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Zirconium Alloys
Zirconium alloys are solid solutions of zirconium or other metals, a common subgroup having the trade mark Zircaloy. Zirconium has very low absorption cross-section of thermal neutrons, high hardness, ductility and corrosion resistance. One of the main uses of zirconium alloys is in nuclear technology, as cladding of fuel rods in nuclear reactors, especially water reactors. A typical composition of nuclear-grade zirconium alloys is more than 95 weight percent zirconium and less than 2% of tin, niobium, iron, chromium, nickel and other metals, which are added to improve mechanical properties and corrosion resistance. The water cooling of reactor zirconium alloys elevates requirement for their resistance to oxidation-related nodular corrosion. Furthermore, oxidative reaction of zirconium with water releases hydrogen gas, which partly diffuses into the alloy and forms zirconium hydrides. The hydrides are less dense and are weaker mechanically than the alloy; their formation results ...
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Nickel
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classifie ...
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Argentina
Argentina, officially the Argentine Republic, is a country in the southern half of South America. It covers an area of , making it the List of South American countries by area, second-largest country in South America after Brazil, the fourth-largest country in the Americas, and the List of countries and dependencies by area, eighth-largest country in the world. Argentina shares the bulk of the Southern Cone with Chile to the west, and is also bordered by Bolivia and Paraguay to the north, Brazil to the northeast, Uruguay and the South Atlantic Ocean to the east, and the Drake Passage to the south. Argentina is a Federation, federal state subdivided into twenty-three Provinces of Argentina, provinces, and one autonomous city, which is the federal capital and List of cities in Argentina by population, largest city of the nation, Buenos Aires. The provinces and the capital have their own constitutions, but exist under a Federalism, federal system. Argentina claims sovereignty ov ...
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Westinghouse Electric Company
Westinghouse Electric Company LLC is an American nuclear power company formed in 1999 from the nuclear power division of the original Westinghouse Electric Corporation. It offers nuclear products and services to utilities internationally, including nuclear fuel, service and maintenance, instrumentation, control and design of nuclear power plants. Westinghouse's world headquarters are located in the Pittsburgh suburb of Cranberry Township, Pennsylvania. The company's main product is the AP1000, a modern pressurized water reactor (PWR) design with many passive safety features and modular construction intended to lower construction time and cost. Twelve AP1000 reactors are currently in operation with a further nineteen in various stages of planning. The company was initially formed as CBS Corporation spun off the remaining pieces of Westinghouse's industrial concerns, as part of Westinghouse's re-creation as a media company. Portions of their nuclear business were initially purc ...
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Pressurized Water Reactor
A pressurized water reactor (PWR) is a type of light-water nuclear reactor. PWRs constitute the large majority of the world's nuclear power plants (with notable exceptions being the UK, Japan, India and Canada). In a PWR, water is used both as a neutron moderator and as coolant fluid for the reactor core. In the core, water is heated by the energy released by the fission of atoms contained in the fuel. Using very high pressure (around 155 bar: 2250 psi) ensures that the water stays in a liquid state. The heated water then flows to a steam generator, where it transfers its thermal energy to the water of a secondary cycle kept at a lower pressure which allows it to vaporize. The resulting steam then drives steam turbines linked to an electric generator. A boiling water reactor (BWR) by contrast does not maintain such a high pressure in the primary cycle and the water thus vaporizes inside of the reactor pressure vessel (RPV) before being sent to the turbine. Most PWR designs ma ...
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CANDU Reactor
The CANDU (CANada Deuterium Uranium) is a Canadian pressurized heavy-water reactor design used to generate electric power. The acronym refers to its deuterium oxide (heavy water) moderator and its use of (originally, natural) uranium fuel. CANDU reactors were first developed in the late 1950s and 1960s by a partnership between Atomic Energy of Canada Limited (AECL), the Hydro-Electric Power Commission of Ontario, Canadian General Electric, and other companies. There have been two major types of CANDU reactors, the original design of around 500  MWe that was intended to be used in multi-reactor installations in large plants, and the optimized CANDU 6 in the 600 MWe class that is designed to be used in single stand-alone units or in small multi-unit plants. CANDU 6 units were built in Quebec and New Brunswick, as well as Pakistan, Argentina, South Korea, Romania, and China. A single example of a non-CANDU 6 design was sold to India. The multi-unit design was used onl ...
