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Formal Charges
In chemistry, a formal charge (F.C. or ), in the covalent view of Chemical bond, chemical bonding, is the hypothetical electric charge, charge assigned to an atom in a molecule, assuming that electrons in all chemical bonds are shared equally between atoms, regardless of relative electronegativity. In simple terms, formal charge is the difference between the number of valence electrons of an atom in a neutral free state and the number assigned to that atom in a Lewis structure. When determining the best Lewis structure (or predominant resonance structure) for a molecule, the structure is chosen such that the formal charge on each of the atoms is as close to zero as possible. The formal charge of any atom in a molecule can be calculated by the following equation: q^ = V - L - \frac where is the number of valence electrons of the neutral atom in isolation (in its ground state); is the number of non-bonding valence electrons assigned to this atom in the Lewis structure of the mo ...
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Formal Charge Principle V
Formal, formality, informal or informality imply the complying with, or not complying with, some set of requirements (forms, in Ancient Greek). They may refer to: Dress code and events * Formal wear Formal wear or full dress is the Western dress code category applicable for the most formal occasions, such as weddings, Baptism, christenings, confirmations, funerals, Easter traditions, Easter and Christmas traditions, in addition to certain ..., attire for formal events * Semi-formal attire, attire for semi-formal events * Informal attire, more controlled attire than casual but less than formal * Formal (university), official university dinner, ball or other event * School formal, official school dinner, ball or other event Logic and mathematics *Formal logic, or symbolic logic ** Informal logic, the complement, whose definition and scope is contentious *Formal fallacy, reasoning of invalid structure ** Informal fallacy, the complement *Informal mathematics, also called naï ...
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Organic Chemistry
Organic chemistry is a subdiscipline within chemistry involving the science, scientific study of the structure, properties, and reactions of organic compounds and organic matter, organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; Greeves, N. and Warren, S. (2012) ''Organic Chemistry''. Oxford University Press. pp. 1–15. . Study of structure determines their structural formula. Study of properties includes Physical property, physical and Chemical property, chemical properties, and evaluation of Reactivity (chemistry), chemical reactivity to understand their behavior. The study of organic reactions includes the organic synthesis, chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical (in silico) study. The range of chemicals studied chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but a ...
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Valence Bond Theory
In chemistry, valence bond (VB) theory is one of the two basic theories, along with molecular orbital (MO) theory, that were developed to use the methods of quantum mechanics to explain chemical bonding. It focuses on how the atomic orbitals of the dissociated atoms combine to give individual chemical bonds when a molecule is formed. In contrast, molecular orbital theory has orbitals that cover the whole molecule. History In 1916, G. N. Lewis proposed that a chemical bond forms by the interaction of two shared bonding electrons, with the representation of molecules as Lewis structures. The chemist Charles Rugeley Bury suggested in 1921 that eight and eighteen electrons in a shell form stable configurations. Bury proposed that the electron configurations in transitional elements depended upon the valence electrons in their outer shell. In 1916, Kossel put forth his theory of the ionic chemical bond (octet rule), also independently advanced in the same year by Gilbert N. Lew ...
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Co2-2
CO or variants may refer to: Chemistry * Carbon monoxide (CO), a colorless, odorless, and tasteless gas * Carbonyl group, composed of a carbon atom double-bonded to an oxygen atom: C=O * Cobalt, a chemical element, symbol Co Computing and telecommunications * .co (second-level domain), the Internet second-level domain meaning "commercial" * .co, the Internet country code top-level domain (ccTLD) for Colombia * Commitment ordering (CO), a concurrency control technique for databases * Telephone exchange, or central office (CO) Mathematics * Cofunction, or Co, in trigonometry * Cuboctahedron, a uniform polyhedron People * Nguyễn Hữu Có (1925–2012), Vietnamese general * Conrado Co (born 1940), Filipino badminton player * Alfredo Co (born 1949), Filipino Sinologist * Atoy Co (born 1951), Filipino actor and basketball coach * Leonard Co (1953–2010), Filipino botanist * Nando Có (born 1973), Bissau-Guinean footballer * Kenedy Có (born 1998), Bissau-Guinean ...
