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Solid Hydrogen
Solid hydrogen is the solid state of the element hydrogen, achieved by decreasing the temperature below hydrogen's melting point of . It was collected for the first time by James Dewar in 1899 and published with the title "Sur la solidification de l'hydrogène" (English: On the solidification of hydrogen) in the ''Annales de Chimie et de Physique'', 7th series, vol. 18, Oct. 1899. Solid hydrogen has a density of 0.086 g/cm3 making it one of the lowest-density solids. Molecular solid hydrogen At low temperatures and at pressures up to around 400 GPa, hydrogen forms a series of solid phases formed from discrete H2 molecules. ''Phase I'' occurs at low temperatures and pressures, and consists of a hexagonal close-packed array of freely rotating H2 molecules. Upon increasing the pressure at low temperature, a transition to ''Phase II'' occurs at up to 110 GPa. Phase II is a broken-symmetry structure in which the H2 molecules are no longer able to rotate freely. If the pressure i ...
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Solid
Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas. The atoms in a solid are bound to each other, either in a regular geometric lattice ( crystalline solids, which include metals and ordinary ice), or irregularly (an amorphous solid such as common window glass). Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because the molecules in a gas are loosely packed. The branch of physics that deals with solids is called solid-state physics, and is the main branch of condensed matter physics (which also includes liquids). Materials s ...
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Compressed Hydrogen
Compressed hydrogen (CH2, CGH2 or CGH2) is the gaseous state of the element hydrogen kept under pressure. Compressed hydrogen in hydrogen tanks at 350 bar (5,000 psi) and 700 bar (10,000 psi) is used for mobile hydrogen storage in hydrogen vehicles. It is used as a fuel gas. Infrastructure Compressed hydrogen is used in hydrogen pipeline transport and in compressed hydrogen tube trailer transport. See also * Cryo-adsorption *Gas compressor * Gasoline gallon equivalent *Hydrogen compressor *Hydrogen safety *Liquid hydrogen * Liquefaction of gases *Metallic hydrogen *Slush hydrogen *Standard cubic foot *Timeline of hydrogen technologies This is a timeline of the history of hydrogen technology. Timeline 16th century * c. 1520 – First recorded observation of hydrogen by Paracelsus through dissolution of metals (iron, zinc, and tin) in sulfuric acid. 17th century * 1625 – F ... References External links COMPRESSED HYDROGEN INFRASTRUCTURE PROGRAM ("CH2IP") Hydrogen p ...
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Solid-state Chemistry
Solid-state chemistry, also sometimes referred as materials chemistry, is the study of the synthesis, structure, and properties of solid phase materials, particularly, but not necessarily exclusively of, non-molecular solids. It therefore has a strong overlap with solid-state physics, mineralogy, crystallography, ceramics, metallurgy, thermodynamics, materials science and electronics with a focus on the synthesis of novel materials and their characterisation. Solids can be classified as crystalline or amorphous on basis of the nature of order present in the arrangement of their constituent particles. History Because of its direct relevance to products of commerce, solid state inorganic chemistry has been strongly driven by technology. Progress in the field has often been fueled by the demands of industry, sometimes in collaboration with academia. Applications discovered in the 20th century include zeolite and platinum-based catalysts for petroleum processing in the 1950s, high-pur ...
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Hydrogen Physics
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occurred about 370, ...
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Air Force Rocket Propulsion Laboratory
The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for liquid water to exist on the Earth's surface, absorbing ultraviolet solar radiation, warming the surface through heat retention (greenhouse effect), and reducing temperature extremes between day and night (the diurnal temperature variation). By mole fraction (i.e., by number of molecules), dry air contains 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.04% carbon dioxide, and small amounts of other gases. Air also contains a variable amount of water vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere. Air composition, temperature, and atmospheric pressure vary with altitude. Within the atmosphere, air suitable for use in photosynthesis by terrestrial plants and breathing of terrestrial animals is found only in ...