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Boiling Water Reactor
A boiling water reactor (BWR) is a type of nuclear reactor used for the generation of electrical power. It is the second most common type of electricity-generating nuclear reactor after the pressurized water reactor (PWR). BWR are thermal neutron reactors, where water is thus used both as a coolant and as a moderator, slowing down neutrons. As opposed to PWR, there is no separation between the reactor pressure vessel (RPV) and the steam turbine in BWR. Water is allowed to vaporize directly inside of the reactor core (at a pressure of approximately 70 bars) before being directed to the turbine which drives the electric generator. Immediately after the turbine, a heat exchanger called a condenser brings the outgoing fluid back into liquid form before it is sent back into the reactor. The cold side of the condenser is made up of the plant's secondary coolant cycle which is fed by the power plant's cold source (generally the sea or a river, more rarely air). The BWR was developed ...
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Niobium
Niobium is a chemical element; it has chemical symbol, symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and Ductility, ductile transition metal. Pure niobium has a Mohs scale of mineral hardness, Mohs hardness rating similar to pure titanium, and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere very slowly, hence its application in jewelry as a hypoallergenic alternative to nickel. Niobium is often found in the minerals pyrochlore and columbite. Its name comes from Greek mythology: Niobe, daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, which makes them difficult to distinguish. English chemist Charles Hatchett reported a new element similar to tantalum in 1801 and named it columbium. In 1809, English chemist William Hyde Wollaston wrongly concluded that tantalum and columbium were identical. German chemist He ...
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Barn (unit)
A barn (symbol: b) is a metric unit of area equal to (100  fm2). This is equivalent to a square that is (10  fm) each side, or a circle of diameter approximately (11.28 fm). Originally used in nuclear physics for expressing the cross sectional area of nuclei and nuclear reactions, today it is also used in all fields of high-energy physics to express the cross sections of any scattering process, and is best understood as a measure of the probability of interaction between small particles. A barn is approximately the cross-sectional area of a uranium nucleus. The barn is also the unit of area used in nuclear quadrupole resonance and nuclear magnetic resonance to quantify the interaction of a nucleus with an electric field gradient. While the barn never was an SI unit, the SI standards body acknowledged it in the 8th SI Brochure (superseded in 2019) due to its use in particle physics. Etymology During Manhattan Project research on the atomic bomb dur ...
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Neutron Cross Section
In nuclear physics, the concept of a neutron cross section is used to express the likelihood of interaction between an incident neutron and a target nucleus. The neutron cross section σ can be defined as the area in cm2 for which the number of neutron-nuclei reactions taking place is equal to the product of the number of incident neutrons that would pass through the area and the number of target nuclei. In conjunction with the neutron flux, it enables the calculation of the reaction rate, for example to derive the thermal power of a nuclear power plant. The standard unit for measuring the cross section is the barn, which is equal to 10−28 m2 or 10−24 cm2. The larger the neutron cross section, the more likely a neutron will react with the nucleus. An isotope (or nuclide) can be classified according to its neutron cross section and how it reacts to an incident neutron. Nuclides that tend to absorb a neutron and either decay or keep the neutron in its nucleus are neutron a ...
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Hafnium
Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1922, by Dirk Coster and George de Hevesy. Hafnium is named after , the Latin name for Copenhagen, where it was discovered. Hafnium is used in filaments and electrodes. Some semiconductor fabrication processes use its oxide for integrated circuits at 45 nanometers and smaller feature lengths. Some superalloys used for special applications contain hafnium in combination with niobium, titanium, or tungsten. Hafnium's large neutron capture cross section makes it a good material for neutron absorption in control rods in nuclear power plants, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear r ...
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Hydrogen Embrittlement
Hydrogen embrittlement (HE), also known as hydrogen-assisted cracking or hydrogen-induced cracking (HIC), is a reduction in the ductility of a metal due to absorbed hydrogen. Hydrogen atoms are small and can Permeation, permeate solid metals. Once absorbed, hydrogen lowers the Stress (mechanics), stress required for cracks in the metal to initiate and propagate, resulting in embrittlement. Hydrogen embrittlement occurs in steels, as well as in iron, nickel, titanium, cobalt, and their alloys. Copper, aluminium, and stainless steels are less susceptible to hydrogen embrittlement. The essential facts about the nature of hydrogen embrittlement have been known since the 19th century. Hydrogen embrittlement is maximised at around room temperature in steels, and most metals are relatively immune to hydrogen embrittlement at temperatures above 150 °C. Hydrogen embrittlement requires the presence of both atomic ("diffusible") hydrogen and a Stress (mechanics), mechanical stress to ...
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