Lithium Titanate
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Lithium Titanate
Lithium titanates are chemical compounds of lithium, titanium and oxygen. They are mixed oxides and belong to the titanates. The most important lithium titanates are: * lithium titanate spinel, Li4Ti5O12 and the related compounds up to Li7Ti5O12. These titanates are used in lithium-titanate batteries. * lithium metatitanate, a compound with the chemical formula Li2TiO3 and a melting point of It is a white powder with possible applications in tritium breeding materials in nuclear fusion applications. Other lithium titanates, i.e. mixed oxides of the system Li2O–TiO2, are: * Lithium orthotitanate Li4TiO4, melting point of * Ramsdellite lithium titanate Li2Ti3O7 and Li''x''TiO2 (0 ≦ ''x'' ≦ 0.57) with ramsdellite structure. = Lithium metatitanate = Lithium metatitanate is a compound with the chemical formula Li2TiO3. It is a white powder with a melting point of . It is also used as an additive in porcelain enamels and ceramic insulating bodies based on titanates. It is fr ...
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Lithium
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. When cut, it exhibits a metallic luster, but moist air corrodes it quickly to a dull silvery gray, then black tarnish. It never occurs freely in nature, but only in (usually ionic) compounds, such as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride. The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes ...
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Flux (metallurgy)
In metallurgy, a flux () is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining. Some of the earliest known fluxes were sodium carbonate, potash, charcoal, coke, borax, lime, lead sulfide and certain minerals containing phosphorus. Iron ore was also used as a flux in the smelting of copper. These agents served various functions, the simplest being a reducing agent, which prevented oxides from forming on the surface of the molten metal, while others absorbed impurities into the slag, which could be scraped off the molten metal. Fluxes are also used in foundries for removing impurities from molten nonferrous metals such as aluminium, or for adding desirable trace elements such as titanium. As cleaning agents, fluxes facilitate soldering, brazing, and welding by removing oxidation from the metals to be joined. In some applications molten flux a ...
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Calcination
Calcination refers to thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition. The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO3(s) → CaO(s) + CO2(g). Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting. Industrial calcination generally emits carbon dioxide (), making it a major contributor to climate change. A calciner is a steel cylinder that rotates inside a heated furnace and performs indirect high-temperature processing (550–1150 °C, or 1000–2100 °F) within a controlled ...
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Citric Acid
Citric acid is an organic compound with the chemical formula HOC(CO2H)(CH2CO2H)2. It is a colorless weak organic acid. It occurs naturally in citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, which occurs in the metabolism of all aerobic organisms. More than two million tons of citric acid are manufactured every year. It is used widely as an acidifier, as a flavoring, and a chelating agent. A citrate is a derivative of citric acid; that is, the salts, esters, and the polyatomic anion found in solution. An example of the former, a salt is trisodium citrate; an ester is triethyl citrate. When part of a salt, the formula of the citrate anion is written as or . Natural occurrence and industrial production Citric acid occurs in a variety of fruits and vegetables, most notably citrus fruits. Lemons and limes have particularly high concentrations of the acid; it can constitute as much as 8% of the dry weight of these fruits (about 47 g ...
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Lithium Carbonate
Lithium carbonate is an inorganic compound, the lithium salt of carbonate with the formula . This white salt is widely used in the processing of metal oxides. It is listed on the World Health Organization's List of Essential Medicines because it can be used as a treatment for mood disorders such as bipolar disorder. Uses Lithium carbonate is an important industrial chemical. Its main use is as a precursor for compounds used in lithium-ion batteries. Glasses derived from lithium carbonate are useful in ovenware. Lithium carbonate is a common ingredient in both low-fire and high-fire ceramic glaze. It forms low-melting fluxes with silica and other materials. Its alkaline properties are conducive to changing the state of metal oxide colorants in glaze, particularly red iron oxide (). Cement sets more rapidly when prepared with lithium carbonate, and is useful for tile adhesives. When added to aluminium trifluoride, it forms LiF which gives a superior electrolyte for the processi ...
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Breeding Blanket
The tritium breeding blanket (also known as a fusion blanket, lithium blanket or simply blanket), is a key part of many proposed fusion reactor designs. It serves several purposes; one is to act as a cooling mechanism, absorbing the energy from the neutrons produced within the plasma by the nuclear fusion reaction between deuterium and tritium (D-T), another is to "breed" further tritium fuel, that would otherwise be difficult to obtain in sufficient quantities, through the reaction of neutrons with lithium in the blanket. The breeder blanket further serves as shielding, preventing the high-energy neutrons from escaping to the area outside the reactor and protecting the more radiation-susceptible portions, such as ohmic or superconducting magnets, from damage. Of these three duties, it is only the breeding portion that cannot be replaced by other means. For instance, a large quantity of water makes an excellent cooling system and neutron shield, as in the case of a conventional nu ...
