakon"), alluding to its poisonous arsenic content. It forms by secondary (oxidizing) processes from primary arsenic minerals. It is associated with picropharmacolite, hornesite, haidingerite and rosslerite. References {{reflist Arsenate minerals Monoclinic minerals Minerals in space group 9 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Picropharmacolite
Picropharmacolite, Ca4Mg(AsO3OH)2(AsO4)2·11H2O, is a rare arsenate mineral. It was named in 1819 from the Greek for bitter, in allusion to its magnesium content, and its chemical similarity to pharmacolite. The mineral irhtemite, Ca4Mg(AsO3OH)2(AsO4)2·4H2O, has the same composition as picropharmacolite, except that it has only four water molecules per formula unit, instead of eleven. It may be formed by the dehydration of picropharmacolite. Structure Infrared spectraAmerican Mineralogist (1974) 59:807 show that picropharmacolite contains water molecules H2O, hydroxyl groups (OH)− co-ordinated with Mg2+ cations, and acid arsenate radicals (HAsO4)2−. There are strong structural similarities with guerinite, Ca5(AsO3OH)2(AsO4)2.9H2O which indicates a similar formula for the two minerals.American Mineralogist (1976) 61:326 X-ray diffraction methods indicate that As, Ca and Mg cations are positioned in corrugated layers parallel to the c axis, the layers being linked by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Pharmacolite (Sainte-Marie-aux-Mines)-Musée De Minéralogie De Strasbourg
Pharmacolite is an uncommon calcium arsenate mineral with formula CaHAsO4·2(H2O). It occurs as soft, white clusters of fibrous crystals and encrustations which crystallize in the monoclinic system. It is the arsenate analogue of the sulfate gypsum and the phosphate brushite. Discovery and occurrence Pharmacolite was first described in 1800 for an occurrence in the Sophia Mine in the Böckelsbach Valley of Wittichen, Schenkenzell, Black Forest, Baden-Württemberg, Germany. The name is from the Greek φάρμακον ("pharmakon"), alluding to its poisonous arsenic content. It forms by secondary (oxidizing) processes from primary arsenic minerals. It is associated with picropharmacolite, hornesite, haidingerite Haidingerite is a calcium arsenate mineral with formula Ca(AsO3OH)·H2O. It crystallizes in the orthorhombic crystal system as short prismatic to equant crystals. It typically occurs as scaly, botryoidal or fibrous coatings.http://rruff.geo.arizona ... and rosslerite. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Arsenate Mineral
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) sO2(OH)2sup>− (example: andyrobertsite). Arsenite minerals are much less common. Both the Dana and the Strunz mineral classifications place the arsenates in with the phosphate minerals. Example arsenate minerals include: *Annabergite Ni3(AsO4)2·8H2O * Austinite CaZn(AsO4)(OH) * Clinoclase Cu3(AsO4)(OH)3 * Conichalcite CaCu(AsO4)(OH) * Cornubite Cu5(AsO4)2(OH)4 * Cornwallite Cu2+5(AsO4)2(OH)2 * Erythrite Co3(AsO4)2·8H2O * Mimetite Pb5(AsO4)3Cl * Olivenite Cu2(AsO4)OH Nickel–Strunz Classification -08- Phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz (mindat.org, 10 ed, pending publication). *Abbreviations: **"*" - disc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Haidingerite
Haidingerite is a calcium arsenate mineral with formula Ca(AsO3OH)·H2O. It crystallizes in the orthorhombic crystal system as short prismatic to equant crystals. It typically occurs as scaly, botryoidal or fibrous coatings.http://rruff.geo.arizona.edu/doclib/hom/haidingerite.pdf Mineral Data Publishing, ''Handbook of Mineralogy'' It is soft, Mohs hardness of 2 to 2.5, and has a specific gravity of 2.95. It has refractive indices of nα = 1.590, nβ = 1.602 and nγ = 1.638.http://www.mindat.org/min-1797.html Mindat with location data It was originally discovered in 1827 in Jáchymov, Czech Republic. It was named to honor Austrian mineralogist Wilhelm Karl Ritter von Haidinger (1795–1871).http://www.webmineral.com/data/Haidingerite.shtml Webmineral data It occurs as a dehydration product of pharmacolite in the Getchell Mine, Nevada. See also * List of minerals named after people This is a list of minerals named after people. The chemical composition of the mineral follows the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Brushite
