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Pine Bluff Arsenal
The Pine Bluff Arsenal is a United States Army installation in Jefferson County, Arkansas, about eight miles northwest of Pine Bluff and thirty miles southeast of Little Rock. Pine Bluff Arsenal is one of nine Army installations in the United States that stored chemical weapons. The arsenal supplies specialized production, storage, maintenance and distribution of readiness products, and delivers technical services to the Armed Forces and Homeland Security. It also designs, manufactures and refurbishes smoke, riot control, and incendiary munitions, as well as chemical/biological defense operations items. It serves as a technology center for illuminating and infrared munitions and is also the only place in the Northern Hemisphere where white phosphorus munitions are filled. Its Homeland Security mission includes first-responder equipment training and surveillance of pre-positioned equipment. History World War II The Pine Bluff Arsenal was established on November 2, 1941, for the ...
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Jefferson County, Arkansas
Jefferson County, officially the County of Jefferson, is a County (United States), county located in the U.S. state of Arkansas in the area known as the Arkansas Delta that extends west of the Mississippi River. Jefferson County consists of five City, cities, two towns, and 20 Civil township, townships. It is bisected by the Arkansas River, which was critical to its development and long the chief transportation byway. In 2020, Jefferson County's population was estimated at 67,260. The county seat and largest city is Pine Bluff, Arkansas, Pine Bluff. The county is included in the Pine Bluff metropolitan area, Pine Bluff metropolitan statistical area. The county seat and the List of municipalities in Arkansas, most populous city is Pine Bluff, Arkansas, Pine Bluff. Jefferson County was formed from Vaugine Township, Pulaski County, Arkansas, Pulaski County and Richland Township, Jefferson County, Arkansas, Richland Township, Arkansas County, Arkansas, Arkansas County in the Arkan ...
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Pine Bluff Chemical Activity
Pine Bluff Chemical Activity (abbreviated PBCA) is a subordinate organization of the United States Army Chemical Materials Agency located at Pine Bluff Arsenal in Pine Bluff, Arkansas. The U.S. Army stored approximately twelve percent of its original chemical weapons at the Pine Bluff Arsenal since 1942. Destruction of the last chemical weapons occurred on November 12, 2010."U.S. Army Completes Chemical Stockpile Destruction at Pine Bluff Chemical Agent Disposal Facility"
(news release), U.S. Army Chemical Materials Agency, Nov. 15, 2010.


Manufacture and storage

Pine Bluff Arsenal stored 90,409 M55 GB rockets, 19,608 M55 VX rockets, 9,378 M23 VX landmines and 3,705 mustard ton containers. It was also the home for th ...
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White Phosphorus
White phosphorus, yellow phosphorus, or simply tetraphosphorus (P4) is an allotrope of phosphorus. It is a translucent waxy solid that quickly yellows in light (due to its photochemical conversion into red phosphorus), and impure white phosphorus is for this reason called yellow phosphorus. White phosphorus is the first allotrope of phosphorus, and in fact the first elementary substance to be discovered that was not known since ancient times. It glows greenish in the dark (when exposed to oxygen) and is highly flammable and pyrophoric (self-igniting) upon contact with air. It is toxic, causing severe liver damage on ingestion and phossy jaw from chronic ingestion or inhalation. The odour of combustion of this form has a characteristic garlic odor, and samples are commonly coated with white " diphosphorus pentoxide", which consists of tetrahedra with oxygen inserted between the phosphorus atoms and at their vertices. White phosphorus is only slightly soluble in water and can ...
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Associated Press
The Associated Press (AP) is an American not-for-profit organization, not-for-profit news agency headquartered in New York City. Founded in 1846, it operates as a cooperative, unincorporated association, and produces news reports that are distributed to its members, major U.S. daily newspapers and radio and television broadcasters. Since the award was established in 1917, the AP has earned 59 Pulitzer Prizes, including 36 for photography. The AP is also known for its widely used ''AP Stylebook'', its AP polls tracking National Collegiate Athletic Association, NCAA sports, sponsoring the National Football League's annual awards, and its election polls and results during Elections in the United States, US elections. By 2016, news collected by the AP was published and republished by more than 1,300 newspapers and broadcasters. The AP operates 235 news bureaus in 94 countries, and publishes in English, Spanish, and Arabic. It also operates the AP Radio Network, which provides twice ...
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Nerve Agent
Nerve agents, sometimes also called nerve gases, are a class of organic chemistry, organic chemicals that disrupt the mechanisms by which nerves transfer messages to organs. The disruption is caused by the blocking of acetylcholinesterase (AChE), an enzyme that catalyzes the breakdown of acetylcholine, a neurotransmitter. Nerve agents are irreversible acetylcholinesterase inhibitors used as poison. Poisoning by a nerve agent leads to constriction of pupils, profuse salivation, convulsions, and involuntary urination and defecation, with the first symptoms appearing in seconds after exposure. Death by asphyxiation or cardiac arrest may follow in minutes due to the loss of the body's control over Respiration (physiology), respiratory and other muscles. Some nerve agents are readily vaporized or aerosolized, and the primary portal of entry into the body is the respiratory system. Nervous agents can also be absorbed through the skin, requiring that those likely to be subjected to su ...