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Deuterium
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one neutron, whereas the far more common protium has no neutrons in the nucleus. Deuterium has a natural abundance in Earth's oceans of about one atom of deuterium among all  atoms of hydrogen (see heavy water). Thus deuterium accounts for approximately 0.0156% by number (0.0312% by mass) of all the naturally occurring hydrogen in the oceans, while protium accounts for more than 99.98%. The abundance of deuterium changes slightly from one kind of natural water to another (see Vienna Standard Mean Ocean Water). ( Tritium is yet another hydrogen isotope, with two neutrons, that is far more rare and is radioactive.) The name ''deuterium'' is derived from the Greek , meaning "second", to denote the two particles composing the nucleus. De ...
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ITER
ITER (initially the International Thermonuclear Experimental Reactor, ''iter'' meaning "the way" or "the path" in Latin) is an international nuclear fusion research and engineering megaproject aimed at creating energy by replicating, on Earth, the fusion processes of the Sun. Upon completion of construction of the main reactor and first plasma, planned for late 2025, it will be the world's largest magnetic confinement plasma physics experiment and the largest experimental tokamak nuclear fusion reactor. It is being built next to the Cadarache facility in southern France. ITER will be the largest of more than 100 fusion reactors built since the 1950s, with ten times the plasma volume of any other tokamak operating today. The long-term goal of fusion research is to generate electricity. ITER's stated purpose is scientific research, and technological demonstration of a large fusion reactor, without electricity generation. ITER's goals are to achieve enough fusion to produc ...
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Anode
An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ACID, for "anode current into device". The direction of conventional current (the flow of positive charges) in a circuit is opposite to the direction of electron flow, so (negatively charged) electrons flow out the anode of a galvanic cell, into an outside or external circuit connected to the cell. For example, the end of a household battery marked with a "-" (minus) is the anode. In both a galvanic cell and an electrolytic cell, the anode is the electrode at which the oxidation reaction occurs. In a galvanic cell the anode is the wire or plate having excess negative charge as a result of the oxidation reaction. In an electrolytic cell, the anode is the wire or plate upon which excess positive charge is imposed. As a result of this, an ...
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Lithium-titanate Battery
The lithium-titanate or lithium-titanium-oxide (LTO) battery is a type of rechargeable battery which has the advantage of being faster to charge than other lithium-ion batteries but the disadvantage of having a much lower energy density. Uses Titanate batteries are used in certain Japanese-only versions of Mitsubishi's i-MiEV electric vehicle as well as Honda's EV-neo electric bike and Fit EV. They are also used in the Tosa concept electric bus. Because of the battery's high level of safety and recharge capabilities, LTO batteries are used in car audio applications as well as mobile medical devices. An LTO battery is also used in the S-Pen that comes with the Samsung Galaxy Note 20 Ultra 5G. According to a Weatherflow Co. article, the Tempest weather-station device contains a 1300mAh LTO battery, charged via four solar panels, requiring "at least 4 hours of adequate sunlight every two weeks." Chemistry A lithium-titanate battery is a modified lithium-ion battery that u ...
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Lithium-ion Batteries
A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also sees significant use for grid-scale energy storage and military and aerospace applications. Compared to other rechargeable battery technologies, Li-ion batteries have high energy densities, low self-discharge, and no memory effect (although a small memory effect reported in LFP cells has been traced to poorly made cells). Chemistry, performance, cost and safety characteristics vary across types of lithium-ion batteries. Most commercial Li-ion cells use intercalation compounds as the active materials. The anode or negative electrode is usually graphite, although silicon-carbon is also being increasingly used. Cells can be manufactured to prioritize either energy or power density. Handheld electronics mostly use lithium polymer batteri ...
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Molten Carbonate Fuel Cell
Molten-carbonate fuel cells (MCFCs) are high-temperature fuel cells that operate at temperatures of 600 °C and above. Molten carbonate fuel cells (MCFCs) were developed for natural gas, biogas (produced as a result of anaerobic digestion or biomass gasification), and coal- based power plants for electrical utility, industrial, and military applications. MCFCs are high-temperature fuel cells that use an electrolyte composed of a molten carbonate salt mixture suspended in a porous, chemically inert ceramic matrix of beta-alumina solid electrolyte (BASE). Since they operate at extremely high temperatures of 650 °C (roughly 1,200 °F) and above, non-precious metals can be used as catalysts at the anode and cathode, reducing costs. Improved efficiency is another reason MCFCs offer significant cost reductions over phosphoric acid fuel cells (PAFCs). Molten carbonate fuel cells can reach efficiencies approaching 60%, considerably higher than the 37–42% efficienci ...
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