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Sulfur Dye
Sulfur dyes are the most commonly used dyes manufactured for cotton in terms of volume. They are inexpensive, generally have good colour fastness, wash-fastness, and are easy to apply. Sulfur dyes are predominantly black, brown, and dark blue. Red sulfur dyes are unknown, although a pink or lighter scarlet (color), scarlet color is available. Chemistry Sulfur linkages are the integral part of chromophore in sulfur dyes. They are organosulfur compounds consisting of sulfide (organic), sulfide (–S–), disulfide (–S–S–) and polysulfide (–Sn–) links in heterocyclic rings. They feature thiazoles, thiazone, thianthrene, and phenothiazonethioanthrone subunits. Being nonionic, sulfur dyes are insoluble in water. Process Dyeing includes a few stages, viz. reduction, dyeing, washing, oxidation, soaping, and final washing. The anion is developed on reducing and solubilising at boil when it shows affinity for cellulose. Sodium sulfide (Na2S), the reducing and solubilising agent, pe ...
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Cotton
Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor percentages of waxes, fats, pectins, and water. Under natural conditions, the cotton bolls will increase the dispersal of the seeds. The plant is a shrub native to tropical and subtropical regions around the world, including the Americas, Africa, Egypt and India. The greatest diversity of wild cotton species is found in Mexico, followed by Australia and Africa. Cotton was independently domesticated in the Old and New Worlds. The fiber is most often spun into yarn or thread and used to make a soft, breathable, and durable textile. The use of cotton for fabric is known to date to prehistoric times; fragments of cotton fabric dated to the fifth millennium BC have been found in the Indus Valley civilization, as well as fabric remnants dat ...
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Indophenol
Indophenol is an organic compound with the formula OC6H4NC6H4OH. It is deep blue dye that is the product of the Berthelot's reaction, a common test for ammonia. The indophenol group, with various substituents in place of O''H'' and various ring substitutions, is found in many dyes used in hair coloring and textiles. Indophenol is used in hair dyes, lubricants, redox materials, liquid crystal displays, fuel cells and chemical-mechanical polishing. It is an environmental pollutant and is toxic to fish. Berthelot test In the Berthelot test (1859), a sample suspected of having containing ammonia is treated with sodium hypochlorite and phenol. The formation of indophenol is used to determine ammonia and paracetamol by spectrophotometry. Other phenols can be used. Dichlorophenol-indophenol (DCPIP), a form of indophenol, is often used to determine the presence of vitamin C ( ascorbic acid). Related compounds Indophenol blue is a different compound with systematic name A systema ...
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Glucose
Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using energy from sunlight, where it is used to make cellulose in cell walls, the most abundant carbohydrate in the world. In energy metabolism, glucose is the most important source of energy in all organisms. Glucose for metabolism is stored as a polymer, in plants mainly as starch and amylopectin, and in animals as glycogen. Glucose circulates in the blood of animals as blood sugar. The naturally occurring form of glucose is -glucose, while -glucose is produced synthetically in comparatively small amounts and is less biologically active. Glucose is a monosaccharide containing six carbon atoms and an aldehyde group, and is therefore an aldohexose. The glucose molecule can exist in an open-chain (acyclic) as well as ring (cyclic) fo ...
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Effluent
Effluent is wastewater from sewers or industrial outfalls that flows directly into surface waters either untreated or after being treated at a facility. The term has slightly different meanings in certain contexts, and may contain various pollutants depending on the source. Treating wastewater efficiently is challenging, but improved technology allows for enhanced removal of specific materials, increased re-use of water, and energy production from waste. Definition Effluent is defined by the United States Environmental Protection Agency (EPA) as "wastewater–treated or untreated–that flows out of a treatment plant, sewer, or industrial outfall. Generally refers to wastes discharged into surface waters". The ''Compact Oxford English Dictionary'' defines effluent as "liquid waste or sewage discharged into a river or the sea". Wastewater is not usually described as effluent while being recycled, re-used, or treated until it is released to surface water. Wastewater percola ...
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Sodium Bromate
Sodium bromate, the inorganic compound with the chemical formula of NaBrO3, is the sodium salt of bromic acid. It is a strong oxidant. Uses Sodium bromate is mainly used in continuous or batch dyeing processes involving sulfur or vat dyes and as a hair-permagent, chemical agent, or gold solvent in gold mines when used with sodium bromide. Production Sodium bromate is produced by passing bromine into a solution of sodium carbonate. It may also be produced by the electrolytic oxidation of sodium bromide. Alternatively, it can also be created by the oxidation of bromine with chlorine to sodium hydroxide at 80 °C. 3 Br2+3 Na2CO3 → 5 NaBr+NaBrO3+3 CO2 Human health issues Bromate in drinking water is undesirable because it is a suspected human carcinogen. Its presence in Coca-Cola's Dasani Dasani () is an American brand of bottled water created by the Coca-Cola Company, launched in 1999. It is one of many brands of Coca-Cola bottled water sold around the world. The ...
