Chalcanthite
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Chalcanthite
Chalcanthite (, ) is a richly colored blue-green water-soluble sulfate mineral . It is commonly found in the late-stage oxidation zones of copper deposits. Due to its ready solubility, chalcanthite is more common in arid regions. Chalcanthite is a pentahydrate and the most common member of a group of similar hydrated sulfates, the chalcanthite group. These other sulfates are identical in chemical composition to chalcanthite, with the exception of replacement of the copper ion by either manganese as jokokuite, iron as melanterite, or magnesium as pentahydrite. Other names include ''blue stone'', ''blue vitriol'', and ''copper vitriol''. Uses of chalcanthite As chalcanthite is a copper mineral, it can be used as an ore of copper. However, its ready solubility in water means that it tends to crystallize, dissolve, and recrystallize as crusts over any mine surface in more humid regions. Therefore, chalcanthite is only found in the most arid regions in sufficiently large quant ...
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Chalcanthite Crystal Structure
Chalcanthite (, ) is a richly colored blue-green water-soluble sulfate mineral . It is commonly found in the late-stage oxidation zones of copper deposits. Due to its ready solubility, chalcanthite is more common in arid regions. Chalcanthite is a pentahydrate and the most common member of a group of similar hydrated sulfates, the chalcanthite group. These other sulfates are identical in chemical composition to chalcanthite, with the exception of replacement of the copper ion by either manganese as jokokuite, iron as melanterite, or magnesium as pentahydrite. Other names include ''blue stone'', ''blue vitriol'', and ''copper vitriol''. Uses of chalcanthite As chalcanthite is a copper mineral, it can be used as an ore of copper. However, its ready solubility in water means that it tends to crystallize, dissolve, and recrystallize as crusts over any mine surface in more humid regions. Therefore, chalcanthite is only found in the most arid regions in sufficiently large quant ...
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Sulfate Mineral
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 **Anglesite PbSO4 ** Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O ** Kieserite MgSO4·H2O ** Starkeyite MgSO4·4H2O ** Hexahydrite MgSO4·6H2O ** Epsomite MgSO4·7H2O ** Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O ** Antlerite Cu3SO4(OH)4 **Brochantit ...
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Copper(II) Sulfate
Copper(II) sulfate, also known as copper sulphate, is an inorganic compound with the chemical formula . It forms hydrates , where ''n'' can range from 1 to 7. The pentahydrate (''n'' = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate. Older names for the pentahydrate include blue vitriol, bluestone, vitriol of copper,Antoine-François de Fourcroy, tr. by Robert Heron (1796) "Elements of Chemistry, and Natural History: To which is Prefixed the Philosophy of Chemistry". J. Murray and others, Edinburgh. Page 348. and Roman vitriol.Oxford University Press,Roman vitriol, Oxford Living Dictionaries. Accessed on 2016-11-13 It exothermically dissolves in water to give the aquo complex , which has octahedral molecular geometry. The structure of the solid pentahydrate reveals a polymeric structure wherein copper is again octahedral but bound to four water ligands. The centers are interconnected by sulfate anions to form chains. Anhydrous copper su ...
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Copper Poisoning
Copper toxicity (or Copperiedus) is a type of metal poisoning caused by an excess of copper in the body. Copperiedus could occur from consuming excess copper salts, but most commonly it is the result of the genetic condition Wilson's disease and Menke's disease, which are associated with mismanaged transport and storage of copper ions. Copper is essential to human health as it is a component of many proteins. Chronic toxicity by copper is "rare". The suggested safe level of copper in drinking water for humans varies depending on the source, but tends to be pegged at 1.3 mg/L. So low is the toxicity of copper that copper(II) sulfate is a routine reagent in undergraduate chemistry laboratories. Signs and symptoms Acute symptoms of copper poisoning by ingestion include vomiting, hematemesis (vomiting of blood), hypotension (low blood pressure), melena (black "tarry" feces), coma, jaundice (yellowish pigmentation of the skin), and gastrointestinal distress. Individuals with ...
