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Trifluoroiodomethane
Trifluoroiodomethane, also referred to as trifluoromethyl iodide is a halomethane with the formula CF3I. It is an experimental alternative to Halon 1301 (CBrF3) in unoccupied areas. It would be used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. Chemistry It is used in the rhodium-catalyzed α-trifluoromethylation of α,β-unsaturated ketones. It can be used as a new generation fire extinguishing agent to replace Halon in fire protection systems. The mechanism of extinguishing fires for CF3I is active and primarily based on interruption of the chain reaction in the combustion area of the flame by so-called "negative" catalytic action. It is also used as an eco-friendly insulation gas to replace SF6 in electrical power industry. In the presence of sunlight or at temperatures above 100 °C it can react with water, forming hazardous by-products such as hydrogen fluoride (HF), hydrogen iodide (HI) and carbonyl fluoride (COF ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trifluoromethylation
Trifluoromethylation in organic chemistry describes any organic reaction that introduces a trifluoromethyl group in an organic compound. Trifluoromethylated compounds are of some importance in pharmaceutical industry and agrochemicals. Several notable pharmaceutical compounds have a trifluoromethyl group incorporated: fluoxetine, mefloquine, leflunomide, nulitamide, dutasteride, bicalutamide, aprepitant, celecoxib, fipronil, fluazinam, penthiopyrad, picoxystrobin, fluridone, norflurazon, sorafenib, and triflurazin. A relevant agrochemical is trifluralin. The development of synthetic methods for adding trifluoromethyl groups to chemical compounds is actively pursued in academic research. History The first to investigate trifluoromethyl groups in relationship to biological activity was F. Lehmann in 1927. An early review appeared in 1958. An early synthetic method was developed by Frédéric Swarts in 1892, based on antimony trifluoride, antimony fluoride. In this reaction benzotrichlo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halomethane
Halomethane compounds are derivatives of methane () with one or more of the hydrogen atoms replaced with halogen atoms (Fluorine, F, Chlorine, Cl, Bromine, Br, or Iodine, I). Halomethanes are both naturally occurring, especially in marine environments, and human-made, most notably as refrigerants, solvents, propellants, and fumigants. Many, including the chlorofluorocarbons, have attracted wide attention because they become active when exposed to ultraviolet light found at high altitudes and destroy the Earth's protective ozone layer. Structure and properties Like methane itself, halomethanes are tetrahedral molecules. The halogen atoms differ greatly in size and charge from hydrogen and from each other. Consequently, most halomethanes deviate from the perfect tetrahedral symmetry of methane.Günter Siegemund, Werner Schwertfeger, Andrew Feiring, Bruce Smart, Fred Behr, Herward Vogel, Blaine McKusick “Fluorine Compounds, Organic” Ullmann's Encyclopedia of Industrial Chemistry, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gaseous Fire Suppression
Gaseous fire suppression, also called clean agent fire suppression, is the use of inert gases and chemical agents to extinguish a fire. These agents are governed by the National Fire Protection Association (NFPA) Standard for Clean Agent Fire Extinguishing Systems – NFPA 2001 in the US, with different standards and regulations elsewhere. The system typically consists of the agent, agent storage containers, agent release valves, fire detectors, fire detection system (wiring control panel, actuation signaling), agent delivery piping, and agent dispersion nozzles. Theory There are four means used by the agents to extinguish a fire. They act on the " fire tetrahedron": * Reduction or isolation of fuel. No agents currently use this as the primary means of fire suppression. * Reduction of heat. Representative agents: Clean agent FS 49 C2 (NAF S 227, MH227, FM-200), Novec 1230, pentafluoroethane (NAF S125, ECARO-25). * Reduction or isolation of oxygen: Representative agents: IG-0 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halomethanes
Halomethane compounds are derivatives of methane () with one or more of the hydrogen atoms replaced with halogen atoms ( F, Cl, Br, or I). Halomethanes are both naturally occurring, especially in marine environments, and human-made, most notably as refrigerants, solvents, propellants, and fumigants. Many, including the chlorofluorocarbons, have attracted wide attention because they become active when exposed to ultraviolet light found at high altitudes and destroy the Earth's protective ozone layer. Structure and properties Like methane itself, halomethanes are tetrahedral molecules. The halogen atoms differ greatly in size and charge from hydrogen and from each other. Consequently, most halomethanes deviate from the perfect tetrahedral symmetry of methane.Günter Siegemund, Werner Schwertfeger, Andrew Feiring, Bruce Smart, Fred Behr, Herward Vogel, Blaine McKusick “Fluorine Compounds, Organic” Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halon 1301
Bromotrifluoromethane, commonly referred to by the code numbers Halon 1301, R13B1, Halon 13B1 or BTM, is an organic halide with the chemical formula carbon, Cbromine, Brfluorine, F3. It is used for gaseous fire suppression as a far less toxic alternative to bromochloromethane. Table of physical properties Synthesis Bromotrifluoromethane is commercially synthesized in a two-step process from chloroform. Chloroform is fluorinated with hydrogen fluoride. CHCl3 + 3 HF → CHF3 + 3 HCl The resulting Fluoroform is then reacted with elemental bromine. CHF3 + Br2 → CF3Br + HBr Uses Halon 1301 was developed in a joint venture between the U.S. Army and Purdue University in the late 1940's, and became a DuPont product in 1954. It was introduced as an effective gaseous fire suppression fixed systems agent in the 1960s, and was used around valuable materials, such as aircraft, Mainframe computer, mainframe computers, and telecommunication telephone exchange, switching centers, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ozone Depletion
Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar regions. The latter phenomenon is referred to as the #Ozone hole and its causes, ozone hole. There are also springtime polar tropospheric ozone depletion events in addition to these stratospheric events. The main causes of ozone depletion and the ozone hole are manufactured chemicals, especially manufactured halocarbon refrigerants, solvents, propellants, and foam-blowing agents (chlorofluorocarbons (CFCs), HCFCs, Haloalkanes, halons), referred to as ''ozone-depleting substances'' (ODS). These compounds are transported into the stratosphere by Turbulence, turbulent mixing after being emitted from the surface, mixing much faster than the molecules can settle. Once in the stratosphere, they release atoms from the halogen group through photod ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fire Suppression Agents
Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. Flames, the most visible portion of the fire, are produced in the combustion reaction when the fuel reaches its ignition point temperature. Flames from hydrocarbon fuels consist primarily of carbon dioxide, water vapor, oxygen, and nitrogen. If hot enough, the gases may become ionized to produce plasma. The color and intensity of the flame depend on the type of fuel and composition of the surrounding gases. Fire, in its most common form, has the potential to result in conflagration, which can lead to permanent physical damage. It directly impacts land-based ecological systems worldwide. The positive effects of fire include stimulating plant growth and maintaining ecological balance. Its negative effects include hazards to life and property, atmospheric pollution, and water contamination. When fire removes protective vegetation, he ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Swedish Defence Materiel Administration
The Swedish Defence Materiel Administration (, FMV) is a Swedish government agency that reports to the Ministry of Defence. The agency is responsible for the supply of materiel to the Swedish defence organisation. It is located in Stockholm. Directors General since 1968 *1968–1975: Sten Wåhlin *1974–1982: Ove Ljung *1982–1988: Carl-Olof Ternryd *1988–1995: Per Borg *1995–2005: Birgitta Böhlin *2005–2012: Gunnar Holmgren *2012–2015: Lena Erixon *2015–2016: Dan Ohlsson (acting) *2016–present: Göran Mårtensson See also *Government agencies in Sweden The government agencies in Sweden are state-controlled organizations that act independently to carry out the policies of the Government of Sweden. The ministries are relatively small and merely policy-making organizations, allowed to monitor the ... References External links * 1968 establishments in Sweden Defence agencies of Sweden Government agencies established in 1968 Government agencies of Sw ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Global Warming Potential
Global warming potential (GWP) is a measure of how much heat a greenhouse gas traps in the atmosphere over a specific time period, relative to carbon dioxide (). It is expressed as a multiple of warming caused by the same mass of carbon dioxide (). Therefore, by definition has a GWP of 1. For other gases it depends on how strongly the gas absorbs thermal radiation, how quickly the gas leaves the atmosphere, and the time frame considered. For example, Methane emissions, methane has a GWP over 20 years (GWP-20) of 81.2. meaning that, a Fugitive gas emissions, leak of a tonne of methane is equivalent to emitting 81.2 tonnes of carbon dioxide measured over 20 years. As methane has a much shorter atmospheric lifetime than carbon dioxide, its GWP is much less over longer time periods, with a GWP-100 of 27.9 and a GWP-500 of 7.95. The carbon dioxide equivalent (e or eq or -e or -eq) can be calculated from the GWP. For any gas, it is the mass of that would warm the earth as much as the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Infrared Window
The infrared atmospheric window is an atmospheric window in the infrared spectrum where there is relatively little absorption of terrestrial thermal radiation by atmospheric gases. The window plays an important role in the atmospheric greenhouse effect by maintaining the balance between incoming solar radiation and outgoing IR to space. In the Earth's atmosphere this window is roughly the region between 8 and 14 μm although it can be narrowed or closed at times and places of high humidity because of the strong absorption in the water vapor continuum or because of blocking by clouds. It covers a substantial part of the spectrum from surface thermal emission which starts at roughly 5 μm. Principally it is a large gap in the absorption spectrum of water vapor. Carbon dioxide plays an important role in setting the boundary at the long wavelength end. Ozone partly blocks transmission in the middle of the window. The importance of the infrared atmospheric window in the atmospheric ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Volcano
A volcano is commonly defined as a vent or fissure in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates are diverging or converging, and because most of Earth's plate boundaries are underwater, most volcanoes are found underwater. For example, a mid-ocean ridge, such as the Mid-Atlantic Ridge, has volcanoes caused by divergent tectonic plates whereas the Pacific Ring of Fire has volcanoes caused by convergent tectonic plates. Volcanoes resulting from divergent tectonic activity are usually non-explosive whereas those resulting from convergent tectonic activity cause violent eruptions."Mid-ocean ridge tectonics, volcanism and geomorphology." Geology 26, no. 455 (2001): 458. https://macdonald.faculty.geol.ucsb.edu/papers/Macdonald%20Mid-Ocean%20Ridge%20Tectonics.pdf Volcanoes can also form where there is str ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