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Hydrogen Peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%–6% by weight) in water for consumer use, and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or " high-test peroxide", decomposes explosively when heated and has been used as a propellant in rocketry. Hydrogen peroxide is a reactive oxygen species and the simplest peroxide, a compound having an oxygen–oxygen single bond. It decomposes slowly when exposed to light, and rapidly in the presence of organic or reactive compounds. It is typically stored with a stabilizer in a weakly acidic solution in a dark bottle to block light. Hydrogen peroxide is found in biological systems including the human body. Enzymes that use or decompose hydrogen peroxide are classified as peroxidases. Properties The boiling p ...
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Sodium Hydrosulfide
Sodium hydrosulfide is the chemical compound with the formula NaHS. This compound is the product of the half-neutralization of hydrogen sulfide () with sodium hydroxide (NaOH). NaSH and sodium sulfide are used industrially, often for similar purposes. Solid NaSH is colorless. The solid has an odor of owing to hydrolysis by atmospheric moisture. In contrast with sodium sulfide (), which is insoluble in organic solvents, NaSH, being a 1:1 electrolyte, is more soluble. Structure and properties Crystalline NaHS undergoes two phase transitions. At temperatures above 360 K, NaSH adopts the NaCl structure, which implies that the behaves as a spherical anion owing to its rapid rotation, leading to equal occupancy of eight equivalent positions. Below 360 K, a rhombohedral structure forms, and the sweeps out a discoidal shape. Below 114 K, the structure becomes monoclinic. The analogous rubidium and potassium compounds behave similarly. NaSH has a relatively low melting poi ...
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Sodium Sulfide
Sodium sulfide is a chemical compound with the formula Na2 S, or more commonly its hydrate Na2S·9 H2O. Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline mass, in flake form, or as a fused solid. They are water-soluble, giving strongly alkaline solutions. When exposed to moist air, Na2S and its hydrates emit hydrogen sulfide, an extremely toxic, flammable and corrosive gas which smells like rotten eggs. Some commercial samples are specified as Na2S·''x''H2O, where a weight percentage of Na2S is specified. Commonly available grades have around 60% Na2S by weight, which means that ''x'' is around 3. These grades of sodium sulfide are often marketed as 'sodium sulfide flakes'. Structure Na2S adopts the antifluorite structure, which means that the Na+ centers occupy sites of the fluoride ...
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Benzothiazole
Benzothiazole is an aromatic heterocyclic compound with the chemical formula . It is colorless, slightly viscous liquid. Although the parent compound, benzothiazole is not widely used, many of its derivatives are found in commercial products or in nature. Firefly luciferin can be considered a derivative of benzothiazole. Structure and preparation Benzothiazoles consist of a 5-membered 1,3-thiazole ring fused to a benzene ring. The nine atoms of the bicycle and the attached substituents are coplanar. Benzothiazoles are prepared by treatment of 2-mercaptoaniline with acid chlorides: :C6H4(NH2)SH + RC(O)Cl → C6H4(NH)SCR + HCl + H2O Uses Benzothiazole occurs naturally in some foods but is also used as a food additive. It has a sulfurous odor and meaty flavor. The European Food Safety Authority assessment had "no safety concern at estimated levels of intake as a flavouring substance". The heterocyclic core of the molecule is readily substituted at the unique methyn ...
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Diaminotoluene
Toluenediamine may refer to these isomeric organic compounds with the formula C6H3(NH2)2(CH3): * 2,4-Diaminotoluene, precursor to toluene diisocyanate Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). 2,4-TDI is produced in the pure state, but TDI is oft ... and azo dye. *2,6-Diaminotoluene, a common impurity in 2,4-diaminotoluene * 2,5-Diaminotoluene, precursor to hair dyes. {{Chemistry index Alkyl-substituted benzenes ...
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1,4-Diaminobenzene
''p''-Phenylenediamine (PPD) is an organic compound with the formula C6H4(NH2)2. This derivative of aniline is a white solid, but samples can darken due to air oxidation. It is mainly used as a component of engineering polymers and composites like kevlar. It is also an ingredient in hair dyes and is occasionally used as a substitute for henna. Production PPD is produced via three routes. Most commonly, 4-nitrochlorobenzene is treated with ammonia and the resulting 4-nitroaniline is then hydrogenated: :ClC6H4NO2 + 2 NH3 → H2NC6H4NO2 + NH4Cl :H2NC6H4NO2 + 3 H2 → H2NC6H4NH2 + 2 H2O In the DuPont route, aniline is converted to diphenyltriazine, which is then converted by acid-catalysis to 4-aminoazobenzene. Hydrogenation of the latter affords PPD.Robert A. Smiley "Phenylene- and Toluenediamines" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2002, Wiley-VCH, Weinheim. Uses Precursor to polymers PPD is a precursor to aramid plastics and fibers such as ...
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