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Porosimetry
Porosimetry is an analytical technique used to determine various quantifiable aspects of a material's porous structure, such as pore diameter, total pore volume, surface area, and bulk and absolute densities. The technique involves the intrusion of a non-wetting liquid (often mercury) at high pressure into a material through the use of a porosimeter. The pore size can be determined based on the external pressure needed to force the liquid into a pore against the opposing force of the liquid's surface tension. A force balance equation known as Washburn's equation for the above material having cylindrical pores is given as: :P_L - P_G = -\frac :P_ = pressure of liquid :P_ = pressure of gas :\sigma = surface tension of liquid :\theta = contact angle of intrusion liquid :D_ = pore diameter Since the technique is usually performed within a vacuum, the initial gas pressure is zero. The contact angle of mercury with most solids is between 135° and 142°, so an average of 140 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Washburn's Equation
In physics, Washburn's equation describes capillary flow in a bundle of parallel cylindrical tubes; it is extended with some issues also to imbibition into porous materials. The equation is named after Edward Wight Washburn; also known as Lucas–Washburn equation, considering that Richard Lucas wrote a similar paper three years earlier, or the Bell-Cameron-Lucas-Washburn equation, considering J.M. Bell and F.K. Cameron's discovery of the form of the equation in 1906. Derivation In its most general form the Lucas Washburn equation describes the penetration length (L) of a liquid into a capillary pore or tube with time t as L=(Dt)^, where D is a simplified diffusion coefficient. This relationship, which holds true for a variety of situations, captures the essence of Lucas and Washburn's equation and shows that capillary penetration and fluid transport through porous structures exhibit diffusive behaviour akin to that which occurs in numerous physical and chemical systems. The dif ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Evapoporometry
Evapoporometry is a method used to determine pore-size in synthetic membranes. Based on the Kelvin equation, this technique is most accurate for detection of pore diameters between 4 nm to 150 nm. Theory Evapoporometry uses modified forms of the Kelvin equation to relate the evaporation of a wetting liquid (usually 2-propanol) from a membrane to the average diameter of the pores in that membrane. The primary equation used in this technique is: d = - Where d is the pore diameter, y is the surface tension, V_\text is the vapor molar volume, R is the gas constant, T is the absolute temperature, W_A is the instantaneous evaporation rate in mol/s, and W^\circ_A is the average evaporation rate of the free-standing liquid layer in mol/s. Method Evapoporometry has the significant advantage of requiring only a lab scale, 2-propanol (or another wetting fluid), and a cell in which to contain the sample and 2-propanol. The sample is immersed for some time in 2-propanol prior ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Contact Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cylinder (geometry)
A cylinder (from ) has traditionally been a three-dimensional solid, one of the most basic of curvilinear geometric shapes. In elementary geometry, it is considered a prism with a circle as its base. A cylinder may also be defined as an infinite curvilinear surface in various modern branches of geometry and topology. The shift in the basic meaning—solid versus surface (as in ball and sphere)—has created some ambiguity with terminology. The two concepts may be distinguished by referring to solid cylinders and cylindrical surfaces. In the literature the unadorned term cylinder could refer to either of these or to an even more specialized object, the ''right circular cylinder''. Types The definitions and results in this section are taken from the 1913 text ''Plane and Solid Geometry'' by George Wentworth and David Eugene Smith . A ' is a surface consisting of all the points on all the lines which are parallel to a given line and which pass through a fixed plane curve in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wood's Metal
Wood's metal, also known as Lipowitz's alloy or by the commercial names Cerrobend, Bendalloy, Pewtalloy and MCP 158, is a metal alloy that is useful for soldering and making custom metal parts, but which is toxic to touch or breathe vapors from. The alloy is named for Barnabas Wood, who first created and patented the alloy in 1860. It is a eutectic, fusible alloy of 50% bismuth, 26.7% lead, 13.3% tin, and 10% cadmium by mass. It has a melting point of approximately . Applications Wood's metal is useful as a low-melting solder, low-temperature casting metal, high-temperature coupling fluid in heat baths, and as a fire-melted valve element in fire sprinkler systems in buildings. Medical gas cylinders in the United Kingdom have a Wood's metal seal, which melts in fire, allowing the gas to escape and reducing the risk of gas explosion. Wood's metal is commonly used as a filler when bending thin-walled metal tubes. For this use the tubing is filled with molte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
BET Theory
