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Sensible Heat
Sensible heat is heat exchanged by a body or thermodynamic system in which the exchange of heat changes the temperature of the body or system, and some macroscopic variables of the body or system, but leaves unchanged certain other macroscopic variables of the body or system, such as volume or pressure. Usage The term is used in contrast to a latent heat, which is the amount of heat exchanged that is hidden, meaning it occurs without change of temperature. For example, during a phase change such as the melting of ice, the temperature of the system containing the ice and the liquid is constant until all ice has melted. Latent and sensible heat are complementary terms. The sensible heat of a thermodynamic process may be calculated as the product of the body's mass (''m'') with its specific heat capacity (''c'') and the change in temperature (\Delta T): : Q_ = m c \Delta T \, . ''Sensible heat'' and ''latent heat'' are not special forms of energy. Rather, they describe exchanges ...
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Heat
In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by such mechanisms as thermal conduction, electromagnetic radiation, and friction, which are microscopic in nature, involving sub-atomic, atomic, or molecular particles, or small surface irregularities, as distinct from the macroscopic modes of energy transfer, which are thermodynamic work and transfer of matter. For a closed system (transfer of matter excluded), the heat involved in a process is the difference in internal energy between the final and initial states of a system, after subtracting the work done in the process. For a closed system, this is the formulation of the first law of thermodynamics. Calorimetry is measurement of quantity of energy transferred as heat by its effect on the states of interacting bodies, for example, by the amount of ice melted or by change in temperature of a body. In the International System of Units (SI), the unit of measurement for he ...
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Vaporization
Vaporization (or vapo(u)risation) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenomenon (a phenomenon in which the whole object or substance is involved in the process). Evaporation Evaporation is a phase transition from the liquid phase to vapor (a state of substance below critical temperature) that occurs at temperatures below the boiling temperature at a given pressure. Evaporation occurs ''on the surface''. Evaporation only occurs when the partial pressure of vapor of a substance is less than the equilibrium vapor pressure. For example, due to constantly decreasing pressures, vapor pumped out of a solution will eventually leave behind a cryogenic liquid. Boiling Boiling is also a phase transition from the liquid phase to gas phase, but boiling is the formation of vapor as bubbles of vapor ''below the surface'' of ...
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Atmospheric Thermodynamics
Atmospheric thermodynamics is the study of heat-to-Work (physics), work transformations (and their reverse) that take place in the Earth's atmosphere and manifest as weather or climate. Atmospheric thermodynamics use the laws of classical thermodynamics, to describe and explain such phenomena as the properties of moist air, the formation of clouds, atmospheric convection, boundary layer meteorology, and vertical instabilities in the atmosphere. Atmospheric thermodynamic diagrams are used as tools in the forecasting of storm development. Atmospheric thermodynamics forms a basis for cloud microphysics and convection parametrization (climate), parameterizations used in numerical weather models and is used in many climate considerations, including convective-equilibrium climate models. Overview The atmosphere is an example of a non-equilibrium system. Atmospheric thermodynamics describes the effect of buoyant forces that cause the rise of less dense (warmer) air, the descent of more d ...
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Thermodynamic Databases For Pure Substances
Thermodynamic databases contain information about List of thermodynamic properties, thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy. Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles. Data is expressed as temperature-dependent values for one mole of substance at the Standard temperature and pressure, standard pressure of 101.325 kPa (1 atm), or 100 kPa (1 bar). Both of these definitions for the Atmospheric pressure, standard condition for pressure are in use. Thermodynamic data Thermodynamic data is usually presented as a table or chart of function values for one mole of a substance (or in the case of the steam tables, one kg). A thermodynamic datafile is a set of equation parameters from which the numerical data values can be calculated. Tables and datafiles are usually presented at a standard pressure of 1 bar or 1 atm, but in the case of steam and ...
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Enthalpy
Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work (physics), work W that was done against constant external pressure P_\text to establish the system's physical dimensions from V_\text=0 to some final volume V_\text (as W=P_\text\Delta V), i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; Bond energy, bond, Lattice energy, lattice, solvation, and other chemical "energies" are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal e ...