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Crystal Habit
In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities due to limited space in the crystallizing medium (commonly in rocks).Klein, Cornelis, 2007, ''Minerals and Rocks: Exercises in Crystal and Mineral Chemistry, Crystallography, X-ray Powder Diffraction, Mineral and Rock Identification, and Ore Mineralogy,'' Wiley, third edition, Wenk, Hans-Rudolph and Andrei Bulakh, 2004, ''Minerals: Their Constitution and Origin,'' Cambridge, first edition, Recognizing the habit can aid in mineral identification and description, as the crystal habit is an external representation of the internal ordered atomic arrangement. Most natural crystals, however, do not display ideal habits and are commonly malformed. Hence, it is also important to describe the quality of the shape of a mineral specimen: * Euhedral: a c ...
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Melanterite
Melanterite is a mineral form of hydrous iron(II) sulfate: FeSO4·7H2O. It is the iron analogue of the copper sulfate chalcanthite. It alters to siderotil by loss of water. It is a secondary sulfate mineral which forms from the oxidation of primary sulfide minerals such as pyrite and marcasite in the near-surface environment. It often occurs as a ''post mine'' encrustation on old underground mine surfaces. It also occurs in coal and lignite seams exposed to humid air and as a rare sublimate phase around volcanic fumaroles. Associated minerals include pisanite, chalcanthite, epsomite, pickeringite, halotrichite Halotrichite, also known as ''feather alum'', is a highly hydrated sulfate of aluminium and iron. Its chemical formula is FeAl2(SO4)4·22H2O. It forms fibrous monoclinic crystals. The crystals are water-soluble. It is formed by the weathering and ... and other sulfate minerals. It was first described in 1850. Gallery File:Melanterite crystal structure.png, Crystal ...
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Malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur. Etymology and history The stone's name derives (via la, molochītis, frm, melochite, and Middle English ''melochites'') from Greek Μολοχίτης λίθος ''molochites lithos'', "mallow-green stone", from μολόχη ''molochē'', variant of μαλάχη ''malāchē'', "mallow". The mineral was given this name due to its resemblance to the leaves of the mallow plant. Malachite was mined from deposits near the Isthmus of Suez and the Sinai as early as 4000 BCE. It ...
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Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). Is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Etymology The name chalcopyrite comes from the Greek words , which means copper, and ', which means striking fire. It was sometimes historically referred to as "yellow copper". Identification Chalcopyrite is often confused with pyrite and gold since all three of these minerals have a yell ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a natural p ...
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Brochantite
Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy for his fellow Frenchman, geologist and mineralogist A. J. M. Brochant de Villiers. Crystals of brochantite can range from emerald green to black-green to blue-green, and can be acicular or prismatic. Brochantite is often associated with minerals such as malachite, azurite, and chrysocolla, and may form pseudomorphs with these minerals. The mineral is found in a number of locations around the world, notably the southwestern United States (especially Arizona), Serifos in Greece and Chile. Brochantite is a common corrosion product on bronze sculptures located in urban areas, where atmospheric sulfur dioxide (a common pollutant) is present. Brochantitie forms mainly in exposed areas where weathering prevents accumulation copper ions and enhancement in the acidity of water ...
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Aragonite
Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including precipitation from marine and freshwater environments. The crystal lattice of aragonite differs from that of calcite, resulting in a different crystal shape, an orthorhombic crystal system with acicular crystal. Repeated twinning results in pseudo-hexagonal forms. Aragonite may be columnar or fibrous, occasionally in branching helictitic forms called ''flos-ferri'' ("flowers of iron") from their association with the ores at the Carinthian iron mines. Occurrence The type location for aragonite is Molina de Aragón in the Province of Guadalajara in Castilla-La Mancha, Spain, for which it was named in 1797. Aragonite is found in this locality as cyclic twins inside gypsum and marls of the Keuper facies of the Triassic. This type of ar ...
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