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VX (nerve Agent)
VX is an extremely toxic chemical synthesis, synthetic chemical compound in the organophosphorus compound, organophosphorus class, specifically, a phosphonate, thiophosphonate. In the class of nerve agents, it was developed for military use in chemical warfare after translational science, translation of earlier discoveries of organophosphate toxicity in pesticide research. In its pure form, VX is an oily, relatively Volatility (chemistry), non-volatile liquid that is amber-like in colour. Because of its low volatility, VX persists in environments where it is dispersed. VX, short for "venomous agent X", is one of the best known of the V nerve agents and originated from pesticide development work at Imperial Chemical Industries (ICI). It was developed further at Porton Down in England during the early 1950s, based on research first done by Gerhard Schrader, a chemist working for IG Farben in Germany during the 1930s. It is now one of a broader V-series of agents which are class ...
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Mustard Gas
Mustard gas or sulfur mustard are names commonly used for the organosulfur compound, organosulfur chemical compound bis(2-chloroethyl) sulfide, which has the chemical structure S(CH2CH2Cl)2, as well as other Chemical species, species. In the wider sense, compounds with the substituents are known as ''sulfur mustards'' or ''nitrogen mustards'', respectively, where X = Cl or Br. Such compounds are potent alkylating agents, making mustard gas acutely and severely toxic. Mustard gas is a carcinogen. There is no preventative agent against mustard gas, with protection depending entirely on skin and airways protection, and no antidote exists for mustard poisoning. Also known as mustard agents, this family of compounds comprises infamous cytotoxicity, cytotoxins and blister agents with a long history of use as chemical weapons. The name ''mustard gas'' is technically incorrect; the substances, when Dispersion (chemistry), dispersed, are often not gases but a fine mist of liquid droplet ...
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Bigeye Bomb
The BLU-80/B BIGEYE bomb was a developmental U.S. air-launched binary chemical weapon. The BIGEYE was a class glide bomb with a radar altimeter fuze intended to disperse the binary generated nerve agent VX, made in flight from the non-lethal chemical components " QL" and sulfur only after aircraft release. The BLU-80-B was designed under the auspices of the U.S. Navy as a safe chemical weapons alternative in response to chemical weapons (CW) threats from the USSR and other actors. BIGEYE was a genuine tri-service program led by the U.S. Navy with significant U.S. Army and U.S. Air Force participation. Initially approved in the 1950s, the program persisted into the 1990s. Background As the stockpile of U.S. unitary (live agent) chemical weapons began to show troubling leakage, the Department of Defense (DoD) became acutely aware of the safety hazard to military personnel and public backlash this could generate. It is now known that the Soviets experienced the same and likely ...
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M687
The M687 was an American 155 mm binary sarin chemical artillery shell. The design was standardized in 1976 and production began on December 16, 1987 at Pine Bluff Arsenal, Pine Bluff, Arkansas. Production was halted three years later, following the 1990 Chemical Weapons Accord between the United States and the USSR, and the dismantling of existing stocks began in November 1997 at Hawthorne Army Depot, Nevada. America's remaining stocks were stored at the Deseret Chemical Depot, Utah, and the Umatilla Chemical Depot (Umatilla County, Oregon). The shell contained two canisters separated by a rupture disk. The compartments were filled with two liquid precursor chemicals for sarin (GB2): methylphosphonyl difluoride (denominated DF) and a mixture of isopropyl alcohol and isopropyl amine (denominated OPA) is in a second canister. The isopropyl amine binds the hydrogen fluoride generated during the chemical reaction. When the shell was fired the force of the acceleration would ca ...
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Methylphosphonic Difluoride
Methylphosphonyl difluoride (DF), also known as EA-1251 or difluoro, is a chemical weapon precursor. Its chemical formula is CH3POF2. It is a Schedule 1 substance under the Chemical Weapons Convention. It is used for production of sarin and soman as a component of binary chemical weapons; an example is the M687 artillery shell, where it is used together with a mixture of isopropyl alcohol and isopropyl amine, producing sarin. Preparation Methylphosphonyl difluoride can be prepared by reacting methylphosphonyl dichloride with hydrogen fluoride (HF) or sodium fluoride (NaF). Safety Methylphosphonyl difluoride is both reactive and corrosive. It is absorbed through skin and causes burns and mild nerve agent symptoms. It reacts with water, producing HF fumes and methylphosphonic acid Methylphosphonic acid is an organophosphorus compound with the chemical formula CH3P(O)(OH)2. The phosphorus center is tetrahedral and is bonded to a methyl group, two OH groups and an oxygen. Met ...
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Incapacitating Agent
Incapacitating agent is a chemical or biological agent which renders a person unable to harm themselves or others, regardless of consciousness. Lethal agents are primarily intended to kill, but incapacitating agents can also kill if administered in a potent enough dose, or in certain scenarios. The term "incapacitation," when used in a general sense, is not equivalent to the term "disability" as used in occupational medicine and denotes the inability to perform a task because of a quantifiable physical or mental impairment. In this sense, any of the chemical warfare agents may incapacitate a victim; however, by the military definition of this type of agent, incapacitation refers to impairments that are temporary and nonlethal. Thus, riot-control agents are incapacitating because they cause temporary loss of vision due to blepharospasm, but they are not considered military incapacitants because the loss of vision does not last long. Although incapacitation may result from physio ...
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