Brunauer–Emmett–Teller (BET) theory aims to explain the physical adsorption of gas molecules on a solid surface and serves as the basis for an important analysis technique for the measurement of the specific surface area of materials. The observations are very often referred to as physical adsorption or physisorption. In 1938, Stephen Brunauer, Paul Hugh Emmett, and Edward Teller presented their theory in the ''Journal of the American Chemical Society''. BET theory applies to systems of multilayer adsorption that usually utilizes a probing gas (called the adsorbate) that do not react chemically with the adsorptive (the material upon which the gas attaches to and the gas phase is called the adsorptive) to quantify specific surface area. Nitrogen is the most commonly employed gaseous adsorbate for probing surface(s). For this reason, standard BET analysis is most often conducted at the boiling temperature of N2 (77 K). Other probing adsorbates are also utilized, albeit less oft ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metre
The metre (British spelling) or meter (American spelling; see spelling differences) (from the French unit , from the Greek noun , "measure"), symbol m, is the primary unit of length in the International System of Units (SI), though its prefixed forms are also used relatively frequently. The metre was originally defined in 1793 as one ten-millionth of the distance from the equator to the North Pole along a great circle, so the Earth's circumference is approximately km. In 1799, the metre was redefined in terms of a prototype metre bar (the actual bar used was changed in 1889). In 1960, the metre was redefined in terms of a certain number of wavelengths of a certain emission line of krypton-86. The current definition was adopted in 1983 and modified slightly in 2002 to clarify that the metre is a measure of proper length. From 1983 until 2019, the metre was formally defined as the length of the path travelled by light in a vacuum in of a second. After the 2019 redefiniti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Millinewton
The newton (symbol: N) is the unit of force in the International System of Units (SI). It is defined as 1 kg⋅m/s, the force which gives a mass of 1 kilogram an acceleration of 1 metre per second per second. It is named after Isaac Newton in recognition of his work on classical mechanics, specifically Newton's second law of motion. Definition A newton is defined as 1 kg⋅m/s (it is a derived unit which is defined in terms of the SI base units). One newton is therefore the force needed to accelerate one kilogram of mass at the rate of one metre per second squared in the direction of the applied force. The units "metre per second squared" can be understood as measuring a rate of change in velocity per unit of time, i.e. an increase in velocity by 1 metre per second every second. In 1946, Conférence Générale des Poids et Mesures (CGPM) Resolution 2 standardized the unit of force in the MKS system of units to be the amount needed to accelerate 1 kilogram of mass at the rate of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacuum
A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or " void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often discuss ideal test results that would occur in a ''perfect'' vacuum, which they sometimes simply call "vacuum" or free space, and use the term partial vacuum to refer to an actual imperfect vacuum as one might have in a laboratory or in space. In engineering and applied physics on the other hand, vacuum refers to any space in which the pressure is considerably lower than atmospheric pressure. The Latin term ''in vacuo'' is used to describe an object that is surrounded by a vacuum. The ''quality'' of a partial vacuum refers to how closely it approaches a perfect vacuum. Other things equal, lower gas pressure means higher-quality vacuum. For example, a typical vacuum cleaner produces enough suction to reduce air pressure by around 20%. But h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Measurement
Measurement is the quantification of attributes of an object or event, which can be used to compare with other objects or events. In other words, measurement is a process of determining how large or small a physical quantity is as compared to a basic reference quantity of the same kind. The scope and application of measurement are dependent on the context and discipline. In natural sciences and engineering, measurements do not apply to nominal properties of objects or events, which is consistent with the guidelines of the ''International vocabulary of metrology'' published by the International Bureau of Weights and Measures. However, in other fields such as statistics as well as the social and behavioural sciences, measurements can have multiple levels, which would include nominal, ordinal, interval and ratio scales. Measurement is a cornerstone of trade, science, technology and quantitative research in many disciplines. Historically, many measurement systems existed f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface (cf. closed-cell foam). There are many ways to test porosity in a substance or part, such as industrial CT scanning. The term porosity is used in multiple fields including pharmaceutics, ceramics, metallurgy, materials, manufacturing, petrophysics, hydrology, earth sciences, soil mechanics, and engineering. Void fraction in two-phase flow In gas-liquid two-phase flow, the void fraction is defined as the fraction of the flow-channel volume that is occupied by the gas phase or, alternatively, as the fraction of the cross-sectional area of the channel that is occupied by the gas phase. Void fraction usually varies from location to location in the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
