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Selenidostannate
Selenidostannates are chemical compounds which contain anionic units of selenium connected to tin. They can be considered as stannates where selenium substitutes for oxygen. Similar compounds include the selenogermanates and thiostannates. They are in the category of chalcogenidotetrelates or more broadly chalcogenometallates. Formation Some selenidostannates can be made by treating tin diselenide (SnSe2) with an alkali selenide dissolved in water. Other possible solvents include choline chloride with 1,8-diaminooctane, Properties Most selenidostannates are semiconductors. Their resistance drops on exposure to light. Also selenidostannates are often coloured, most often orange, red or yellow. Many are unstable in humid air, as the water reacts with the selenidostannate to form hydrogen selenide (H2Se). Use Selenidostannates are primarily of research interest. They are under investigation as photoelectric materials. List References {{selenides Selenides Tin c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Selenogermanates
Selenidogermanates are compounds with anions with selenium bound to germanium. They are analogous with germanate In chemistry, germanate is a compound containing an oxyanion of germanium. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central germanium atom, for example potassium hexafluorogermanate, K2GeF6.Eg ...s, thiogermanates, and telluridogermanates. List References {{Germanium compounds Selenides Germanium compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thiostannate
Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermanates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known, Some thiostannate minerals are known. In nature the tin can be partly replaced by arsenic, germanium, antimony or indium. Many thiostannate minerals contain copper, silver or lead. In the field of mineralogy, these compound can be termed sulfostannates or sulphostannates. Different cluster anions are known: nS4sup>4–, nS3sup>2–, n2S5sup>2–, n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tin Diselenide
Tin is a chemical element; it has symbol Sn () and atomic number 50. A silvery-colored metal, tin is soft enough to be cut with little force, and a bar of tin can be bent by hand with little effort. When bent, a bar of tin makes a sound, the so-called "tin cry", as a result of twinning in tin crystals. Tin is a post-transition metal in group 14 of the periodic table of elements. It is obtained chiefly from the mineral cassiterite, which contains stannic oxide, . Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable +4. Tin is the 49th most abundant element on Earth, making up 0.00022% of its crust, and with 10 stable isotopes, it has the largest number of stable isotopes in the periodic table, due to its magic number of protons. It has two main allotropes: at room temperature, the stable allotrope is β-tin, a silvery-white, malleable metal; at low temperatures it is les ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Choline Chloride
Choline chloride is an organic compound with the formula . It is a quaternary ammonium salt, consisting of choline cations () and chloride anions (). It is a bifunctional compound, meaning, it contains both a quaternary ammonium functional group and a hydroxyl functional group. The cation of this salt, choline, occurs in nature in living beings. Choline chloride is a white, water-soluble salt used mainly in animal feed. Synthesis In the laboratory, choline can be prepared by methylation of dimethylethanolamine with methyl chloride. Choline chloride is mass-produced with world production estimated at 160 000 tons in 1999. Industrially, it is produced by the reaction of ethylene oxide, hydrogen chloride, and trimethylamine, or from the pre-formed salt: : Choline chloride can also be made by treating trimethylamine with 2-chloroethanol. : Applications It is an important additive in feed especially for chickens where it accelerates growth. It forms a deep eutectic solvent with ure ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Selenide
Hydrogen selenide is an inorganic compound with the formula H2Se. This hydrogen chalcogenide is the simplest and most commonly encountered hydride of selenium. H2Se is a colorless, flammable gas under standard conditions. It is the most toxic selenium compoundhttp://www.epa.gov/ttnatw01/hlthef/selenium.html, US Environmental Protection Agency, Air Toxins website with an exposure limit of 0.05 ppm over an 8-hour period.https://www.cdc.gov/niosh/docs/81-123/pdfs/0336.pdf Occupational Health Guideline for Hydrogen Selenide, The National Institute for Occupational Safety and Health, 1978 Even at extremely low concentrations, this compound has a very irritating smell resembling that of decayed horseradish or "leaking gas", but smells of rotten eggs at higher concentrations. Structure and properties H2Se adopts a bent structure with a H−Se−H bond angle of 91°. Consistent with this structure, three IR-active vibrational bands are observed: 2358, 2345, and 1034 cm−1. The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Selenides
A selenide is a chemical compound containing a selenium with oxidation number of −2. Similar to sulfide, selenides occur both as inorganic compounds and as organic derivatives, which are called organoselenium compound. Inorganic selenides The parent inorganic selenide is hydrogen selenide (H2Se). It is a colorless, malodorous, toxic gas. It dissolves in aqueous solution, to give the hydrogenselenide or biselenide ion HSe−. At higher pH, selenide forms. Solutions of hydrogen selenide and selenide are oxidized by air to give elemental selenium: : Most elements form selenides. They sometimes have salt-like properties, e.g. sodium selenide, but most exhibit covalent bonding, e.g. molybdenum diselenide. Their properties are diverse, mirroring the diverse properties of the corresponding sulfides. As indicated by the fact that only a few thousand tons of selenium are produced annually, the subset of selenium compounds called selenides find few applications. Commercially s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