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Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ...
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Enolate
In organic chemistry, enolates are organic anions derived from the deprotonation of carbonyl () compounds. Rarely isolated, they are widely used as reagents in the Organic synthesis, synthesis of organic compounds. Bonding and structure Enolate anions are electronically related to allyl anions. The anionic charge is delocalized over the oxygen and the two carbon sites. Thus they have the character of both an alkoxide and a carbanion. Although they are often drawn as being simple salts, in fact they adopt complicated structures often featuring aggregates. Preparation Deprotonation of enolizable ketones, aromatic alcohols, aldehydes, and esters gives enolates. With strong bases, the deprotonation is quantitative. Typically enolates are generated from using lithium diisopropylamide (LDA). Often, as in conventional Claisen condensations, Mannich reactions, and aldol condensations, enolates are generated in low concentrations with alkoxide bases. Under such conditions, they ex ...
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Organolithium Reagent
In organometallic chemistry, organolithium reagents are chemical compounds that contain carbon–lithium (C–Li) bonds. These reagents are important in organic synthesis, and are frequently used to transfer the organic group or the lithium atom to the substrates in synthetic steps, through nucleophilic addition or simple deprotonation. Organolithium reagents are used in industry as an initiator for anionic polymerization, which leads to the production of various elastomers. They have also been applied in asymmetric synthesis in the pharmaceutical industry. Due to the large difference in electronegativity between the carbon atom and the lithium atom, the C−Li bond is highly ionic. Owing to the polar nature of the C−Li bond, organolithium reagents are good nucleophiles and strong bases. For laboratory organic synthesis, many organolithium reagents are commercially available in solution form. These reagents are highly reactive, and are sometimes pyrophoric. History and ...
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Oligomer
In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relative molecular mass, the structure of which essentially comprises a small plurality of units derived, actually or conceptually, from molecules of lower relative molecular mass.'' The name is composed of Greek elements '' oligo-'', "a few" and '' -mer'', "parts". An adjective form is ''oligomeric''. The oligomer concept is contrasted to that of a polymer, which is usually understood to have a large number of units, possibly thousands or millions. However, there is no sharp distinction between these two concepts. One proposed criterion is whether the molecule's properties vary significantly with the removal of one or a few of the units. An oligomer with a specific number of units is referred to by the Greek prefix denoting that number, w ...
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Formal Charge Conventions
Formal, formality, informal or informality imply the complying with, or not complying with, some set of requirements (forms, in Ancient Greek). They may refer to: Dress code and events * Formal wear, attire for formal events * Semi-formal attire, attire for semi-formal events * Informal attire, more controlled attire than casual but less than formal * Formal (university), official university dinner, ball or other event * School formal, official school dinner, ball or other event Logic and mathematics *Formal logic, or symbolic logic ** Informal logic, the complement, whose definition and scope is contentious *Formal fallacy, reasoning of invalid structure ** Informal fallacy, the complement *Informal mathematics, also called naïve mathematics *Formal cause, Aristotle's intrinsic, determining cause *Formal power series, a generalization of power series without requiring convergence, used in combinatorics *Formal calculation, a calculation which is systematic, but without a rig ...
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Coordination Chemistry
A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of chemical bond, bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many metal-containing chemical compound, compounds, especially those that include transition metals (elements like titanium that belong to the periodic table's d-block), are coordination complexes. Nomenclature and terminology Coordination complexes are so pervasive that their structures and reactions are described in many ways, sometimes confusingly. The atom within a ligand that is bonded to the central metal atom or ion is called the donor atom. In a typical complex, a metal ion is bonded to several donor atoms, which can be the same or different. A Ligand#Polydentate and polyhapto ligand motifs and nomenclature, polydentate (multiple bonded) ligand is a molecule or ion that bonds to the central atom ...
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