Brushite is a phosphate mineral with the chemical formula . Crystals of the pure compound belong to the monoclinic space group C2/c and are colorless.Brishite Webmineral It is the phosphate analogue of the pharmacolite. Discovery and occurrence Brushite was first described in 1865 as an occurrence on Aves Island, Nueva Esparta, |
Slag
The general term slag may be a by-product or co-product of smelting (pyrometallurgical) ores and recycled metals depending on the type of material being produced. Slag is mainly a mixture of metal oxides and silicon dioxide. Broadly, it can be classified as ferrous (co-products of processing iron and steel), ferroalloy (a by-product of ferroalloy production) or non-ferrous/ base metals (by-products of recovering non-ferrous materials like copper, nickel, zinc and phosphorus). Within these general categories, slags can be further categorized by their precursor and processing conditions (e.g., blast furnace slags, air-cooled blast furnace slag, granulated blast furnace slag, basic oxygen furnace slag, and electric arc furnace slag). Slag generated from the EAF process can contain toxic metals, which can be hazardous to human and environmental health. Due to the large demand for ferrous, ferralloy, and non-ferrous materials, slag production has increased throughout the years des ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Arsenate Minerals
The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, Double bond, double bonded to one oxygen atom and Single bond, single bonded to a further three oxygen atoms. The four oxygen atoms orient around the arsenic atom in a Tetrahedral molecular geometry, tetrahedral geometry. Resonance (chemistry), Resonance disperses the ion's −3 charge across all four oxygen atoms. Arsenate readily reacts with metals to form arsenate metal Arsenic compounds, compounds. Arsenate is a moderate Oxidant, oxidizer and an electron acceptor, with an electrode potential of +0.56 Volt, V for its Reduction potential, reduction to arsenite. Due to arsenic having the same Valence (chemistry), valency and similar Atomic radii of the elements (data page), atomic radius to phosphorus, arsenate shares similar Tetrahedral molecular geometry, geometry and Reactivity (chemistry), reactivity with phosphate. Arsenate can replace phosphate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Baden-Württemberg
Baden-Württemberg ( ; ), commonly shortened to BW or BaWü, is a states of Germany, German state () in Southwest Germany, east of the Rhine, which forms the southern part of Germany's western border with France. With more than 11.07 million inhabitants across a total area of nearly , it is the third-largest German state by both List of German states by area, area (behind Bavaria and Lower Saxony) and List of German states by population, population (behind North Rhine-Westphalia and Bavaria). The List of cities in Baden-Württemberg by population, largest city in Baden-Württemberg is the state capital of Stuttgart, followed by Mannheim and Karlsruhe. Other major cities are Freiburg im Breisgau, Heidelberg, Heilbronn, Konstanz, Pforzheim, Reutlingen, Tübingen, and Ulm. Modern Baden-Württemberg includes the historical territories of Baden, Prussian Province of Hohenzollern, Hohenzollern, and Württemberg. Baden-Württemberg became a state of West Germany in April 1952 through ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Black Forest
The Black Forest ( ) is a large forested mountain range in the States of Germany, state of Baden-Württemberg in southwest Germany, bounded by the Rhine Valley to the west and south and close to the borders with France and Switzerland. It is the source of the Danube and Neckar rivers. Its highest peak is the Feldberg (Black Forest), Feldberg with an elevation of above sea level. Roughly oblong in shape, with a length of and breadth of up to , it has an area of about . Historically, the area was known for forestry and the mining of ore deposits, but tourism has now become the primary industry, accounting for around 300,000 jobs. There are Baroque fortifications in the Black Forest, several ruined military fortifications dating back to the 17th century. History In ancient times, the Black Forest was known as , after the Celtic deity, Abnoba. In Roman times (Late antiquity), it was given the name ("Marcynian Forest", from the Germanic word ''marka'', "border"). The Black ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