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Eddy Covariance
The eddy covariance (also known as eddy correlation and eddy flux) is a key atmospheric measurement technique to measure and calculate vertical turbulent fluxes within planetary boundary layer, atmospheric boundary layers. The method analyses high-frequency wind and scalar (physics), scalar atmospheric data series, gas, energy, and momentum, which yields values of fluxes of these properties. It is a statistics, statistical method used in meteorology and other applications (Microscale meteorology, micrometeorology, oceanography, hydrology, agricultural sciences, industrial and regulatory applications, etc.) to determine exchange rates of trace gases over natural ecosystems and agricultural fields, and to quantify gas emissions rates from other land and water areas. It is frequently used to estimate momentum, heat flux, heat, water vapour, carbon dioxide and methane fluxes.Burba, G., 2013. Eddy Covariance Method for Scientific, Industrial, Agricultural and Regulatory Applications: a ...
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Earth's Atmosphere
The atmosphere of Earth is composed of a layer of gas mixture that surrounds the Earth's planetary surface (both lands and oceans), known collectively as air, with variable quantities of suspended aerosols and particulates (which create weather features such as clouds and hazes), all retained by Earth's gravity. The atmosphere serves as a protective buffer between the Earth's surface and outer space, shields the surface from most meteoroids and ultraviolet solar radiation, keeps it warm and reduces diurnal temperature variation (temperature extremes between day and night) through heat retention (greenhouse effect), redistributes heat and moisture among different regions via air currents, and provides the chemical and climate conditions allowing life to exist and evolve on Earth. By mole fraction (i.e., by quantity of molecules), dry air contains 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.04% carbon dioxide, and small amounts of other trace gases (see Composition below ...
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Flux
Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications in physics. For transport phenomena, flux is a vector quantity, describing the magnitude and direction of the flow of a substance or property. In vector calculus flux is a scalar quantity, defined as the surface integral of the perpendicular component of a vector field over a surface. Terminology The word ''flux'' comes from Latin: ''fluxus'' means "flow", and ''fluere'' is "to flow". As '' fluxion'', this term was introduced into differential calculus by Isaac Newton. The concept of heat flux was a key contribution of Joseph Fourier, in the analysis of heat transfer phenomena. His seminal treatise ''Théorie analytique de la chaleur'' (''The Analytical Theory of Heat''), defines ''fluxion'' as a central quantity and proceeds to derive the now well-known expre ...
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Condensation
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition. Condensation is usually associated with water. Initiation Condensation is initiated by the formation of atomic/molecular clusters of that species within its gaseous volume—like rain drop or snow flake formation within clouds—or at the contact between such gaseous phase and a liquid or solid surface. In clouds, this can be catalyzed by water-nucleating proteins, produced by atmospheric microbes, which are capable of binding gaseous or liquid water molecules. Reversibility scenarios A few distinct rev ...
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Water Vapor
Water vapor, water vapour, or aqueous vapor is the gaseous phase of Properties of water, water. It is one Phase (matter), state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the Sublimation (phase transition), sublimation of ice. Water vapor is transparent, like most constituents of the atmosphere. Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed by condensation. It is less dense than most of the other constituents of air and triggers convection currents that can lead to clouds and fog. Being a component of Earth's hydrosphere and hydrologic cycle, it is particularly abundant in Earth's atmosphere, where it acts as a greenhouse gas and warming feedback, contributing more to total greenhouse effect than non-condensable gases such as carbon dioxide and methane. Use of water vapor, as steam, has been important for cooking, and as a major component in energy prod ...
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Thermodynamic System
A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics. Thermodynamic systems can be passive and active according to internal processes. According to internal processes, passive systems and active systems are distinguished: passive, in which there is a redistribution of available energy, active, in which one type of energy is converted into another. Depending on its interaction with the environment, a thermodynamic system may be an isolated system, a Closed system#In thermodynamics, closed system, or an Open system (systems theory), open system. An isolated system does not exchange matter or energy with its surroundings. A closed system may exchange heat, experience forces, and exert forces, but does not exchange matter. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its ...
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