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Timeline Of Hydrogen Technologies
This is a timeline of the history of hydrogen technology. Timeline 16th century * c. 1520 – First recorded observation of hydrogen by Paracelsus through dissolution of metals (iron, zinc, and tin) in sulfuric acid. 17th century * 1625 – First description of hydrogen by Johann Baptista van Helmont. First to use the word "gas". * 1650 – Turquet de Mayerne obtained a gas or "inflammable air" by the action of dilute sulphuric acid on iron. * 1662 – Boyle's law (gas law relating pressure and volume) * 1670 – Robert Boyle produced hydrogen by reacting metals with acid. * 1672 – "New Experiments touching the Relation between Flame and Air" by Robert Boyle. * 1679 – Denis Papin – safety valve * 1700 – Nicolas Lemery showed that the gas produced in the sulfuric acid/iron reaction was explosive in air 18th century * 1755 – Joseph Black confirmed that different gases exist. / Latent heat * 1766 – Henry Cavendish published in "On Factitious Airs" a description of ...
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Slush Hydrogen
Slush hydrogen is a combination of liquid hydrogen and solid hydrogen at the triple point with a lower temperature and a higher density than liquid hydrogen. It is commonly formed by repeating a freeze-thaw process. This is most easily done by bringing liquid hydrogen near its boiling point and then reducing pressure using a vacuum pump. The decrease in pressure causes the liquid hydrogen to vaporize/boil - which removes latent heat, and ultimately decreases the temperature of the liquid hydrogen. Solid hydrogen is formed on the surface of the boiling liquid (between the gas/liquid interface) as the liquid is cooled and reaches its triple point. The vacuum pump is stopped, causing an increase of pressure, the solid hydrogen formed on the surface partially melts and begins to sink. The solid hydrogen is agitated in the liquid and the process is repeated. The resulting hydrogen slush has an increased density of 16–20% when compared to liquid hydrogen. It is proposed as a rocket fuel ...
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Metallic Hydrogen
Metallic hydrogen is a phase of hydrogen in which it behaves like an electrical conductor. This phase was predicted in 1935 on theoretical grounds by Eugene Wigner and Hillard Bell Huntington. At high pressure and temperatures, metallic hydrogen can exist as a partial liquid rather than a solid, and researchers think it might be present in large quantities in the hot and gravitationally compressed interiors of Jupiter and Saturn, as well as in some exoplanets. Theoretical predictions Hydrogen under pressure Though often placed at the top of the alkali metal column in the periodic table, hydrogen does not, under ordinary conditions, exhibit the properties of an alkali metal. Instead, it forms diatomic molecules, analogous to halogens and some nonmetals in the second period of the periodic table, such as nitrogen and oxygen. Diatomic hydrogen is a gas that, at atmospheric pressure, liquefies and solidifies only at very low temperature (20 degrees and 14 degrees above absolu ...
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Liquid Hydrogen
Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully liquid state at atmospheric pressure, H2 needs to be cooled to .IPTS-1968
iupac.org, accessed 2020-01-01
A common method of obtaining liquid hydrogen involves a compressor resembling a jet engine in both appearance and principle. Liquid hydrogen is typically used as a concentrated form of hydrogen storage. Storing it as liquid takes less space than storing it as a gas at normal temperature and pressure ...
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Quantum Monte Carlo
Quantum Monte Carlo encompasses a large family of computational methods whose common aim is the study of complex quantum systems. One of the major goals of these approaches is to provide a reliable solution (or an accurate approximation) of the quantum many-body problem. The diverse flavors of quantum Monte Carlo approaches all share the common use of the Monte Carlo method to handle the multi-dimensional integrals that arise in the different formulations of the many-body problem. Quantum Monte Carlo methods allow for a direct treatment and description of complex many-body effects encoded in the wave function, going beyond mean-field theory. In particular, there exist numerically exact and polynomially-scaling algorithms to exactly study static properties of boson systems without geometrical frustration. For fermions, there exist very good approximations to their static properties and numerically exact exponentially scaling quantum Monte Carlo algorithms, but none that ar ...
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Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occur ...
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Density Functional Theory
Density-functional theory (DFT) is a computational quantum mechanical modelling method used in physics, chemistry and materials science to investigate the electronic structure (or nuclear structure) (principally the ground state) of many-body systems, in particular atoms, molecules, and the condensed phases. Using this theory, the properties of a many-electron system can be determined by using functionals, i.e. functions of another function. In the case of DFT, these are functionals of the spatially dependent electron density. DFT is among the most popular and versatile methods available in condensed-matter physics, computational physics, and computational chemistry. DFT has been very popular for calculations in solid-state physics since the 1970s. However, DFT was not considered accurate enough for calculations in quantum chemistry until the 1990s, when the approximations used in the theory were greatly refined to better model the exchange and correlation interactions ...
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